3,635 research outputs found
Visualization of defect-induced excitonic properties of the edges and grain boundaries in synthesized monolayer molybdenum disulfide
Atomically thin two-dimensional (2D) transition metal dichalcogenides (TMDCs)
are attractive materials for next generation nanoscale optoelectronic
applications. Understanding nanoscale optical behavior of the edges and grain
boundaries of synthetically grown TMDCs is vital for optimizing their
optoelectronic properties. Elucidating the nanoscale optical properties of 2D
materials through far-field optical microscopy requires a diffraction-limited
optical beam diameter sub-micron in size. Here we present our experimental work
on spatial photoluminescence (PL) scanning of large size ( microns)
monolayer MoS grown by chemical vapor deposition (CVD) using a diffraction
limited blue laser beam spot (wavelength 405 nm) with a beam diameter as small
as 200 nm allowing us to probe nanoscale excitonic phenomena which was not
observed before. We have found several important features: (i) there exists a
sub-micron width strip ( nm) along the edges that fluoresces brighter than the region far inside; (ii) there is another brighter
wide region consisting of parallel fluorescing lines ending at the corners of
the zig-zag peripheral edges; (iii) there is a giant blue shifted A-excitonic
peak, as large as meV, in the PL spectra from the edges. Using
density functional theory calculations, we attribute this giant blue shift to
the adsorption of oxygen dimers at the edges, which reduces the excitonic
binding energy. Our results not only shed light on defect-induced excitonic
properties, but also offer an attractive route to tailor optical properties at
the TMDC edges through defect engineering.Comment: 10 pages, 4 figures in Journal of Physical Chemistry C, 201
Anti-Hyperon Enhancement through Baryon Junction Loops
The baryon junction exchange mechanism recently proposed to explain valence
baryon number transport in nuclear collisions is extended to study midrapidity
anti-hyperon production. Baryon junction-anti-junction (J anti-J) loops are
shown to enhance anti-Lambda, anti-Xi, anti-Omega yields as well as lead to
long range rapidity correlations. Results are compared to recent WA97 Pb + Pb
-> Y + anti-Y + X data.Comment: 10 pages, 4 figure
Metformin plus PIAF combination chemotherapy for hepatocellular carcinoma
Objectives: Metformin, the most used oral antidiabetic drug for the treatment of type 2 diabetus mellitus, has proved encouraging results when used in the treatment of various types of cancer such as triple-negative breast cancer. Despite compelling evidence of a role of metformin as an anticancer drug, the mechanisms by which metformin exerts its oncostatic actions are not fully understood yet. Therefore, we tried to bring new insights by analyzing the anti-neoplastic effect of metformin for hepatocellular carcinoma-derived stem-like cells treated with conventional combination chemotherapy. Methods: Cancer stem-like cells previusly isolated from a hepatocellular carcinoma biopsy were treated with metformin, PIAF chemotherapy regimen and the combination of these two protocols. Measurements of lipid peroxidation, reduced glutathione, fluorescein diacetate and proliferation rates were determined, apart from the autophagy assay and apoptosis determination by chip flow cytometry. Results: Metformin alone and especially metformin in association with PIAF increases oxidative stress within the cells by increasing the levels of lipid peroxids as well as decreasing the levels of reduced glutathione. The MTT cell proliferation assay showed decreased proliferation rates for the arm treated with metformin and with the combination of drugs in comparison with the control arm, proving high correlation with the oxidative stress results. The autophagy assay and determination of apoptosis by chip flow cytometry confirmed the results obtained in the previous assays. Conclusion: Metformin could be used in chemotherapy treatments to induce reactive oxygen species and increase the cytostatics effects within the tumor cell. Still, further experiments must be carried out on murine models before we can move on and use this drugs in the adjuvant setting for unresectable primary liver cancer
Thermal Conductivity and Thermal Rectification in Graphene Nanoribbons: a Molecular Dynamics Study
We have used molecular dynamics to calculate the thermal conductivity of
symmetric and asymmetric graphene nanoribbons (GNRs) of several nanometers in
size (up to ~4 nm wide and ~10 nm long). For symmetric nanoribbons, the
calculated thermal conductivity (e.g. ~2000 W/m-K @400K for a 1.5 nm {\times}
5.7 nm zigzag GNR) is on the similar order of magnitude of the experimentally
measured value for graphene. We have investigated the effects of edge chirality
and found that nanoribbons with zigzag edges have appreciably larger thermal
conductivity than nanoribbons with armchair edges. For asymmetric nanoribbons,
we have found significant thermal rectification. Among various
triangularly-shaped GNRs we investigated, the GNR with armchair bottom edge and
a vertex angle of 30{\deg} gives the maximal thermal rectification. We also
studied the effect of defects and found that vacancies and edge roughness in
the nanoribbons can significantly decrease the thermal conductivity. However,
substantial thermal rectification is observed even in the presence of edge
roughness.Comment: 13 pages, 5 figures, slightly expanded from the published version on
Nano Lett. with some additional note
Baryon Junction Loops in HIJING/B\=Bv2.0 and the Baryon/Meson Anomaly at RHIC
A new version, v2.0, of the HIJING/B\=B Monte Carlo nuclear collision event
generator is introduced in order to explore further the possible role of baryon
junctions loops in the baryon/meson anomaly (2 5 GeV/c) observed in
200A GeV Au+Au reactions at RHIC. We show that junction loops with an enhanced
intrinsic GeV/c transverse momentum kick may provide a partial
explanation of the anomaly as well as other important baryon stopping
observables.Comment: 27 pages, Latex(revtex), 8 figure
Development of the Tilburg Pregnancy Distress Scale: the TPDS
Contains fulltext :
96807.pdf (publisher's version ) (Open Access)ABSTRACT: BACKGROUND: Pregnant women with high levels of stress, depression and/or anxiety are at increased risk for adverse perinatal outcomes and impaired neurologic and emotional development of the offspring. Pregnancy specific instruments to measure psychological functioning during gestation are scarce and do not define items based on in-depth interviews of pregnant and recently delivered women. The current study developed a pregnancy specific scale that measures psychological functioning using in-depth interviews. METHODS: Three focus groups were formed to discuss issues most relevant to pregnancy distress; 22 candidate items were derived for pilot testing (study I, n = 419) its psychometric properties by means of explorative factor analyses (EFA). This resulted in a 17-item TPDS which was further explored by confirmatory factor analyses (CFA) and concurrent and construct validity assessment (study II, n = 454). RESULTS: EFA in study I suggested a two component solution (negative affect (NA) and partner involvement (PI)). CFA in study II resulted in a higher order model of the NA subscale into three more subscales: NA regarding confinement, delivery and general health. TPDS, EPDS and GAD-7 were all significantly correlated. CONCLUSIONS: The TPDS constitutes a valid and user friendly instrument to assess pregnancy distress. In addition to its proven ability to pick up pregnancy specific negative affect it also includes an important sub-scale measuring perceived partner involvement
Do Search for Dibaryonic De - Excitations in Relativistic Nuclear Reactions
Some odd characteristics are observed in the single particle distributions
obtained from interactions at momenta which are
explained as the manifestation of a new mechanism of strangeness production via
dibaryonic de-excitations. A signature of the formation of hadronic and
baryonic clusters is also reported. The di-pionic signals of the dibaryonic
orbital de-excitations are analyzed in the frame of the MIT - bag Model and a
Monte Carlo simulation.The role played by the dibaryonic resonances in
relativistic nuclear collisions could be a significant one.
Key words: Relativistic nuclear interactions negative pions, negative kaons,
di-pions , streamer chamber, dibaryons, MIT - bag model
PACS codes: 25.75.+r,14.40.Aq,14.20.Pt,12.40.AsComment: 17 pages,LATEX, preprint ICTP -243 1993,figures available by reques
Kinematical coincidence method in transfer reactions
A new method to extract high resolution angular distributions from
kinematical coincidence measurements in binary reactions is presented.
Kinematic is used to extract the center of mass angular distribution from the
measured energy spectrum of light particles. Results obtained in the case of
10Be+p-->9Be+d reaction measured with the CHIMERA detector are shown. An
angular resolution of few degrees in the center of mass is obtained.Comment: 6 Page 10 Figures submitted to Nuclear Instruments and Methods
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