74 research outputs found

    Bromoform concentrations in slush-layer water in Antarctic fast ice

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    学生による企画展の報告「写真で見る前身校PartⅡ~キンダイ医学の源流を辿る~」

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    In this article, we look back on the studentʼs exhibition “Kanazawa Universityʼs Former Schools seen in the photos, Part II : Tracing the origins of modern medicine,” at Kanazawa University (9/11/2020-20/01/2021) and it will be evaluated by the students who actuary participated in this exhibition program. Kawai and Matsunaga introduce this article, presenting the background of the special exhibition by the students at Kanazawa University as a part of the class “Museum Training” and the overview of the class schedule. Furuta discusses Chapter 2, 4, 5, 6, while Ooki discusses Chapter 3. In Chapter 2, Furuta explains the idea of this exhibition, and provides selection and research of the materials in Chapter 3, focuses on the display of the exhibition in Chapter 4, describes on the exhibition devices in Chapter 5, discuses related events in Chapter 6. Finally, Matsunaga, who is another instructor of the class and a curator of Kanazawa University Museum, considers this significance of the special exhibition conducted by the students in the University Museum

    Transport of trace metals (Mn, Fe, Ni, Zn and Cd) in the western Arctic Ocean (Chukchi Sea and Canada Basin) in late summer 2012

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    Distributions of trace metals (Mn, Fe, Ni, Zn and Cd) in the western Arctic Ocean (Chukchi Sea and Canada Basin) in September 2012 were investigated to elucidate the mechanisms behind the transport of these metals from the Chukchi Shelf to the Canada Basin. Filtered (<0.22 μm) and unfiltered seawater samples were analyzed to determine dissolved (D) and total dissolvable (TD) trace metal concentrations, respectively. We identified maxima in vertical profiles for the concentrations of D-Fe and TD-Fe, as well as for the other four analyzed trace metals, which occurred in the halocline and/or near-bottom waters. Concentration profiles of all trace metals except for Cd also tended to show peaks near the surface, which suggest that the inflow of low-salinity Pacific-origin water from the Bering Strait, as well as local fresh water inputs such as river water and melting sea-ice, influenced trace metal concentrations. The distribution patterns and concentration ranges were generally similar between the D and TD fractions for Ni, Zn and Cd, which indicate that Ni, Zn and Cd were present mainly in their dissolved forms, whereas the concentrations of TD-Fe and TD-Mn were generally higher than those of D-Fe and D-Mn, respectively. These results are consistent with the results of previous studies of this region. For both Fe and Mn, labile particulate (LP) concentrations (the difference between the TD and D fractions, which is acid-leachable fraction in the particles during storage at pH 1.5?1.6) were highest in the near-bottom waters of the Chukchi Shelf region. The relationships between the distance from the shelf break and the concentrations of trace metals revealed that Fe and Mn concentrations in halocline waters tended to decrease logarithmically with distance, whereas changes in the concentrations of Ni, Zn, Cd and phosphate with distance were small. These results suggest that the distributions of Fe and Mn were controlled mainly by input from shelf sediment and removal through scavenging processes. Based on the phase distributions of Fe and Mn, which were calculated as ratios between the LP and D fractions, different behaviors between Fe and Mn were expressed during lateral transportation. The concentration of TD-Fe declined rapidly via removal of LP-Fe from the water column, whereas the concentration of TD-Mn declined more slowly through the transformation of D-Mn into LP-Mn. In contrast, the concentrations of D-Cd, D-Zn and D-Ni were more strongly correlated with phosphate levels, which suggest that, like phosphate, the distributions of Cd, Zn and Ni were generally controlled by the internal biogeochemical cycles of the ocean interior. Based on the findings of studies that have previously evaluated the concentration maxima of Ni, Zn and Cd within the halocline layer in the Canada Basin near the Canadian Arctic Archipelago, the elevated Ni, Zn and Cd concentrations in the halocline layer may extend across the Canada Basin from the Chukchi Sea shelf-break area. The determination coefficients for correlations with phosphate concentration varied between the concentrations of Ni, Zn and Cd, which suggest that the sources of these trace metals, such as sediments and sea-ice melting, affected their patterns of distributions differently. Our findings reveal the importance and impact of the halocline layer for the transport of trace metals in the western Arctic Ocean during the late summer. The existence of rich and various sources likely sustained the high concentrations of trace metals and their unique profiles in this region

    Size-resolved sulfate and ammonium measurements in marine boundary layer over the North and South Pacific

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    Marine background levels of non-sea-salt- (nss-) SO42− (5.0–9.7 neq m−3), NH4+ (2.1–4.4 neq m−3) and elemental carbon (EC) (40–80 ngC m−3) in aerosol samples were measured over the equatorial and South Pacific during a cruise by the R/V Hakuho-maru from November 2001 to March 2002. High concentrations of nss-SO42− (47–94 neq m−3), NH4+ (35–94 neq m−3) and EC (130–460 ngC m−3) were found in the western North Pacific near the coast of the Asian continent under the influence of the Asian winter monsoon. Particle size distributions of ionic components showed that the equivalent concentrations of nss-SO42− were balanced with those of NH4+ in the size range of 0.060.22 μm were decreased with increase in particle size. We estimated the source contributions of those aerosol components in the marine background air over the equatorial and South Pacific. Biomass burning accounted for the large fraction (80–98% in weight) of EC and the minor fraction (2–4% in weight) of nss-SO42−. Marine biogenic source accounted for several tens percents of NH4+ and nss-SO42−. In the accumulation mode, 70% of particle number existed in the size range of 0.1<D<0.2 μm. In the size rage of 0.06<D<0.22 μm, the dominant aerosol component of (NH4)2SO4 would be mainly derived from the marine biogenic sources

    Bromoform concentrations in slush-layer water in Antarctic fast ice

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    Bromoform concentrations in water of the slush layer that developed at the interface between snow and sea ice were measured during the seasonal warming in Lützow-Holm Bay, East Antarctica. Mean bromoform concentration was 5.5 ± 2.4 pmol l-1, which was lower than that of the under-ice water (10.9 ± 3.5 pmol l-1). Temporal decrease in bromoform concentrations and salinity with increasing temperature of the slush water suggest that the bromoform concentrations were reduced through dilution with meltwater input from the upper surface of sea ice. In contrast, bromoform concentrations in the under-ice water increased during this period while the salinity of the under-ice water decreased. It is speculated that the sea ice meltwater input contained high bromoform concentrations from the brine channels within the sea ice and from the bottom of the ice that were contributed to the increased bromoform concentrations in the under-ice water

    A global-scale map of isoprene and volatile organic iodine in surface seawater of the Arctic, Northwest Pacific, Indian, and Southern Oceans

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    Isoprene (C5H8) and three volatile organic iodine compounds (VOIs: CH3I, C2H5I, and CH2ClI) in surface seawater were measured in the western Arctic, Northwest Pacific, Indian, and Southern Oceans during the period 2008-2012. These compounds are believed to play an important role in the marine atmospheric chemistry after their emission. The measurements were performed with high time-resolution (1-6 h intervals) using an online equilibrator gas chromatography mass spectrometer. C5H8 was most abundant in high-productivity transitional waters and eutrophic tropical waters. The chlorophyll-a normalized production rates of C5H8 were high in the warm subtropical and tropical waters, suggesting the existence of a high emitter of C5H8 in the biological community of the warm waters. High concentrations of the three VOIs in highly productive transitional water were attributed to biological productions. For CH3I, the highest concentrations were widely distributed in the basin area of the oligotrophic subtropical NW Pacific, probably due to photochemical production and/or high emission rates from phytoplankton. In contrast, the lowest concentrations of C2H5I in subtropical waters were attributed to photochemical removal. Enhancement of CH2ClI concentrations in the shelf-slope areas of the Chukchi Sea and the transitional waters of the NW Pacific in winter suggested that vertical mixing with subsurface waters by regional upwelling or winter cooling acts to increase the CH2ClI concentrations in surface layer. Sea-air flux calculations revealed that the fluxes of CH2ClI were the highest among the three VOIs in shelf-slope areas; the CH3I flux was highest in basin areas

    Production of Dibromomethane and Changes in the Bacterial Community in Bromoform-Enriched Seawater

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    The responses of bacterial communities to halocarbon were examined using a 28-d incubation of bromoform- and methanol-enriched subarctic surface seawater. Significant increases were observed in dibromomethane concentrations and bacterial 16S rRNA gene copy numbers in the treated substrates incubated for 13 d. The accumulated bacterial community was investigated by denaturing gradient gel electrophoresis and amplicon analyses. The dominant genotypes corresponded to the genera Roseobacter, Lentibacter, and Antylibacter; the family Flavobacteriaceae; and the phylum Planctomycetes, including methylotrophs of the genus Methylophaga and the family Methylophilaceae. Therefore, various phylotypes responded along with the dehalogenation processes in subarctic seawater

    Sediment-Associated Phytoplankton Release From the Seafloor in Response to Wind-Induced Barotropic Currents in the Bering Strait

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    Bering Strait is the single gateway between the Arctic and Pacific Oceans, and has localized strong currents, which can exceed 100 cm s^-1. Although massive spring phytoplankton blooms and the subsequent production of particulate organic matter that sinks to the seafloor are observed in the surrounding regions of the Bering Strait, the impact of the locally strong current on the horizontal and vertical transport of the particles remains unclear. Therefore, we conducted year-round mooring measurements from 2016 to 2017 by focusing on near-bottom processes associated with ocean currents. Our time-series analysis showed that high-turbidity events, triggered by strong barotropic currents, occurred near the seafloor in all seasons. Consequently, the fluorescence sensor detected highly concentrated chlorophyll a in the resuspended sediment; however, the amount of chlorophyll a release was seasonal, with large and small amounts being released during the warm and cold seasons, respectively. The small amounts of chlorophyll a may be attributed to small amounts of phytoplankton in the sediment owing to less input of fresh phytoplankton from the overlaying water column and organic matter decomposition in the sediments under no-light conditions. The barotropic currents were modulated by surface winds associated with an intercontinental atmospheric pattern having a 5000-km spatial scale on a timescale of 6 days. The locally strong ocean current in the Bering Strait, driving the upward transport of sediment and the subsequent horizontal transport, may play a vital role in supplying particulate organic matter/phytoplankton/nutrients to the downstream region of the southern Chukchi Sea where the formation of biological hotspots is reported
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