Evaluation of the potential for dissolved oxygen ingress into deep sedimentary basins during a glaciation event

Geochemical conditions in intracratonic sedimentary basins are currently reducing, even at relatively shallow depths. However, during glaciation-deglaciation events, glacial meltwater production may result in enhanced recharge (Bea et al., 2011; and Bea et al., 2016) potentially having high concentrations of dissolved oxygen (O2). In this study, the reactive transport code Par-MIN3PTHCm was used to perform an informed, illustrative set of simulations assessing the depth of penetration of low salinity, O2-rich, subglacial recharge. Simulation results indicate that the large-scale basin hydrostratigraphy, in combination with the presence of dense brines at depth, results in low groundwater velocities during glacial meltwater infiltration, restricting the vertical ingress of dilute recharge waters. Furthermore, several geochemical attenuation mechanisms exist for O2, which is consumed by reactions with reduced mineral phases and solid organic matter (SOM). The modeling showed that effective oxidative mineral dissolution rates and SOMoxidation rates between 5 × 10-15 and 6 × 10-13 mol dm-3 bulk s-1 were sufficient to restrict the depth of O2 ingress to less than 200m.These effective rates are low and thus conservative, in comparison to rates reported in the literature. Additional simulations with more realistic, yet still conservative, parameters reaffirm the limited ability for O2 to penetrate into sedimentary basin rocks during a glaciation-deglaciation event.Fil: Bea, Sergio Andrés. Universidad Nacional del Centro de la Provincia de Buenos Aires. Rectorado. Instituto de Hidrología de Llanuras - Sede Tandil. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto de Hidrología de Llanuras - Sede Tandil; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Su, Danyang. University of British Columbia; CanadáFil: Mayer, Klaus Ulrich. University of British Columbia; CanadáFil: MacQuarrie, T. B.. University of New Brunswick; Canad

Spin-orbital excitation continuum and anomalous electron-phonon interaction in the Mott insulator LaTiO3_3

Raman scattering experiments on stoichiometric, Mott-insulating LaTiO$_3$ over a wide range of excitation energies reveal a broad electronic continuum which is featureless in the paramagnetic state, but develops a gap of $\sim 800$ cm$^{-1}$ upon cooling below the N\'eel temperature $T_N = 146$ K. In the antiferromagnetic state, the spectral weight below the gap is transferred to well-defined spectral features due to spin and orbital excitations. Low-energy phonons exhibit pronounced Fano anomalies indicative of strong interaction with the electron system for $T > T_N$, but become sharp and symmetric for $T < T_N$. The electronic continuum and the marked renormalization of the phonon lifetime by the onset of magnetic order are highly unusual for Mott insulators and indicate liquid-like correlations between spins and orbitals.Comment: to appear in Phys. Rev. Let

Phonon anomalies in pure and underdoped R{1-x}K{x}Fe{2}As{2} (R = Ba, Sr) investigated by Raman light scattering

We present a detailed temperature dependent Raman light scattering study of optical phonons in Ba{1-x}K{x}Fe{2}As{2} (x ~ 0.28, superconducting Tc ~ 29 K), Sr{1-x}K{x}Fe{2}As{2} (x ~ 0.15, Tc ~ 29 K) and non-superconducting BaFe{2}As{2} single crystals. In all samples we observe a strong continuous narrowing of the Raman-active Fe and As vibrations upon cooling below the spin-density-wave transition Ts. We attribute this effect to the opening of the spin-density-wave gap. The electron-phonon linewidths inferred from these data greatly exceed the predictions of ab-initio density functional calculations without spin polarization, which may imply that local magnetic moments survive well above Ts. A first-order structural transition accompanying the spin-density-wave transition induces discontinuous jumps in the phonon frequencies. These anomalies are increasingly suppressed for higher potassium concentrations. We also observe subtle phonon anomalies at the superconducting transition temperature Tc, with a behavior qualitatively similar to that in the cuprate superconductors.Comment: 5 pages, 6 figures, accepted versio

Doping Dependence of Bilayer Resonant Spin Excitations in (Y,Ca)Ba2Cu3O6+x\bf (Y,Ca)Ba_2Cu_3O_{6+x}

Resonant magnetic modes with odd and even symmetries were studied by inelastic neutron scattering experiments in the bilayer high-$T_c$ superconductor $\rm Y_{1-x}Ca_{x}Ba_2Cu_3O_{6+y}$ over a wide doping range. The threshold of the spin excitation continuum in the superconducting state, deduced from the energies and spectral weights of both modes, is compared with the superconducting d-wave gap, measured on the same samples by electronic Raman scattering in the $B_{1g}$ symmetry. Above a critical doping level of $\delta \simeq 0.19$, both mode energies and the continuum threshold coincide. We find a simple scaling relationship between the characteristic energies and spectral weights of both modes, which indicates that the resonant modes are bound states in the superconducting energy gap, as predicted by the spin-exciton model of the resonant mode.Comment: 4 figure

Open Space – a collaborative process for facilitating Tourism IT partnerships

The success of IT projects depends on the success of the partnerships on which they are based. However past research by the author has identified a significant rate of failure in these partnerships, predominantly due to an overly technical mindset, leading to the question: “how do we ensure that, as technological solutions are implemented within tourism, due consideration is given to human-centred issues?” The tourism partnership literature is explored for additional insights revealing that issues connected with power, participation and normative positions play a major role. The method, Open Space, is investigated for its ability to engage stakeholders in free and open debate. This paper reports on a one-day Open Space event sponsored by two major intermediaries in the UK travel industry who wanted to consult their business partners. Both the running of the event and its results reveal how Open Space has the potential to address some of the weaknesses associated with tourism partnerships

Air Shower Simulation and Hadronic Interactions

The aim of this report of the Working Group on Hadronic Interactions and Air Shower Simulation is to give an overview of the status of the field, emphasizing open questions and a comparison of relevant results of the different experiments. It is shown that an approximate overall understanding of extensive air showers and the corresponding hadronic interactions has been reached. The simulations provide a qualitative description of the bulk of the air shower observables. Discrepancies are however found when the correlation between measurements of the longitudinal shower profile are compared to that of the lateral particle distributions at ground. The report concludes with a list of important problems that should be addressed to make progress in understanding hadronic interactions and, hence, improve the reliability of air shower simulations.Comment: Working Group report given at UHECR 2012 Symposium, CERN, Feb. 2012. Published in EPJ Web of Conferences 53, 01007 (2013

Quantum mutual information of an entangled state propagating through a fast-light medium

Although it is widely accepted that classical information cannot travel faster than the speed of light in vacuum, the behavior of quantum correlations and quantum information propagating through actively-pumped fast-light media has not been studied in detail. To investigate this behavior, we send one half of an entangled state of light through a gain-assisted fast-light medium and detect the remaining quantum correlations. We show that the quantum correlations can be advanced by a small fraction of the correlation time while the entanglement is preserved even in the presence of noise added by phase-insensitive gain. Additionally, although we observe an advance of the peak of the quantum mutual information between the modes, we find that the degradation of the mutual information due to the added noise appears to prevent an advancement of the leading edge. In contrast, we show that both the leading and trailing edges of the mutual information in a slow-light system can be significantly delayed