2,970 research outputs found
Continuum Theory of Polymer Crystallization
We present a kinetic model of crystal growth of polymers of finite molecular
weight. Experiments help to classify polymer crystallization broadly into two
kinetic regimes. One is observed in melts or in high molar mass polymer
solutions and is dominated by nucleation control with , where is the growth rate and is the super-cooling. The
other is observed in low molar mass solutions (as well as for small molecules)
and is diffusion controlled with , for small . Our
model unifies these two regimes in a single formalism. The model accounts for
the accumulation of polymer chains near the growth front and invokes an
entropic barrier theory to recover both limits of nucleation and diffusion
control. The basic theory applies to both melts and solutions, and we
numerically calculate the growth details of a single crystal in a dilute
solution. The effects of molecular weight and concentration are also determined
considering conventional polymer dynamics. Our theory shows that entropic
considerations, in addition to the traditional energetic arguments, can capture
general trends of a vast range of phenomenology. Unifying ideas on
crystallization from small molecules and from flexible polymer chains emerge
from our theory.Comment: 37 double-spaced pages including 8 figures, submitted to the Journal
of Chemical Physic
Seeding of supercooled polyethylene with extended chain crystals
Seeding of supercooled polyethylene with extended chain crystal
Co-planar spin-polarized light emitting diode
Studies of spin manipulation in semiconductors has benefited from the
possibility to grow these materials in high quality on top of optically active
III-V systems. The induced electroluminescence in these layered semiconductor
heterostructures has been used for a reliable spin detection. In semiconductors
with strong spin-orbit interaction, the sensitivity of vertical devices may be
insufficient, however, because of the sepration of the spin aligner part and
the spin detection region by one or more heterointerfaces and becuse of the
short spin coherence length. Here we demostrate that higly sensitive spin
detection can be achieved using a lateral arrangement of the spin polarized and
optically active regions. Using our co-planar spin-polarized light emitting
diodes we detect electrical field induced spin generation in a semiconductor
heterojunction two-dimensional hole gas. The polarization results from spin
asymmetric recombination of injected electrons with strongly SO coupled
two-dimensional holes. The possibility to detect magnetized Co particles
deposited on the co-planar diode structure is also demonstrated.Comment: 8 pages, 3 figure
Measuring entanglement in condensed matter systems
We show how entanglement may be quantified in spin and cold atom many-body
systems using standard experimental techniques only. The scheme requires no
assumptions on the state in the laboratory and a lower bound to the
entanglement can be read off directly from the scattering cross section of
Neutrons deflected from solid state samples or the time-of-flight distribution
of cold atoms in optical lattices, respectively. This removes a major obstacle
which so far has prevented the direct and quantitative experimental study of
genuine quantum correlations in many-body systems: The need for a full
characterization of the state to quantify the entanglement contained in it.
Instead, the scheme presented here relies solely on global measurements that
are routinely performed and is versatile enough to accommodate systems and
measurements different from the ones we exemplify in this work.Comment: 6 pages, 2 figure
Low-dimensional light-emitting transistor with tunable recombination zone
We present experimental and numerical studies of a light-emitting transistor
comprising two quasi-lateral junctions between a two-dimensional electron and
hole gas. These lithographically defined junctions are fabricated by etching of
a modulation doped GaAs/AlGaAs heterostructure. In this device electrons and
holes can be directed to the same area by drain and gate voltages, defining a
recombination zone tunable in size and position. It could therefore provide an
architecture for probing low-dimensional devices by analysing the emitted light
of the recombination zone.Comment: 12 Pages, to be published in Journal of Modern Optic
Enhancement of laser cooling by the use of magnetic gradients
We present a laser cooling scheme for trapped ions and atoms using a
combination of laser couplings and a magnetic gradient field. In a
Schrieffer-Wolff transformed picture, this setup cancels the carrier and blue
sideband terms completely resulting in an improved cooling behaviour compared
to standard cooling schemes (e.g. sideband cooling) and allowing cooling to the
vibrational ground state. A condition for optimal cooling rates is presented
and the cooling behaviour for different Lamb-Dicke parameters and spontaneous
decay rates is discussed. Cooling rates of one order of magnitude less than the
trapping frequency are achieved using the new cooling method. Furthermore the
scheme turns out to be robust under deviations from the optimal parameters and
moreover provides good cooling rates also in the multi particle case.Comment: 14 pages, 8 figure
Time-dependent Reactions of the Crystallizing and Solidifying of Linear High Polymers
Polyethylene polymer crystal growth - effects of high pressure, high temperature, and formation time on thermodynamic stabilit
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