8,068 research outputs found
Real space first-principles derived semiempirical pseudopotentials applied to tunneling magnetoresistance
In this letter we present a real space density functional theory (DFT)
localized basis set semi-empirical pseudopotential (SEP) approach. The method
is applied to iron and magnesium oxide, where bulk SEP and local spin density
approximation (LSDA) band structure calculations are shown to agree within
approximately 0.1 eV. Subsequently we investigate the qualitative
transferability of bulk derived SEPs to Fe/MgO/Fe tunnel junctions. We find
that the SEP method is particularly well suited to address the tight binding
transferability problem because the transferability error at the interface can
be characterized not only in orbital space (via the interface local density of
states) but also in real space (via the system potential). To achieve a
quantitative parameterization, we introduce the notion of ghost semi-empirical
pseudopotentials extracted from the first-principles calculated Fe/MgO bonding
interface. Such interface corrections are shown to be particularly necessary
for barrier widths in the range of 1 nm, where interface states on opposite
sides of the barrier couple effectively and play a important role in the
transmission characteristics. In general the results underscore the need for
separate tight binding interface and bulk parameter sets when modeling
conduction through thin heterojunctions on the nanoscale.Comment: Submitted to Journal of Applied Physic
Electronic Structures of Nitridomanganese(V) Complexes
The single-crystal polarized absorption and circular dichroism spectra of the nitridomanganese(V) complexes (salen)Mn⋮N (1), (1S,2S-(−)-saldpen)Mn⋮N (2), and (1R,2R-(+)-saldpen)Mn⋮N (3) have been measured [salen = N,N‘-ethylenebis(salicylideneaminato) dianion, 1S,2S-(−)-saldpen = N,N‘-(1S,2S-(−)-diphenyl)ethylenebis(salicylideneaminato) dianion, and 1R,2R-(+)-saldpen = N,N‘-(1R,2R-(+)-diphenyl)ethylenebis(salicylideneaminato) dianion]. As revealed by X-ray crystal structure analyses, these molecules have a distorted square-pyramidal geometry with a short Mn⋮N bond distance (1.52(3) Å for 2). The Cs compounds have a low-spin^ 1A‘[a‘(x^2 − y^2)]^2 ground state. The lowest absorption system (∼600 nm) consists of two components that are separated by approximately 4000 cm^(-1); these are assigned to ^1A‘ → ^1A‘[a‘(x^2 − y^2)a‘(yz)] (14 900 cm^(-1)) and ^1A‘ → ^1A‘‘[a‘(x^2 − y^2)a‘‘(xz)] (18 900 cm^(-1)) transitions
On the rate of black hole binary mergers in galactic nuclei due to dynamical hardening
We assess the contribution of dynamical hardening by direct three-body
scattering interactions to the rate of stellar-mass black hole binary (BHB)
mergers in galactic nuclei. We derive an analytic model for the single-binary
encounter rate in a nucleus with spherical and disk components hosting a
super-massive black hole (SMBH). We determine the total number of encounters
needed to harden a BHB to the point that inspiral due to
gravitational wave emission occurs before the next three-body scattering event.
This is done independently for both the spherical and disk components. Using a
Monte Carlo approach, we refine our calculations for to include
gravitational wave emission between scattering events. For astrophysically
plausible models we find that typically 10.
We find two separate regimes for the efficient dynamical hardening of BHBs:
(1) spherical star clusters with high central densities, low velocity
dispersions and no significant Keplerian component; and (2) migration traps in
disks around SMBHs lacking any significant spherical stellar component in the
vicinity of the migration trap, which is expected due to effective orbital
inclination reduction of any spherical population by the disk. We also find a
weak correlation between the ratio of the second-order velocity moment to
velocity dispersion in galactic nuclei and the rate of BHB mergers, where this
ratio is a proxy for the ratio between the rotation- and dispersion-supported
components. Because disks enforce planar interactions that are efficient in
hardening BHBs, particularly in migration traps, they have high merger rates
that can contribute significantly to the rate of BHB mergers detected by the
advanced Laser Interferometer Gravitational-Wave Observatory.Comment: 13 pages, 9 figures, accepted for publication in MNRA
Age Dating of a High-Redshift QSO B1422+231 at Z=3.62 and its Cosmological Implications
The observed Fe II(UV+optical)/Mg II lambda lambda 2796,2804 flux ratio from
a gravitationally lensed quasar B1422+231 at z=3.62 is interpreted in terms of
detailed modeling of photoionization and chemical enrichment in the broad-line
region (BLR) of the host galaxy. The delayed iron enrichment by Type Ia
supernovae is used as a cosmic clock. Our standard model, which matches the Fe
II/Mg II ratio, requires the age of 1.5 Gyr for B1422+231 with a lower bound of
1.3 Gyr, which exceeds the expansion age of the Einstein-de Sitter Omega_0=1
universe at a redshift of 3.62 for any value of the Hubble constant in the
currently accepted range, H_0=60-80 km,s^{-1},Mpc^{-1}. This problem of an age
discrepancy at z=3.62 can be unraveled in a low-density Omega_0<0.2 universe,
either with or without a cosmological constant, depending on the allowable
redshift range of galaxy formation. However, whether the cosmological constant
is a required option in modern cosmology awaits a thorough understanding of
line transfer processes in the BLRs.Comment: 7 pages including 3 figures, to appear in ApJ Letter
Solitons in Tonks-Girardeau gas with dipolar interactions
The existence of bright solitons in the model of the Tonks-Girardeau (TG) gas
with dipole-dipole (DD) interactions is reported. The governing equation is
taken as the quintic nonlinear Schr\"{o}dinger equation (NLSE) with the
nonlocal cubic term accounting for the DD attraction. In different regions of
the parameter space (the dipole moment and atom number), matter-wave solitons
feature flat-top or compacton-like shapes. For the flat-top states, the NLSE
with the local cubic-quintic (CQ) nonlinearity is shown to be a good
approximation. Specific dynamical effects are studied assuming that the
strength of the DD interactions is ramped up or drops to zero. Generation of
dark-soliton pairs in the gas shrinking under the action of the intensifying DD
attraction is observed. Dark solitons exhibit the particle-like collision
behavior. Peculiarities of dipole solitons in the TG gas are highlighted by
comparison with the NLSE including the local CQ terms. Collisions between the
solitons are studied too. In many cases, the collisions result in merger of the
solitons into a breather, due to strong attraction between them.Comment: 15 pages, 8 figures, accepted by J. Phys. B: At. Mol. Opt. Phy
Granular Scale Magnetic Flux Cancellations in the Photosphere
We investigate the evolution of 5 granular-scale magnetic flux cancellations
just outside the moat region of a sunspot by using accurate spectropolarimetric
measurements and G-band images with the Solar Optical Telescope aboard Hinode.
The opposite polarity magnetic elements approach a junction of the
intergranular lanes and then they collide with each other there. The
intergranular junction has strong red shifts, darker intensities than the
regular intergranular lanes, and surface converging flows. This clearly
confirms that the converging and downward convective motions are essential for
the approaching process of the opposite-polarity magnetic elements. However,
motion of the approaching magnetic elements does not always match with their
surrounding surface flow patterns in our observations. This suggests that, in
addition to the surface flows, subsurface downward convective motions and
subsurface magnetic connectivities are important for understanding the approach
and collision of the opposite polarity elements observed in the photosphere. We
find that the horizontal magnetic field appears between the canceling opposite
polarity elements in only one event. The horizontal fields are observed along
the intergranular lanes with Doppler red shifts. This cancellation is most
probably a result of the submergence (retraction) of low-lying photospheric
magnetic flux. In the other 4 events, the horizontal field is not observed
between the opposite polarity elements at any time when they approach and
cancel each other. These approaching magnetic elements are more concentrated
rather than gradually diffused, and they have nearly vertical fields even while
they are in contact each other. We thus infer that the actual flux cancellation
is highly time dependent events at scales less than a pixel of Hinode SOT
(about 200 km) near the solar surface.Comment: Accepted for publication in the Astrophysical Journa
Nutrient-Dense Orange-Fleshed Sweetpotato: Advances in Drought-Tolerance Breeding and Understanding of Management Practices for Sustainable Next-Generation Cropping Systems in Sub-Saharan Africa
Almost half of children < 5 years old living in sub-Saharan Africa (SSA) suffer from vitamin A deficiency and 60% suffer from iron deficiency. Thus, there has been a strong
commitment to breeding for, promoting awareness of, and delivering adapted pro-vitamin A rich orange-fleshed sweetpotato (OFSP) in SSA during the past two decades and
for enhanced iron content since 2014. This review article focuses on major breeding efforts in SSA to enhance the drought tolerance of OFSP and reviews integrated crop
management practices for improved and sustained sweetpotato production in SSA farming systems. Under climate change, the frequency and severity of droughts is expected to increase. Technical issues are presented in the context of addressing challenges along the entire value chain to ensure adoption. First, the use of an accelerated breeding scheme reduced the breeding cycle from 8–10 to 4–5 years.
Since 2010, 19 drought-tolerant OFSP cultivars have been released in Mozambique, 7 in Malawi, and 2 in South Africa. Moreover, research in four breeding populations
using the heterosis exploiting breeding scheme (HEBS) demonstrated that within one breeding cycle of 5 years, clones with significantly higher root yield, abiotic tolerance, host plant resistance to pests and diseases, and early maturity can be produced. In the future, HEBS will be combined with greater use of modern genomic tools,
new phenotyping tools, and CRISPR/Cas9-mediated gene editing. Second, beyond genetic enhancements, evidence is presented that using improved crop management
systems, existing sweet potato yields can be increased 2–4 times. Current knowledge is reviewed concerning sweetpotato’s role in diverse farming systems, but integrated crop management is clearly under researched. Third, the outlook for drought tolerance breeding indicates that two distinct classes of nutrient-rich cultivars are emerging: (1) Early maturing cultivars (< 4 month growing period) that escape drought but also serve humid environments with small landholding size per capita; and (2) Medium maturing (4–6 month growing period) cultivars that avoid drought, are drought tolerant and exhibit
continuous root formation. Increasing commercialization of the crop and climate change will drive demand, and the willingness of farmers to invest in improved sweetpotato
crop management
An implicit method for radiative transfer with the diffusion approximation in SPH
An implicit method for radiative transfer in SPH is described. The diffusion
approximation is used, and the hydrodynamic calculations are performed by a
fully three--dimensional SPH code. Instead of the energy equation of state for
an ideal gas, various energy states and the dissociation of hydrogen molecules
are considered in the energy calculation for a more realistic temperature and
pressure determination. In order to test the implicit code, we have performed
non--isothermal collapse simulations of a centrally condensed cloud, and have
compared our results with those of finite difference calculations performed by
MB93. The results produced by the two completely different numerical methods
agree well with each other.Comment: 25 pages, 9 figure
Synthesis And Properties Of Clay-ZrO2-Cellulose Fibre-Reinforced Polymeric Nano-Hybrids
Epoxy nano-hybrids reinforced with cellulose fibre (CF), nano-kaolinite (K), and micro-ZrO2 (Z) have been synthesized. The influence of CF/K/Z dispersions on the mechanical properties of these hybrids have been characterized in terms of elastic modulus, hardness, flexural strength, fracture toughness and indentation responses. This new but cost-effective approach has been developed to improve the physical and mechanical properties of polymeric materials without adversely affecting their processing characteristics. The mechanism of reinforcement in these organic/inorganic nanohybrid materials has been investigated. The micromechanisms of toughening and failure processes are identified and discussed in the light of observed nano- and micro-structures
The Hydromagnetic Interior of a Solar Quiescent Prominence. I. Coupling between Force-balance and Steady Energy-transport
This series of papers investigates the dynamic interior of a quiescent
prominence revealed by recent {\it Hinode} and {\it SDO/AIA} high-resolution
observations. This first paper is a study of the static equilibrium of the
Kippenhahn-Schl\"{u}ter diffuse plasma slab, suspended vertically in a bowed
magnetic field, under the frozen-in condition and subject to a theoretical
thermal balance among an optically-thin radiation, heating, and field-aligned
thermal conduction. The everywhere-analytical solutions to this nonlinear
problem are an extremely restricted subset of the physically admissible states
of the system. For most values of the total mass frozen into a given bowed
field, force-balance and steady energy-transport cannot both be met without a
finite fraction of the total mass having collapsed into a cold sheet of zero
thickness, within which the frozen-in condition must break down. An exact,
resistive hydromagnetic extension of the Kippenhahn-Schl\"{u}ter slab is also
presented, resolving the mass-sheet singularity into a finite-thickness layer
of steadily-falling dense fluid. Our hydromagnetic result suggests that the
narrow, vertical prominence threads may be falling across magnetic
fields, with optically-thick cores much denser and ionized to much lower
degrees than conventionally considered. This implication is discussed in
relation to (i) the recent {\it SDO/AIA} observations of quiescent prominences
that are massive and yet draining mass everywhere in their interiors, (ii) the
canonical range of determined from spectral-polarimetric observations
of prominence magnetic fields over the years and (iii) the need for a more
realistic multi-fluid treatment.Comment: 45 pages, 14 figure
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