Organic Haze as a Biosignature in Anoxic Earth-like Atmospheres

Early Earth may have hosted a biologically-mediated global organic haze during the Archean eon (3.8-2.5 billion years ago). This haze would have significantly impacted multiple aspects of our planet, including its potential for habitability and its spectral appearance. Here, we model worlds with Archean-like levels of carbon dioxide orbiting the ancient sun and an M4V dwarf (GJ 876) and show that organic haze formation requires methane fluxes consistent with estimated Earth-like biological production rates. On planets with high fluxes of biogenic organic sulfur gases (CS2, OCS, CH3SH, and CH3SCH3), photochemistry involving these gases can drive haze formation at lower CH4/CO2 ratios than methane photochemistry alone. For a planet orbiting the sun, at 30x the modern organic sulfur gas flux, haze forms at a CH4/CO2 ratio 20% lower than at 1x the modern organic sulfur flux. For a planet orbiting the M4V star, the impact of organic sulfur gases is more pronounced: at 1x the modern Earth organic sulfur flux, a substantial haze forms at CH4/CO2 ~ 0.2, but at 30x the organic sulfur flux, the CH4/CO2 ratio needed to form haze decreases by a full order of magnitude. Detection of haze at an anomalously low CH4/CO2 ratio could suggest the influence of these biogenic sulfur gases, and therefore imply biological activity on an exoplanet. When these organic sulfur gases are not readily detectable in the spectrum of an Earth-like exoplanet, the thick organic haze they can help produce creates a very strong absorption feature at UV-blue wavelengths detectable in reflected light at a spectral resolution as low as 10. In direct imaging, constraining CH4 and CO2 concentrations will require higher spectral resolution, and R > 170 is needed to accurately resolve the structure of the CO2 feature at 1.57 {\mu}m, likely, the most accessible CO2 feature on an Archean-like exoplanet.Comment: accepted for publication in Astrobiolog

Investigating the negative fan behaviors of a branded collegiate basketball student section

Branded collegiate student sections (e.g., the Cameron Crazies at Duke University) have been identified as the most committed supporters of the team. The marketing benefits of these groups have been documented yet the potential negative consequences have gone unexplored in the literature. This study aimed to understand what types of behavior fans in this context engaged in, why they engaged in these actions, and attempts to link some of these observations to relevant theory on fan violence. A multiple method design was employed in order to obtain both breadth and depth of the phenomenon as well as for data triangulation. Ten members of a large, collegiate basketball fan group participated in in-depth, semi-structured interviews and extensive fieldwork of the fan group was conducted over the course of a season. Finally, 197 members of the same college basketball fan group responded to a survey questionnaire. The results of this study indicated there are negative consequences linked to the behavior of members of the branded student section. University officials should be aware of the potential danger of these branded student sections and strengthen relations and authority over these groups to minimize the likelihood of negative fan behavior

Going green: paperless technology and feedback from the classroom

The purpose of this study is to measure the following: student satisfaction with the paperless classroom; student satisfaction with paperless feedback; and costs savings as a result of the paperless classroom. Traditionally, software courses are paper-intensive because of the large amount of assignments being submitted for grading by students. In an effort to “go green,” this study is proposing the electronic submission of software assignments and electronic feedback by instructors using Blackboard’s virtual hard drive and USB flash drives. The response from students on their satisfaction with electronic submission and feedback of assignments was overwhelmingly positive. The study also resulted in a 48% cost savings on paper and toner

Juror Information on the Web: A Study of Hispanic Populated Texas Counties

In response to the initiative of providing juror education materials online, this study proposes that unless Web sites are designed in a usable fashion, this initiative could fail to enhance jury response and further aggravate the problem of underrepresentation by minorities. This study suggests that all online juror information Web sites be analyzed for “usability” and “design” if they are to be an effective education tool. In addition, this study proposes to compare responses to county Web sites in order to gauge bias responses of participants to their own county’s Web site vs. other county Web sites

Lessons Learned from Radiative Transfer Simulations of the Venus Atmosphere

The Venus atmosphere is extremely complex, and because of this the spectrum of Earths sister planet is likewise intricate and a challenge to model accurately. However, accurate modeling of Venus spectrum opens up multiple opportunities to better understand the planet next door, and even for understanding Venus-like planets beyond our solar system. Near-infrared (1-2.5 um, NIR) spectral windows observable on the Venus nigthside present the opportunity to probe beneath the Venusian cloud deck and measure thermal emission from the surface and lower atmosphere remotely from Earth or from orbit. These nigthside spectral windows were discovered by Allen and Crawford (1984) and have since been used measure trace gas abundances in the Venus lower atmosphere (less than 45 km), map surface emissivity varisions, and measure properties of the lower cloud deck. These windows sample radiation from below the cloud base at roughly 45 km, and pressures in this region range from roughly Earthlike (approx. 1 bar) up to 90 bars at the surface. Temperatures in this region are high: they range from about 400 K at the base of the cloud deck up to about 740 K at the surface. This high temperature and pressure presents several challenges to modelers attempting radiative transfer simulations of this region of the atmosphere, which we will review. Venus is also important to spectrally model to predict the remote observables of Venus-like exoplanets in anticipation of data from future observatories. Venus-like planets are likely one of the most common types of terrestrial planets and so simulations of them are valuable for planning observatory and detector properties of future telescopes being designed, as well as predicting the types of observations required to characterize them

Identifying Planetary Biosignature Impostors: Spectral Features of CO and O4 Resulting from Abiotic O2/O3 Production

O2 and O3 have been long considered the most robust individual biosignature gases in a planetary atmosphere, yet multiple mechanisms that may produce them in the absence of life have been described. However, these abiotic planetary mechanisms modify the environment in potentially identifiable ways. Here we briefly discuss two of the most detectable spectral discriminants for abiotic O2/O3: CO and O4. We produce the first explicit self-consistent simulations of these spectral discriminants as they may be seen by JWST. If JWST-NIRISS and/or NIRSpec observe CO (2.35, 4.6 um) in conjunction with CO2 (1.6, 2.0, 4.3 um) in the transmission spectrum of a terrestrial planet it could indicate robust CO2 photolysis and suggest that a future detection of O2 or O3 might not be biogenic. Strong O4 bands seen in transmission at 1.06 and 1.27 um could be diagnostic of a post-runaway O2-dominated atmosphere from massive H-escape. We find that for these false positive scenarios, CO at 2.35 um, CO2 at 2.0 and 4.3 um, and O4 at 1.27 um are all stronger features in transmission than O2/O3 and could be detected with SNRs $\gtrsim$ 3 for an Earth-size planet orbiting a nearby M dwarf star with as few as 10 transits, assuming photon-limited noise. O4 bands could also be sought in UV/VIS/NIR reflected light (at 0.345, 0.36, 0.38, 0.445, 0.475, 0.53, 0.57, 0.63, 1.06, and 1.27 um) by a next generation direct-imaging telescope such as LUVOIR/HDST or HabEx and would indicate an oxygen atmosphere too massive to be biologically produced.Comment: 7 pages, 4 figures, accepted to the Astrophysical Journal Letter

Finding the Needles in the Haystacks: High-Fidelity Models of the Modern and Archean Solar System for Simulating Exoplanet Observations

We present two state-of-the-art models of the solar system, one corresponding to the present day and one to the Archean Eon 3.5 billion years ago. Each model contains spatial and spectral information for the star, the planets, and the interplanetary dust, extending to 50 AU from the sun and covering the wavelength range 0.3 to 2.5 micron. In addition, we created a spectral image cube representative of the astronomical backgrounds that will be seen behind deep observations of extrasolar planetary systems, including galaxies and Milky Way stars. These models are intended as inputs to high-fidelity simulations of direct observations of exoplanetary systems using telescopes equipped with high-contrast capability. They will help improve the realism of observation and instrument parameters that are required inputs to statistical observatory yield calculations, as well as guide development of post-processing algorithms for telescopes capable of directly imaging Earth-like planets.Comment: Accepted for publication in PAS