Predicción de la frescura del aceite de oliva virgen extra durante el almacenamiento mediante espectroscopía de fluorescencia

Virgin olive oil quality relates to flavor and unique health benefits. Some of these properties are at the most desirable level when the oil is just extracted, since it is not a product that improves with age. On the contrary, the concentrations of many compounds change during its shelf-life. These changes reveal the aging of the oil but do not necessarily mean decay in sensory properties, so in some cases an aged oil from healthy olives may be better qualified than a fresh one from olives affected by fermentation. The aim of this work is to analyze different methodologies proposed for assessing the quality of virgin olive oil with implications in freshness and aging of the oil, and to highlight the possibilities of rapid spectrofluorimetric techniques for assessing oil freshness by checking the evolution of pigments during storage. The observed change in the selected spectral features and mathematical modelling over time was compared with the accepted model for predicting the amount of pyropheophytin a, which is based on isokinetic studies. The best regression was obtained for 655 nm (adjustedR2 = 0.91) wavelength, which matches the distinctive band of pigments. The two mathematical models described in this study highlight the usefulness of pigments in the prediction of the shelf-life of extra virgin olive oil.La calidad del aceite de oliva virgen está relacionada con su flavor y sus beneficios únicos para la salud. Algunas de estas propiedades se encuentran en el nivel más deseable cuando el aceite está recién extraído, ya que no es un producto que mejore con el tiempo. Por el contrario, las concentraciones de muchos compuestos cambian a lo largo de la vida útil. Estos cambios revelan el envejecimiento del aceite, pero no implican necesariamente la alteración de las propiedades sensoriales, por lo que en algunos casos un aceite envejecido procedente de aceitunas sanas puede presentar mejor calidad que uno fresco procedente de aceitunas afectadas por procesos de fermentación. El objetivo de este trabajo es estudiar diferentes metodologías propuestas para evaluar la calidad del aceite de oliva virgen con implicaciones en la frescura y el envejecimiento del aceite, destacando las posibilidades de las rápidas técnicas espectrofluorométricas para evaluar la frescura del aceite verificando la evolución de los pigmentos durante el almacenamiento. El cambio observado en las características espectrales seleccionadas y su modelado matemático a lo largo del tiempo se comparó con el modelo aceptado para predecir la cantidad de pirofeofitina a, que se basa en estudios isocinéticos. Los dos modelos matemáticos descritos en este estudio pusieron de manifiesto la utilidad de los pigmentos en la predicción de la vida útil del aceite de oliva virgen extra. La mejor regresión se obtuvo para 655 nm (R2 -ajustado = 0,91), longitud de onda que coincide con la banda distintiva de pigmentos.Secretaría de Estado de Investigación, Desarrollo e Innovación de España-AGL2015-69320-

Predicción de la frescura del aceite de oliva virgen extra durante el almacenamiento mediante espectroscopía de fluorescencia

Virgin olive oil quality relates to flavor and unique health benefits. Some of these properties are at the most desirable level when the oil is just extracted, since it is not a product that improves with age. On the contrary, the concentrations of many compounds change during its shelf-life. These changes reveal the aging of the oil but do not necessarily mean decay in sensory properties, so in some cases an aged oil from healthy olives may be better qualified than a fresh one from olives affected by fermentation. The aim of this work is to analyze different methodologies proposed for assessing the quality of virgin olive oil with implications in freshness and aging of the oil, and to highlight the possibilities of rapid spectrofluorimetric techniques for assessing oil freshness by checking the evolution of pigments during storage. The observed change in the selected spectral features and mathematical modelling over time was compared with the accepted model for predicting the amount of pyropheophytin a, which is based on isokinetic studies. The best regression was obtained for 655 nm (adjustedR2 = 0.91) wavelength, which matches the distinctive band of pigments. The two mathematical models described in this study highlight the usefulness of pigments in the prediction of the shelf-life of extra virgin olive oil.La calidad del aceite de oliva virgen está relacionada con su flavor y sus beneficios únicos para la salud. Algunas de estas propiedades se encuentran en el nivel más deseable cuando el aceite está recién extraído, ya que no es un producto que mejore con el tiempo. Por el contrario, las concentraciones de muchos compuestos cambian a lo largo de la vida útil. Estos cambios revelan el envejecimiento del aceite, pero no implican necesariamente la alteración de las propiedades sensoriales, por lo que en algunos casos un aceite envejecido procedente de aceitunas sanas puede presentar mejor calidad que uno fresco procedente de aceitunas afectadas por procesos de fermentación. El objetivo de este trabajo es estudiar diferentes metodologías propuestas para evaluar la calidad del aceite de oliva virgen con implicaciones en la frescura y el envejecimiento del aceite, destacando las posibilidades de las rápidas técnicas espectrofluorométricas para evaluar la frescura del aceite verificando la evolución de los pigmentos durante el almacenamiento. El cambio observado en las características espectrales seleccionadas y su modelado matemático a lo largo del tiempo se comparó con el modelo aceptado para predecir la cantidad de pirofeofitina a, que se basa en estudios isocinéticos. Los dos modelos matemáticos descritos en este estudio pusieron de manifiesto la utilidad de los pigmentos en la predicción de la vida útil del aceite de oliva virgen extra. La mejor regresión se obtuvo para 655 nm (R2 -ajustado = 0,91), longitud de onda que coincide con la banda distintiva de pigmentos.Secretaría de Estado de Investigación, Desarrollo e Innovación de España-AGL2015-69320-

Detection of advanced persistent threat using machine-learning correlation analysis

As one of the most serious types of cyber attack, Advanced Persistent Threats (APT) have caused major concerns on a global scale. APT refers to a persistent, multi-stage attack with the intention to compromise the system and gain information from the targeted system, which has the potential to cause significant damage and substantial financial loss. The accurate detection and prediction of APT is an ongoing challenge. This work proposes a novel machine learning-based system entitled MLAPT, which can accurately and rapidly detect and predict APT attacks in a systematic way. The MLAPT runs through three main phases: (1) Threat detection, in which eight methods have been developed to detect different techniques used during the various APT steps. The implementation and validation of these methods with real traffic is a significant contribution to the current body of research; (2) Alert correlation, in which a correlation framework is designed to link the outputs of the detection methods, aims to identify alerts that could be related and belong to a single APT scenario; and (3) Attack prediction, in which a machine learning-based prediction module is proposed based on the correlation framework output, to be used by the network security team to determine the probability of the early alerts to develop a complete APT attack. MLAPT is experimentally evaluated and the presented sy

Spatially resolved LMC star formation history: I. Outside in evolution of the outer LMC disk

We study the evolution of three fields in the outer LMC disk Rgc=3.5-6.2 Kpc. Their star formation history indicates a stellar populations gradient such that younger stellar populations are more centrally concentrated. We identify two main star forming epochs, separated by a period of lower activity between ~7 and ~4 Gyr ago. Their relative importance varies from a similar amount of stars formed in the two epochs in the innermost field, to only 40% of the stars formed in the more recent epoch in the outermost field. The young star forming epoch continues to the present time in the innermost field, but lasted only till ~0.8 and 1.3 Gyr ago at Rgc=5.5 degrees and 7.1 degrees, respectively. This gradient is correlated with the measured HI column density and implies an outside-in quenching of the star formation, possibly related to a variation of the size of the HI disk. This could either result from gas depletion due to star formation or ram-pressure stripping, or from to the compression of the gas disk as ram-pressure from the Milky Way halo acted on the LMC interstellar medium. The latter two situations may have occurred when the LMC first approached the Milky Way.Comment: 15 pages, 13 figures, 4 tables. MNRAS, in pres

A state-of-the-art analysis of the dwarf irregular galaxy NGC 6822

We present a detailed photometric study of the dwarf irregular galaxy NGC 6822 aimed at investigating the properties of its stellar populations and, in particular, the presence of stellar radial gradients. Our goal is to analyse the stellar populations in six fields, which cover the whole bar of this dwarf galaxy. We derived the quantitative star formation history (SFH) of the six fields using the IAC method, involving IAC-pop/MinnIAC codes. The solutions we derived show an enhanced star formation rate (SFR) in Fields 1 and 3 during the past 500 Myr. The SFRs of the other fields are almost extinguished at very recent epochs and. We study the radial gradients of the SFR and consider the total mass converted into stars in two time intervals (between 0 and 0.5 Gyr ago and between 0.5 and 13.5 Gyr ago). We find that the scale lengths of the young and intermediate-to-old populations are perfectly compatible, with the exception of the young populations in Fields 1 and 3. The recent SF in these two fields is greater than in the other ones. This might be an indication that in these two fields we are sampling incipient spiral arms. Further evidence and new observations are required to prove this hypothesis. In addition, we derived the age-metallicity relations. As expected, the metallicity increases with time for all of the fields. We do not observe any radial gradient in the metallicity.Comment: 9 pages, 11 figures, Accepted to A&

Pyrene-functionalized Foldamer: Structural Impact and Recognition Properties supported by Donor-Acceptor Interactions

An electroactive and luminescent foldamer based on an oligopyridine biscarboxamide skeleton was synthesized and characterised. Its conformation in the solid state proved to be strongly affected by the peripheral pyrene units. The latter also endow the target derivative with recognition abilities toward electron-withdrawing molecules, which allow tuning of the spectroscopic properties of the foldamer