Spin polarization of Auger- and of photoelectrons from barium atoms exposed to circularly polarized radiation and their cross comparison

Kuntze R, Salzmann M, Böwering N, Heinzmann U. Spin polarization of Auger- and of photoelectrons from barium atoms exposed to circularly polarized radiation and their cross comparison. Zeitschrift für Physik D: Atoms, Molecules and Clusters. 1994;30(2-3):235-237.New results of spin polarization of both photoelectrons and Auger electrons are reported after 5[Rho] photoionization of free Ba atoms with circularly polarized light. A substantial polarization transfer from the spin polarized photons to the spin polarized photoelectrons and via the hole state orientation to the spin polarized Auger-electrons is observed. The cross comparison of the results for photoelectrons and Auger-electrons allows a quantitative test of the assumed two step model where both electron-emission processes occur in sequence

Angle- and spin-resolved photoelectron spectroscopy in the region of the 6s6p(2) autoionisation of Tl

Müller M, Böwering N, Svensson A, Heinzmann U. Angle- and spin-resolved photoelectron spectroscopy in the region of the 6s6p(2) autoionisation of Tl. Journal of Physics B: Atomic, Molecular and Optical Physics. 1990;23(13):2267S-2275S.An angle-, energy- and spin-resolved photoionisation experiment was performed in the region of the 6s6p(2)autoionisation resonances of thallium. Using monochromatic circularly polarised synchrotron radiation the energy dependence of the spin-polarisation parameters A, xi and alpha and the angular asymmetry parameter beta of the differential cross section were determined. In the wavelength region investigated these dynamical parameters show a pronounced variation which agrees well with the results of the random phase approximation with exchange' calculation by Cherepkov (1980). A detailed discussion of the resonance behaviour for the autoionising states is given in terms of dipole-matrix elements and phaseshift differences which are extracted from the experimental data

Photoelectron spin polarization approaching unity: photoionization of TI

Böwering N, Salzmann M, Müller M, Klausing H-W, Heinzmann U. Photoelectron spin polarization approaching unity: photoionization of TI. Physica Scripta. 1990;41(4):429-432.It is shown that a complete photoelectron-spin polarization occurs independent of emission angle for two special sets of values of the dynamical photoionization parameters. In spin- and angle-resolved photoelectron spectroscopy of thallium the dynamical parameters were measured near the autoionization resonances at 149 nm and 82 nm. A pronounced angular variation of the polarization component A[Theta] was observed at 83 nm. For both resonances the parameters were found to approach different limiting values such that the length of the spin-polarization vector assumes values close to unity at all emission angles. The implications of these results for the corresponding dipole transition matrix elements are discussed

Orientation dependence of the sticking probability of NO at Ni(100)

Fecher GH, Volkmer M, Pawlitzky B, Böwering N, Heinzmann U. Orientation dependence of the sticking probability of NO at Ni(100). Vacuum. 1990;41(1-3):265-268

Influence of autoionisation and predissociation on the photoelectron parameters in HBr

Lefebvre-Brion H, Salzmann M, Klausing H-W, Müller M, Böwering N, Heinzmann U. Influence of autoionisation and predissociation on the photoelectron parameters in HBr. Journal of Physics B: Atomic, Molecular and Optical Physics. 1989;22(23):3891-3900

Vibrationally induced inversion of photoelectron forward-backward asymmetry in chiral molecule photoionization by circularly polarized light

Electron–nuclei coupling accompanying excitation and relaxation processes is a fascinating phenomenon in molecular dynamics. A striking and unexpected example of such coupling is presented here in the context of photoelectron circular dichroism measurements on randomly oriented, chiral methyloxirane molecules, unaffected by any continuum resonance. Here, we report that the forward-backward asymmetry in the electron angular distribution, with respect to the photon axis, which is associated with photoelectron circular dichroism can surprisingly reverse direction according to the ion vibrational mode excited. This vibrational dependence represents a clear breakdown of the usual Franck–Condon assumption, ascribed to the enhanced sensitivity of photoelectron circular dichroism (compared with other observables like cross-sections or the conventional anisotropy parameter-β) to the scattering phase off the chiral molecular potential, inducing a dependence on the nuclear geometry sampled in the photoionization process. Important consequences for the interpretation of such dichroism measurements within analytical contexts are discussed

Multimass thermal desorption spectroscopy as a monitoring device for chemical reaction products

Zagatta G, Müller H, Böwering N, Heinzmann U. Multimass thermal desorption spectroscopy as a monitoring device for chemical reaction products. Review of Scientific Instruments. 1994;65(2):359-362.To observe the products of surface reaction mechanisms we combined a standard quadrupole mass spectrometer featuring high-speed scanning options with fast data acquisition and a computer-controlled sample heating system. This combination served to obtain a general view (like a 'fingerprint') of the reaction occurring on a Pt(100) crystal upon heating the adsorbate covered surface, as well as to allow for a detailed analysis of the gas compounds leaving the surface within a single measurement. The method is denoted by multimass thermal desorption spectroscopy (MTDS). The MTDS device is capable of recording 850 amu/s providing up to 15 complete mass spectra per second of 50 amu width while heating the surface linearly. The data contain the ion currents of both the reaction products and their fractions (cracking patterns) generated in the spectrometer. Thus it is possible to distinguish between gas species with equal mass numbers by subsequent numerical evaluation

Observation of vibrational excitation in photoelectron spectroscopy of HI+2[Pi]

Böwering N, Klausing H-W, Müller M, Salzmann M, Heinzmann U. Observation of vibrational excitation in photoelectron spectroscopy of HI+2[Pi]. Chemical Physics Letters. 1992;189(4-5):467-472