Uranium(III) coordination chemistry and oxidation in a flexible small-cavity macrocycle

U(III) complexes of the conformationally flexible, small-cavity macrocycle trans-calix[2]benzene[2]pyrrolide (L)2–, [U(L)X] (X = O-2,6-tBu2C6H3, N(SiMe3)2), have been synthesized from [U(L)BH4] and structurally characterized. These complexes show binding of the U(III) center in the bis(arene) pocket of the macrocycle, which flexes to accommodate the increase in the steric bulk of X, resulting in long U–X bonds to the ancillary ligands. Oxidation to the cationic U(IV) complex [U(L)X][B(C6F5)4] (X = BH4) results in ligand rearrangement to bind the smaller, harder cation in the bis(pyrrolide) pocket, in a conformation that has not been previously observed for (L)2–, with X located between the two ligand arene rings

Collective modes of an Anisotropic Quark-Gluon Plasma II

We continue our exploration of the collective modes of an anisotropic quark gluon plasma by extending our previous analysis to arbitrary Riemann sheets. We demonstrate that in the presence of momentum-space anisotropies in the parton distribution functions there are new relevant singularities on the neighboring unphysical sheets. We then show that for sufficiently strong anisotropies that these singularities move into the region of spacelike momentum and their effect can extend down to the physical sheet. In order to demonstrate this explicitly we consider the polarization tensor for gluons propagating parallel to the anisotropy direction. We derive analytic expressions for the gluon structure functions in this case and then analytically continue them to unphysical Riemann sheets. Using the resulting analytic continuations we numerically determine the position of the unphysical singularities. We then show that in the limit of infinite contraction of the distribution function along the anisotropy direction that the unphysical singularities move onto the physical sheet and result in real spacelike modes at large momenta for all "out-of-plane" angles of propagation.Comment: 13 pages, 8 figure

Dynamics of Quark-Gluon-Plasma Instabilities in Discretized Hard-Loop Approximation

Non-Abelian plasma instabilities have been proposed as a possible explanation for fast isotropization of the quark-gluon plasma produced in relativistic heavy-ion collisions. We study the real-time evolution of these instabilities in non-Abelian plasmas with a momentum-space anisotropy using a hard-loop effective theory that is discretized in the velocities of hard particles. We extend our previous results on the evolution of the most unstable modes, which are constant in directions transverse to the direction of anisotropy, from gauge group SU(2) to SU(3). We also present first full 3+1-dimensional simulation results based on velocity-discretized hard loops. In contrast to the effectively 1+1-dimensional transversely constant modes we find subexponential behaviour at late times.Comment: 30 pages, 16 figures. v3 typos fixe

Criteria for strong and weak random attractors

The theory of random attractors has different notions of attraction, amongst them pullback attraction and weak attraction. We investigate necessary and sufficient conditions for the existence of pullback attractors as well as of weak attractors

Jet quenching in shock waves

We study the propagation of an ultrarelativistic light quark jet inside a shock wave using the holographic principle. The maximum stopping distance and its dependency on the energy of the jet is obtained

An Enhanced Archive Facilitating Climate Impacts and Adaptation Analysis

We describe the expansion of a publicly available archive of downscaled climate and hydrology projections for the United States. Those studying or planning to adapt to future climate impacts demand downscaled climate model output for local or regional use. The archive we describe attempts to fulfill this need by providing data in several formats, selectable to meet user needs. Our archive has served as a resource for climate impacts modelers, water managers, educators, and others. Over 1,400 individuals have transferred more than 50 TB of data from the archive. In response to user demands, the archive has expanded from monthly downscaled data to include daily data to facilitate investigations of phenomena sensitive to daily to monthly temperature and precipitation, including extremes in these quantities. New developments include downscaled output from the new Coupled Model Intercomparison Project phase 5 (CMIP5) climate model simulations at both the monthly and daily time scales, as well as simulations of surface hydrologi- cal variables. The web interface allows the extraction of individual projections or ensemble statistics for user-defined regions, promoting the rapid assessment of model consensus and uncertainty for future projections of precipitation, temperature, and hydrology. The archive is accessible online (http://gdo-dcp.ucllnl.org/downscaled_ cmip_projections)

Thermalization and the chromo-Weibel instability

Despite the apparent success of ideal hydrodynamics in describing the elliptic flow data which have been produced at Brookhaven National Lab's Relativistic Heavy Ion Collider, one lingering question remains: is the use of ideal hydrodynamics at times t < 1 fm/c justified? In order to justify its use a method for rapidly producing isotropic thermal matter at RHIC energies is required. One of the chief obstacles to early isotropization/thermalization is the rapid longitudinal expansion of the matter during the earliest times after the initial nuclear impact. As a result of this expansion the parton distribution functions become locally anisotropic in momentum space. In contrast to locally isotropic plasmas anisotropic plasmas have a spectrum of soft unstable modes which are characterized by exponential growth of transverse chromo-magnetic/-electric fields at short times. This instability is the QCD analogue of the Weibel instability of QED. Parametrically the chromo-Weibel instability provides the fastest method for generation of soft background fields and dominates the short-time dynamics of the system.Comment: 8 pages, 4 figures, Invited plenary talk given at the 19th International Conference on Ultrarelativistic Nucleus-Nucleus Collisions: Quark Matter 2006 (QM 2006), Shanghai, China, 14-20 Nov 200

Valley Bifurcation in an O(3)O(3) σ\sigma Model: Implications for High-Energy Baryon Number Violation

The valley method for computing the total high-energy anomalous cross section $S_{anom}$ is the extension of the optical theorem to the case of instanton-antiinstanton backgrounds. As a toy model for baryon number violation in Electroweak theory, we consider a version of the $O(3)$ $\sigma$ model in which the conformal invariance is broken perturbatively. We show that at a critical energy the saddle-point values of the instanton size and instanton-antiinstanton separation bifurcate into complex conjugate pairs. This nonanalytic behavior signals the breakdown of the valley method at an energy where $S_{anom}$ is still exponentially suppressed. (Figures replaced 5/3/93).Comment: (14 pages, Los Alamos Preprint LA-UR-93-811). 3 uuencoded figures include

QGP collective effects and jet transport

We present numerical simulations of the SU(2) Boltzmann-Vlasov equation including both hard elastic particle collisions and soft interactions mediated by classical Yang-Mills fields. We provide an estimate of the coupling of jets to a hot isotropic plasma, which is independent of infrared cutoffs. In addition, we investigate jet propagation in anisotropic plasmas, as created in heavy-ion collisions. The broadening of jets is found to be stronger along the beam line than in azimuth due to the creation of field configurations with B_t>E_t and E_z>B_z via plasma instabilities.Comment: 4 pages, 5 figures. Presented at the 20th International Conference on Ultra-Relativistic Nucleus-Nucleus Collisions: Quark Matter 2008 (QM2008), Jaipur, India, 4-10 Feb 200