150 research outputs found
RESIK observations of He-like Ar X-ray line emission in solar flares
The Ar XVII X-ray line group principally due to transitions 1s2 - 1s2l (l=s,
p) near 4 Anstroms was observed in numerous flares by the RESIK bent crystal
spectrometer aboard CORONAS-F between 2001 and 2003. The three line features
include the Ar XVII w (resonance line), a blend of x and y (intercombination
lines), and z (forbidden line), all of which are blended with Ar XVI
dielectronic satellites. The ratio G, equal to [I(x+y) + I(z)]/I(w), varies
with electron temperature Te mostly because of unresolved dielectronic
satellites. With temperatures estimated from GOES X-ray emission, the observed
G ratios agree fairly well with those calculated from CHIANTI and other data.
With a two-component emission measure, better agreement is achieved. Some S XV
and S XVI lines blend with the Ar lines, the effect of which occurs at
temperatures greater than 8MK, allowing the S/Ar abundance ratio to be
determined. This is found to agree with coronal values. A nonthermal
contribution is indicated for some spectra in the repeating-pulse flare of 2003
February 6.Comment: Latex file and 3 ps files. Astrophysical Journal Letters (accepted,
June 2008
Highly Ionized Potassium Lines in Solar X-ray Spectra and the Abundance of Potassium
The abundance of potassium is derived from X-ray lines observed during flares
by the RESIK instrument on the solar mission CORONAS-F between 3.53 A and 3.57
A. The lines include those emitted by He-like K and Li-like K dielectronic
satellites, which have been synthesized using the CHIANTI atomic code and newly
calculated atomic data. There is good agreement of observed and synthesized
spectra, and the theoretical behavior of the spectra with varying temperature
estimated from the ratio of the two GOES channels is correctly predicted. The
observed fluxes of the He-like K resonance line per unit emission measure gives
log A(K) = 5.86 (on a scale log A(H) = 12), with a total range of a factor 2.9.
This is higher than photospheric abundance estimates by a factor 5.5, a
slightly greater enhancement than for other elements with first ionization
potential (FIP) less than about 10 eV. There is, then, the possibility that
enrichment of low-FIP elements in coronal plasmas depends weakly on the value
of the FIP which for K is extremely low (4.34 eV). Our work also suggests that
fractionation of elements to form the FIP effect occurs in the low chromosphere
rather than higher up, as in some models.Comment: 14 pages, 3 figure
Chandra High Resolution X-ray Spectroscopy of AM Her
We present the results of high resolution spectroscopy of the prototype polar
AM Herculis observed with Chandra High Energy Transmission Grating. The X-ray
spectrum contains hydrogen-like and helium-like lines of Fe, S, Si, Mg, Ne and
O with several Fe L-shell emission lines. The forbidden lines in the spectrum
are generally weak whereas the hydrogen-like lines are stronger suggesting that
emission from a multi-temperature, collisionally ionized plasma dominates. The
helium-like line flux ratios yield a plasma temperature of 2 MK and a plasma
density 1 - 9 x10^12 cm^-3, whereas the line flux ratio of Fe XXVI to Fe XXV
gives an ionization temperature of 12.4 +1.1 -1.4 keV. We present the
differential emission measure distribution of AM Her whose shape is consistent
with the volume emission measure obtained by multi-temperature APEC model. The
multi-temperature plasma model fit to the average X-ray spectrum indicates the
mass of the white dwarf to be ~1.15 M_sun. From phase resolved spectroscopy, we
find the line centers of Mg XII, S XVI, resonance line of Fe XXV, and Fe XXVI
emission modulated by a few hundred to 1000 km/s from the theoretically
expected values indicating bulk motion of ionized matter in the accretion
column of AM Her. The observed velocities of Fe XXVI ions are close to the
expected shock velocity for a 0.6 M_sun white dwarf. The observed velocity
modulation is consistent with that expected from a single pole accreting binary
system.Comment: 6 figures, AASTEX style, accepted for publication in Ap
The Solar Flare Chlorine Abundance from RESIK X-ray Spectra
The abundance of chlorine is determined from X-ray spectra obtained with the
RESIK instrument on {\em CORONAS-F} during solar flares between 2002 and 2003.
Using weak lines of He-like Cl, \ion{Cl}{16}, between 4.44 and 4.50 \AA, and
with temperatures and emission measures from {\em GOES} on an isothermal
assumption, we obtained on a scale . The uncertainty reflects an approximately factor 2 scatter in measured
line fluxes. Nevertheless our value represents what is probably the best solar
determination yet obtained. It is higher by factors of 1.8 and 2.7 than Cl
abundance estimates from an infrared sunspot spectrum and nearby \ion{H}{2}
regions. The constancy of the RESIK abundance values over a large range of
flares ({\em GOES} class from below C1 to X1) argues for any fractionation that
may be present in the low solar atmosphere to be independent of the degree of
solar activity.Comment: 13 pages, 3 colour figures. To be published, Astrophysical Journa
Excitation of the 3.071mm Hyperfine Line in Li-Like 57-Fe in Astrophysical Plasmas
As noted first by Sunyaev & Churazov (1984), the 3.071 mm hyperfine line from
might be observable in astrophysical plasmas. We assess the
atomic processes which might contribute to the excitation of this line. We
determine the intensity of the hyperfine line from an isothermal, coronal
plasma in collisional ionization equilibrium and for a coronal plasma cooling
isobarically due to its own radiation. Comparisons of the hyperfine line to
other lines emitted by the same ion, Fe, are shown to be useful for
deriving the isotopic fraction of Fe. We calculate the ratios of the
hyperfine line to the 2s--2p EUV lines at 192 \AA and 255 \AA, and the 2s--3p
X-ray doublet at 10.6 \AA.Comment: 28 pages text+figures, Accepted to ApJ in Jan 98, also at
http://www.astro.virginia.edu/~nld2n/research.htm
SOLORZANO, ÁNGELES Y ROSARIO [Material gráfico]
Copia digital. Madrid : Ministerio de Educación, Cultura y Deporte, 201
State-resolved valence shell photoionization of Be-like ions: experiment and theory
High-resolution photoionization experiments were carried out using beams of
Be-like C, N, and O ions with roughly equal populations of
the S ground-state and the P manifold of metastable components. The
energy scales of the experiments are calibrated with uncertainties of 1 to 10
meV depending on photon energy. Resolving powers beyond 20,000 were reached
allowing for the separation of contributions from the individual metastable
P, P, and P states. The measured data compare
favourably with semi-relativistic Breit-Pauli R-matrixComment: 23 figures and 3 table
Effects of regular salt marsh haying on marsh plants, algae, invertebrates and birds at Plum Island Sound, Massachusetts
Author Posting. © The Author(s), 2009. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Wetlands Ecology and Management 17 (2009): 469-487, doi: 10.1007/s11273-008-9125-3.The haying of salt marshes, a traditional activity since colonial times in New England, still occurs in about 400 ha of marsh in the Plum Island Sound estuary in northeastern Massachusetts. We took advantage of this haying activity to investigate how the periodic large-scale removal of aboveground biomass affects a number of marsh processes. Hayed marshes were no different from adjacent reference marshes in plant species density (species per area) and end-of-year aboveground biomass, but did differ in vegetation composition. Spartina patens was more abundant in hayed marshes than S. alterniflora, and the reverse was true in reference marshes. The differences in relative covers of these plant species were not associated with any differences between hayed and reference marshes in the elevations of the marsh platform. Instead it suggested that S. patens was more tolerant of haying than S. alterniflora. S. patens had higher stem densities in hayed marshes than it did in reference marshes, suggesting that periodic cutting stimulated tillering of this species. Although we predicted that haying would stimulate benthic chlorophyll production by opening up the canopy, we found differences to be inconsistent, possibly due to the relatively rapid regrowth of S. patens and to grazing by invertebrates on the algae. The pulmonate snail, Melampus bidendatus was depleted in its δ13C content in the hayed marsh compared to the reference, suggesting a diet shift to benthic algae in hayed marshes. The stable isotope ratios of a number of other consumer species were not affected by haying activity. Migratory shorebirds cue in to recently hayed marshes and may contribute to short term declines in some invertebrate species, however the number of taxa per unit area of marsh surface invertebrates and their overall abundances were unaffected by haying over the long term. Haying had no impact on nutrient concentrations in creeks just downstream from hayed plots, but the sediments of hayed marshes were lower in total N and P compared to references. In sum, haying appeared to affect plant species composition but had only short-term affects on consumer organisms. This contrasts with many grassland ecosystems, where an intermediate level of disturbance, such as by grazing, increases species diversity and may stimulate productivity. From a management perspective, periodic mowing could be a way to maintain S. patens habitats and the suite of species with which they are associated.This research was supported by the Plum Island Ecosystem Long Term Ecological Research program (OCE-972692 and OCE 0423565) of the National Science Foundation (NSF). J. Horowitz and J. Ludlam were supported by NSF Research Experience for Undergraduate (REU) grants when they were students at Hampshire College and Gordon College respectively
Platinum–rhodium–tin/carbon electrocatalysts for ethanol oxidation in acid media: effect of the precursor addition order and the amount of tin
Carbon-supported Pt x –Rh y –Sn z catalysts (x:y:z = 3:1:4, 6:2:4, 9:3:4) are prepared by Pt, Rh, and Sn precursors reduction in different addition order. The materials are characterized by X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy techniques and are evaluated for the electrooxidation of ethanol in acidic media by cyclic voltammetry, chronoamperometry, and anode potentiostatic polarization. The influence of both the order in which the precursors are added and the composition of metals in the catalysts on the electrocatalytic activity and physico-chemical characteristics of Pt x –Rh y –Sn z /C catalysts is evaluated. Oxidized Rh species prevail on the surface of catalysts synthesized by simultaneous co-precipitation, thus demonstrating the influence of synthesis method on the oxidation state of catalysts. Furthermore, high amounts of Sn in composites synthesized by co-precipitation result in very active catalysts at low potentials (bifunctional effect), while medium Sn load is needed for sequentially deposited catalysts when the electronic effect is most important (high potentials), since more exposed Pt and Rh sites are needed on the catalyst surface to alcohol oxidation. The Pt3–Rh1–Sn4/C catalyst prepared by co-precipitation is the most active at potentials lower than 0.55 V (related to bifunctional effect), while the Pt6–Rh2–Sn4/C catalyst, prepared by sequential precipitation (first Rh and, after drying, Pt + Sn), is the most active above 0.55 V.The authors thank the Brazilian National Council of Technological and Scientific Development-CNPq (Grants: 402243/2012-9, 303630/2012-4, 474261/2013-1, 407274/2013-8, and 310282/2013-6) for the scholarships and financial support for this work
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