7,592 research outputs found
SNS Timing System
This poster describes the timing system being designed for Spallation Neutron
Source being built at Oak Ridge National lab
Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHMe)(2)}]
Addition of PMe2Ph to fused-cluster syn-[(η5-C5Me5)IrB18H20] 1 to give [(η5-C5Me5)HIrB18H19(PMe2Ph)] 3 entails a diminution in the degree of intimacy of the intercluster fusion, rather than retention of inter-subcluster binding intimacy and a nido → arachno conversion of the character of either of the subclusters. Reaction with MeNC gives [(η5-C5Me5)HIrB18H19{C(NHMe)2}] 4 which has a similar structure, but with the ligand now being the carbene {:C(NHMe)2}, resulting from a reductive assembly reaction involving two MeNC residues and the loss of a carbon atom
Macropolyhedral boron-containing cluster chemistry: two-electron variations in intercluster bonding intimacy. Contrasting structures of 19-vertex [(eta(5)-C5Me5)HIrB18H19(PHPh2)] and [(eta(5) -C5Me5)IrB18H18(PH2Ph)]
Fused double-cluster [(5-C5Me5)IrB18H18(PH2Ph)]8, from syn-[(5-C5Me5)IrB18H20] 1 and PH2Ph, retains the three-atoms-in-common cluster fusion intimacy of 1, in contrast to [(5-C5Me5)HIrB18H19(PHPh2)]6, from PHPh2 with 1, which exhibits an opening to a two atoms-in-common cluster fusion intimacy. Compound 8 forms via spontaneous dihydrogen loss from its precursor [(5-C5Me5)HIrB18H19(PH2Ph)]7, which has two-atoms-in-common cluster-fusion intimacy and is structurally analogous to 6
Fairbanks Gang Assessment
The Justice Center at University of Alaska Anchorage partnered with the Fairbanks Gang Reduction and Intervention Network (GRAIN) to perform a thorough assessment of the gang problem in Fairbanks following the protocol outlined by the Office of Juvenile Justice and Delinquency Prevention (OJJDP)’s Comprehensive Gang Model. Law enforcement data show that there are at least 12 active gangs in the Fairbanks North Star Borough, with the percentage of crime reported to law enforcement attributable to gangs (2007-2009) varying from a low of 4.3% in 2007 to a high of 7.2% in 2008. The complete assessment, contained in this report, includes a review of community demographic data, law enforcement data, student and school data, and community perceptions data.Fairbanks Gang Reduction and Intervention Network
Grant No. 2007-JV-FX-0331Index of Tables and Figures / Acknowledgements / Section I Fairbanks Gang Assessment: Executive Summary / Section II Fairbanks Gang Assessment: Community Demographic Data / Section III Fairbanks Gang Assessment: Law Enforcement Data / Section IV Fairbanks Gang Assessment: Student and School Data / Section V Fairbanks Gang Assessment: Community Perceptions Data / Section VI Fairbanks Gang Assessment: Community Resources Data / Section VII Fairbanks Gang Assessment Methods / References / Appendix A Community Resident Survey / Appendix B Student Survey / Appendix C Youth Serving and Law Enforcement Agency Survey / Appendix D Gang Member Interview For
Ab initio electronic structure calculations of solid, solution-processed metallotetrabenzoporphyrins
An ab initio study of the electronic structures of solid
metallotetrabenzoporphyrins (MTBPs) utilized in organic transistors and
photovoltaics is presented. Bandstructures, densities of states, and orbitals
are calculated for H2, Cu, Ni, and Zn core substitutions of the unit cell of
solid TBP, as deposited via soluble precursors that are thermally annealed to
produce polycrystalline, semiconducting thin-films. While the unit cells of the
studied MTBPs are nearly isomorphous, substitution of the core atoms alters the
structure of the bands around the energy bandgap and the composition of the
densities of states. Cu and Ni core substitutions introduce
nearly-dispersionless energy bands near the valence and conduction band edges,
respectively, that form acceptor or deep generation/recombination states.Comment: 7 pages, 3 figures, 4 table
Another shock for the Bullet cluster, and the source of seed electrons for radio relics
With Australia Telescope Compact Array observations, we detect a highly
elongated Mpc-scale diffuse radio source on the eastern periphery of the Bullet
cluster 1E0657-55.8, which we argue has the positional, spectral and
polarimetric characteristics of a radio relic. This powerful relic (2.3+/-0.1 x
10^25 W Hz^-1) consists of a bright northern bulb and a faint linear tail. The
bulb emits 94% of the observed radio flux and has the highest surface
brightness of any known relic. Exactly coincident with the linear tail we find
a sharp X-ray surface brightness edge in the deep Chandra image of the cluster
-- a signature of a shock front in the hot intracluster medium (ICM), located
on the opposite side of the cluster to the famous bow shock. This new example
of an X-ray shock coincident with a relic further supports the hypothesis that
shocks in the outer regions of clusters can form relics via diffusive shock
(re-)acceleration. Intriguingly, our new relic suggests that seed electrons for
reacceleration are coming from a local remnant of a radio galaxy, which we are
lucky to catch before its complete disruption. If this scenario, in which a
relic forms when a shock crosses a well-defined region of the ICM polluted with
aged relativistic plasma -- as opposed to the usual assumption that seeds are
uniformly mixed in the ICM -- is also the case for other relics, this may
explain a number of peculiar properties of peripheral relics.Comment: 10 pages, 9 figures, 1 table, accepted for publication in MNRA
Under Pressure: Quenching Star Formation in Low-Mass Satellite Galaxies via Stripping
Recent studies of galaxies in the local Universe, including those in the
Local Group, find that the efficiency of environmental (or satellite) quenching
increases dramatically at satellite stellar masses below ~ . This suggests a physical scale where quenching transitions from a
slow "starvation" mode to a rapid "stripping" mode at low masses. We
investigate the plausibility of this scenario using observed HI surface density
profiles for a sample of 66 nearby galaxies as inputs to analytic calculations
of ram-pressure and viscous stripping. Across a broad range of host properties,
we find that stripping becomes increasingly effective at $M_{*} < 10^{8-9}\
{\rm M}_{\odot}n_{\rm halo} <
10^{-3.5}{\rm cm}^{-3}$), we find that stripping is not fully effective;
infalling satellites are, on average, stripped of < 40 - 70% of their cold gas
reservoir, which is insufficient to match observations. By including a host
halo gas distribution that is clumpy and therefore contains regions of higher
density, we are able to reproduce the observed HI gas fractions (and thus the
high quenched fraction and short quenching timescale) of Local Group
satellites, suggesting that a host halo with clumpy gas may be crucial for
quenching low-mass systems in Local Group-like (and more massive) host halos.Comment: updated version after review, now accepted to MNRAS; Accepted 2016
August 22. Received 2016 August 18; in original form 2016 June 2
Cosmic ray tables - Asymptotic directions, variational coefficients and cut-off rigidities IQSY instruction manual no. 10
Cosmic ray deflections in geomagnetic field, variational coefficients, and diurnal intensity variations - table
- …
