1,267 research outputs found

    Ultracold homonuclear and heteronuclear collisions in metastable helium

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    Scattering and ionizing cross sections and rates are calculated for ultracold collisions between metastable helium atoms using a fully quantum-mechanical close-coupled formalism. Homonuclear collisions of the bosonic 4{}^{4}He+4^{*} +{}^{4}He^{*} and fermionic 3{}^{3}He+3^{*} + {}^{3}He^{*} systems, and heteronuclear collisions of the mixed 3{}^{3}He+4^{*} +{}^{4}He^{*} system, are investigated over a temperature range 1 μ\muK to 1 K. Carefully constructed Born-Oppenheimer molecular potentials are used to describe the electrostatic interaction between the colliding atoms, and complex optical potentials used to represent loss through ionization from the 1,3Σ{}^{1,3}\Sigma states. Magnetic spin-dipole mediated transitions from the 5Σ{}^{5}\Sigma state are included and results reported for spin-polarized and unpolarized systems. Comparisons are made with experimental results, previous semi-classical models, and a perturbed single channel model.Comment: 14 pages, 9 figure

    Increased resistance to stress corrosion of aluminum alloys

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    Stress corrosion resistance is increased by distorting surface grain-boundary structure and by interrupting the corrosion and stress corrosion. The first is accomplished by machining or shot peening and the second by removal from and later reexposure to the corrosive environment

    Photoassociation spectra and the validity of the dipole approximation for weakly bound dimers

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    Photoassociation (PA) of ultracold metastable helium to the 2s2p manifold is theoretically investigated using a non-perturbative close-coupled treatment in which the laser coupling is evaluated without assuming the dipole approximation. The results are compared with our previous study [Cocks and Whittingham, Phys. Rev. A 80, 023417 (2009)] that makes use of the dipole approximation. The approximation is found to strongly affect the PA spectra because the photoassociated levels are weakly bound, and a similar impact is predicted to occur in other systems of a weakly bound nature. The inclusion or not of the approximation does not affect the resonance positions or widths, however significant differences are observed in the background of the spectra and the maximum laser intensity at which resonances are discernable. Couplings not satisfying the dipole selection rule |J-1| <= J' <= |J+1| do not lead to observable resonances.Comment: 5 pages, 2 figures; Minor textual revision

    Sintering Kinetics of Plasma-Sprayed Zirconia TBCs

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    A model of the sintering exhibited by EB-PVD TBCs, based on principles of free energy minimization, was recently published by Hutchinson et al. In the current paper, this approach is applied to sintering of plasma-sprayed TBCs and comparisons are made with experimental results. Predictions of through-thickness shrinkage and changing pore surface area are compared with experimental data obtained by dilatometry and BET analysis respectively. The sensitivity of the predictions to initial pore architecture and material properties are assessed. The model can be used to predict the evolution of contact area between overlying splats. This is in turn related to the through-thickness thermal conductivity, using a previously-developed analytical model

    Study of the general mechanism of stress corrosion of aluminum alloys and development of techniques for its detection Annual summary report, 2 Jun. 1967 - 1 Jun. 1968

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    Stress corrosion cracking of high strength aluminum alloys investigated by electrochemical, mechanical, and electron microscopic technique

    "Beat" patterns for the odd-even staggering in octupole bands from a quadrupole-octupole Hamiltonian

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    We propose a collective Hamiltonian which incorporates the standard quadrupole terms, octupole terms classified according to the irreducible representations of the octahedron group, a quadrupole-octupole interaction, as well as a term for the bandhead energy linear in K (the projection of angular momentum on the body-fixed z-axis). The energy is subsequently minimized with respect to K for each given value of the angular momentum I, resulting in K values increasing with I within each band, even in the case in which K is restricted to a set of microscopically plausible values. We demonstrate that this Hamiltonian is able to reproduce a variety of ``beat'' patterns observed recently for the odd-even staggering in octupole bands of light actinides.Comment: LaTeX, 20 pages plus 12 figures given in separate .ps file

    Role of the misfit stress between grains in the Bauschinger effect for a polycrystalline material

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    The role of misfit stress in kinematic hardening under reversed straining of a Type 316H austenitic stainless steel has been investigated by using neutron diffraction combined with in situ deformation. Initial misfit stresses, often referred to an intergranular internal stresses, were created by the tensile pre-straining at high temperature. The misfit stresses at the length-scale of grain families, measured by neutron diffraction, were shown to be a function of the magnitude of the tensile pre-strain. The pre-strained specimens were further subjected to either continued (tensile) straining or reversed (compressive) straining at room temperature. In situ neutron diffraction measurements were undertaken to monitor the change of the misfit stresses during loading. The macroscopic stress–strain behaviour was used to derive isotropic and kinematic hardening stresses developed in the pre-strained specimens. Results show that the change of the transient softening stress towards a zero value is accompanied by a decrease in the change of the misfit stresses. A multi-scale self-consistent model has been developed to assist in understanding the measured change of the misfit stresses when subjecting the material to strain reversal. An important conclusion is that the origin of the kinematic hardening of Type 316H austenitic stainless steel arises from the misfit stress between grains
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