Sinkholes in hypogene versus epigene karst systems, illustrated with the hypogene gypsum karst of the Sant Miquel de Campmajor Valley, NE Spain

The Garrotxa-Banyoles artesian aquifer system in NE Spain includes zones with epigene and hypogene evaporite karst and sinkhole development. The sinkhole fields related to hypogene evaporite dissolution are associated with the discharge zones of the aquifer, where groundwater from a confined limestone rises traversing an overlying gypsum formation capped by thick marls. This work analyses the sinkhole field developed in the Sant Miquel de Campmajor Valley (SMCV), a discharge area of the aquifer, where a cartographic inventory including 94 sinkholes has been produced. Sinkholes in this hypogene gypsum karst are mainly large caprock-collapse sinkholes rooted in deep-seated cavities generated by interstratal hypogene karstification, as corroborated by an electrical resistivity imaging (ERI) survey. They show a non-clustered distribution within the sinkhole field and the variations in size and density across the area are mainly controlled by the thickness of the marl caprock. The magnitude and frequency relationships of the sinkholes can be modelled with a high goodness of fit with a log-normal function, like in other regions of the world. However, in this deep-seated hypogene system the depressions show much larger dimensions. Potential differences between the sinkholes developed in hypogene and epigene karst environments are discussed, including their distribution with respect to the groundwater flow system, their spatial patterns and dimensions

4D monitoring of active sinkholes with a Terrestrial Laser Scanner (TLS): A Case study in the evaporite karst of the Ebro Valley, NE Spain

This work explores, for the first time, the application of a Terrestrial Laser Scanner (TLS) and a comparison of point clouds in the 4D monitoring of active sinkholes. The approach is tested in three highly-active sinkholes related to the dissolution of salt-bearing evaporites overlain by unconsolidated alluvium. The sinkholes are located in urbanized areas and have caused severe damage to critical infrastructure (flood-control dike, a major highway). The 3D displacement models derived from the comparison of point clouds with exceptionally high spatial resolution allow complex spatial and temporal subsidence patterns within one of the sinkholes to be resolved. Detected changes in the subsidence activity (e.g., sinkhole expansion, translation of the maximum subsidence zone, development of incipient secondary collapses) are related to potential controlling factors such as floods, water table changes or remedial measures. In contrast, with detailed mapping and high-precision leveling, the displacement models, covering a relatively short time span of around 6 months, do not capture the subtle subsidence (< 0.6-1 cm) that affects the marginal zones of the sinkholes, precluding precise mapping of the edges of the subsidence areas. However, the performance of TLS can be adversely affected by some methodological limitations and local conditions: (1) limited accuracy in large investigation areas that require the acquisition of a high number of scans, increasing the registration error; (2) surface changes unrelated to sinkhole activity (e.g., vegetation, loose material); (3) traffic-related vibrations and wind blast that affect the stability of the scanner

Tracking Cats: Problems with Placing Feline Carnivores on δ18O, δD Isoscapes

Several felids are endangered and threatened by the illegal wildlife trade. Establishing geographic origin of tissues of endangered species is thus crucial for wildlife crime investigations and effective conservation strategies. As shown in other species, stable isotope analysis of hydrogen and oxygen in hair (δD(h), δ(18)O(h)) can be used as a tool for provenance determination. However, reliably predicting the spatial distribution of δD(h) and δ(18)O(h) requires confirmation from animal tissues of known origin and a detailed understanding of the isotopic routing of dietary nutrients into felid hair.We used coupled δD(h) and δ(18)O(h) measurements from the North American bobcat (Lynx rufus) and puma (Puma concolor) with precipitation-based assignment isoscapes to test the feasibility of isotopic geo-location of felidae. Hairs of felid and rabbit museum specimens from 75 sites across the United States and Canada were analyzed. Bobcat and puma lacked a significant correlation between H/O isotopes in hair and local waters, and also exhibited an isotopic decoupling of δ(18)O(h) and δD(h). Conversely, strong δD and δ(18)O coupling was found for key prey, eastern cottontail rabbit (Sylvilagus floridanus; hair) and white-tailed deer (Odocoileus virginianus; collagen, bone phosphate).Puma and bobcat hairs do not adhere to expected pattern of H and O isotopic variation predicted by precipitation isoscapes for North America. Thus, using bulk hair, felids cannot be placed on δ(18)O and δD isoscapes for use in forensic investigations. The effective application of isotopes to trace the provenance of feline carnivores is likely compromised by major controls of their diet, physiology and metabolism on hair δ(18)O and δD related to body water budgets. Controlled feeding experiments, combined with single amino acid isotope analysis of diets and hair, are needed to reveal mechanisms and physiological traits explaining why felid hair does not follow isotopic patterns demonstrated in many other taxa

Temperature dependence on the magnetic, morphological and structural properties of Fe3O4(111)/SrTiO3(111) thin films grown by PLD

Poster presented at the Trends in NanoTechnology, held in Fribourg (Switzerland) on September 5-9th, 2016