Evaporation induced flow inside circular wells

Flow field and height averaged radial velocity inside a droplet evaporating in an open circular well were calculated for different modes of liquid evaporation.Comment: 5 page, 3 figures, submitted to European Physical Journal

2-Sulfoethylammonium trifluoromethanesulfonate as an Ionic Liquid for High Temperature PEM Fuel Cells

2-Sulfoethylammonium trifluoromethanesulfonate ([2-Sea+][TfO−]) represents a novel class of proton-conducting ionic liquids (PILs) based on aminoalkylsulfonic acids. The fundamental suitability of [2-Sea+][TfO−] for application as a protic electrolyte in high temperature PEM fuel cells (HT-PEFCs) was investigated up to a temperature of 130°C. A comparison was made against a state-of-the-art electrolyte, phosphoric acid. [2-Sea+][TfO−] is electrochemically and thermally stable up to 140°C. The specific conductivity of 95 wt% [2-Sea+][TfO−] aqueous solution at 130°C is ≈20 times lower compared to 95 wt% H3PO4. The strong coupling of ion transport and viscous flow suggests a vehicular ion (proton) transport in [2-Sea+][TfO−]. 95 wt% [2-Sea+][TfO−] shows superior kinetics in terms of oxygen reduction reaction (ORR) on polycrystalline Pt compared to 95 wt% H3PO4 at temperatures greater than 90°C in a fuel cell-applicable potential range. Double layer capacitances suggest a complex double layer structure, including adsorbed [2-Sea+][TfO−] and water, as well as intermediates of oxygen reduction and Pt oxidation. Potential and temperature-dependent ORR kinetics in the presence of 95 wt% [2-Sea+][TfO−] yield different Tafel slopes (b = 82–139 mV) and symmetry factors (β = 0.46–0.96), indicating changes in surface coverages of the adsorbed species and possibly also a change in the reaction mechanism

The Structure of Polyvinyl Alcohol Adsorption Layers at Interfaces with Benzene in Connection with Stability of Concentrated Emulsions

Determination of PV A adsorbtion on interfaces between PV A and benzene was performed. Adsorbed layers are formed under dynamic conditions emulsions were prepared by vibrocomminution and ultrasonic dispergation). Adsorbtion data are used in calculation of the area per adsorbed molecule and the thickness of interfacial adsorpbtion layers. Adsorption isotherms are compared with rheological parameters of adsorbed layers. On the basis of reported data on the distribution of adsorbed segments of PV A molecules, the interfacial thickness of the adsorbed layer is estimated to be several hundreds of A in a fo rm of gel. The formation of the gel is a result of condensation and phase deemulgation which is in agreement with a similar mechanism of gel formation in solution with diffuse distribution of polymer segments in the adsorbed layer. It is shown that at least one monolayer must cover drops of benzene in order to obtain stable emulsions. Kinetic parameters and the energy of activation of coalescence are dependent on PV A adsorption

Computer simulation and study of the IR spectra of irradiated polymer materials

Within the framework of MDDP the calculations of IR spectra have been performed for the initial polyethylene terephthalate (PET) and its state with the cation which satisfactorily describing experimental data. The calculations were made using the MDDP (modified neglect of diatomic differential overlap), implemented in the program MOPAC 2012. A feature of the method is that the overlap integrals are replaced by the [delta]-function, single-site Coulomb and exchange integrals are calculated by atomic parameters Slater-Condon. In recent years the studies of the structure and physico-chemical properties of polyethylene terephthalate and composites made on it basis have got the intensive development. Comparison of calculations with experimental data gives their satisfactory agreement

Correlation effects during liquid infiltration into hydrophobic nanoporous mediums

Correlation effects arising during liquid infiltration into hydrophobic porous medium are considered. On the basis of these effects a mechanism of energy absorption at filling porous medium by nonwetting liquid is suggested. In accordance with this mechanism, the absorption of mechanical energy is a result expenditure of energy for the formation of menisci in the pores on the shell of the infinite cluster and expenditure of energy for the formation of liquid-porous medium interface in the pores belonging to the infinite cluster of filled pores. It was found that in dependences on the porosity and, consequently, in dependences on the number of filled pores neighbors, the thermal effect of filling can be either positive or negative and the cycle of infiltration-defiltration can be closed with full outflow of liquid. It can occur under certain relation between percolation properties of porous medium and the energy characteristics of the liquid-porous medium interface and the liquid-gas interface. It is shown that a consecutive account of these correlation effects and percolation properties of the pores space during infiltration allow to describe all experimental data under discussion

Biomimetic thin film deposition

Biological mineral deposition for the formation of bone, mollusk shell and other hard tissues provides materials scientists with illustrative materials processing strategies. This presentation will review the key features of biomineralization and how these features can be of technical importance. We have adapted existing knowledge of biomineralization to develop a unique method of depositing inorganic thin films and coating. Our approach to thin film deposition is to modify substrate surfaces to imitate the proteins found in nature that are responsible for controlling mineral deposition. These biomimetic surfaces control the nucleation and growth of the mineral from a supersaturated aqueous solution. This has many processing advantages including simple processing equipment, environmentally benign reagents, uniform coating of highly complex shapes, and enhanced adherence of coating. Many different types of metal oxide, hydroxide, sulfide and phosphate materials with useful mechanical, optical, electronic and biomedical properties can be deposited

Классификация криогенно-оползневых форм рельефа для целей картографирования и прогноза

A classification of cryogenic-landslide landforms is developed for mapping their distribution and dynamics. It is based on the previously suggested classification subdividing cryogenic landsliding into two main types: cryogenic translational landslides (or active-layer detachment slides), and cryogenic earth flows (or retrogressive thaw slumps). The increased proportion of retrogressive thaw slumps compared to active layer detachments in the North of West Siberia in the last decade creates the need for an expanded classification of cryogenic earth flows. One of the important issues is separating the process of landsliding and resulting landforms, which in English are covered by one term ‘retrogressive thaw slump’. In dealing with the landforms, we distinguish (1) open and (2) closed ones. Open cryogenic-landslide landforms are those formed by the retreating of the coast bluff due to the thaw of ice or ice-rich deposits with an additional impact from wave or stream action. Closed cryogenic-landslide landforms are those initiated on a slope landward, and thawed material is delivered to the coast or stream through an erosional channel. Morphologically we distinguish thermocirques and thermoterraces depending on the shape of the retreating headwall, crescent or linear, respectively. An important issue is the type of ground ice subjected to thaw: tabular, ice-wedge or constitutional ground ice are distinguished. Landforms can be active, stabilized or ancient. One can find both single landforms and their combination. The classification is based on a significant amount of field studies and interpretation of remote sensing data. Mapping of the cryogenic-landslide landforms is suggested using the proposed classification and indication features. The classification is based on the experience obtained mainly in the north of West Siberia. Applying it to other regions may require additional studies.Разработана классификация криогенно-оползневых форм рельефа, сформированных криогенными оползнями течения (КОТФР), для картографирования их распространения и динамики. В основе лежит значительный объем полевых исследований и интерпретации данных дистанционного зондирования Земли. Классификация включает генетические, морфологические и криолитологические особенности пород, определяющие морфологию и динамику КОТФР, их положение в рельефе, степень их активности, сочетание и комплексирование единичных КОТФР. Предложенная классификация и индикационные признаки используются для картографирования КОТФР на севере Западной Сибири

Nonlinear dynamics of magnetohydrodynamic flows of heavy fluid over an arbitrary surface in shallow water approximation

The magnetohydrodynamic equations system for heavy fluid over an arbitrary surface in shallow water approximation is studied in the present paper. It is shown that simple wave solutions exist only for underlying surfaces that are slopes of constant inclination. All self-similar discontinuous and continuous solutions are found. The exact explicit solutions of initial discontinuity decay problem over a flat plane and a slope are found. It is shown that the initial discontinuity decay solution is represented by one of five possible wave configurations. For each configuration the necessary and sufficient conditions for its realization are found. The change of dependent and independent variables transforming the initial equations over a slope to those over a flat plane is found.Comment: 43 pages, submitted to Theoretical and Computational Fluid Dynamic

Grafted block complex coacervate core micelles and their effect on protein adsorption on silica and polystyrene

We have studied the formation and the stability of grafted block complex coacervate core micelles (C3Ms) in solution and the influence of grafted block C3M coatings on the adsorption of the proteins β-lactoglobulin, bovine serum albumin, and lysozyme. The C3Ms consist of a grafted block copolymer PAA21-b-PAPEO14 (poly(acrylic acid)-b-poly(acrylate methoxy poly(ethylene oxide)), with a negatively charged PAA block and a neutral PAPEO block and a positively charged homopolymer P2MVPI (poly(N-methyl 2-vinyl pyridinium iodide). In solution, these C3Ms partly disintegrate at salt concentrations between 50 and 100 mM NaCl. Adsorption of C3Ms and proteins has been studied with fixed-angle optical reflectometry, at salt concentrations ranging from 1 to 100 mM NaCl. In comparison with the adsorption of PAA21-b-PAPEO14 alone adsorption of C3Ms significantly increases the amount of PAA21-b-PAPEO14 on the surface. This results in a higher surface density of PEO chains. The stability of the C3M coatings and their influence on protein adsorption are determined by the composition and the stability of the C3Ms in solution. A C3M-PAPEO14/P2MVPI43 coating strongly suppresses the adsorption of all proteins on silica and polystyrene. The reduction of protein adsorption is the highest at 100 mM NaCl (>90%). The adsorbed C3M-PAPEO14/P2MVPI43 layer is partly removed from the surface upon exposure to an excess of β-lactoglobulin solution, due to formation of soluble aggregates consisting of β-lactoglobulin and P2MVPI43. In contrast, C3M-PAPEO14/P2MVPI228 which has a fivefold longer cationic block enhances adsorption of the negatively charged proteins on both surfaces at salt concentrations above 1 mM NaCl. A single PAA21-b-PAPEO14 layer causes only a moderate reduction of protein adsorption