19 research outputs found
Tunable hysteresis effect for perovskite solar cells
Perovskite solar cells (PSCs) usually suffer from a hysteresis effect in current–voltage measurements,
which leads to an inaccurate estimation of the device e
fficiency. Although ion migration, charge trapping/
detrapping, and accumulation have been proposed as a b
asis for the hysteresis, the
origin of the hysteresis
has not been apparently unraveled. Herein we reporte
d a tunable hysteresis effect based uniquely on open-
circuit voltage variations in printable mesos
copic PSCs with a simplified triple-layer TiO
2
/ZrO
2
/carbon
architecture. The electrons are collected by the compact TiO
2
/mesoporous TiO
2
(c-TiO
2
/mp-TiO
2
)bilayer,
and the holes are collected by the carbon layer. By adj
usting the spray deposition cycles for the c-TiO
2
layer
andUV-ozonetreatment,weachievedhysteresis-norm
al, hysteresis-free, and hysteresis-inverted PSCs.
Such unique trends of tunable hysteresis are anal
yzed by considering the polarization of the TiO
2
/perovskite
interface, which can accumulate positive charges reversibly. Successfully tuning of the hysteresis effect
clarifies the critical importance of the c-TiO
2
/perovskite interface in controlling the hysteretic trends
observed, providing important insights towards the understanding of this rapidly developing photovoltaic
technology
Applications of Metal Oxide Charge Transport Layers in Perovskite Solar Cells
Metal oxide (MO) charge transport layers (CTLs) are widely used for fabricating highly efficient and stable perovskite solar cells (PSCs) due to their superior stability, material and preparation cost, light transmission, and charge selection. However, the complex surface states, unbalanced carrier mobility, and variable energy band structure determined by MOs can lead to additional interfacial charge recombination and transport losses within the device, which limit further improvements in device performance. Extensive research has been conducted to address these challenges. In this review, an overview of current popular MO‐CTLs and their preparation methods for PSCs are provided. Interface regulation strategies, such as passivating interface defects, modulating interface energy level alignment, and improving interface contact are also discussed, which can enhance the performance of PSCs. Meanwhile, the commonly used dopants and doping strategies for optimizing the charge transport properties of CTLs are also discussed
Improvement in Solid-State Dye Sensitized Solar Cells by <i>p</i>‑Type Doping with Lewis Acid SnCl<sub>4</sub>
The
Lewis acid SnCl<sub>4</sub> is employed as a <i>p</i>-type
dopant for 2,2′,7,7′-tetrakis(<i>N</i>,<i>N</i>-di-<i>p</i>-methoxyphenylamine)-9,9′-spirobifluorene
(spiro-OMeTAD) for the solution process in solid-state dye sensitized
solar cell. The UV–vis absorption spectra and time-resolved
photoluminescence (PL) spectra are used to investigate the doping
level of spiro-OMeTAD with a <i>p</i>-type dopant, indicating
the strong molecular acceptor of SnCl<sub>4</sub>. X-ray photoelectron
spectra (XPS) exhibiting close energy shifts of the Fermi level toward
HOMO are observed when adding Li salt or SnCl<sub>4</sub>. A significant
enhancement in fill factor of the photovoltaic devices, corresponding
to the power conversion efficiency, is observed when doping with SnCl<sub>4</sub>. This is attributed to the low charge transport resistance
of the hole transport film and high hole injection efficiency from
the hole transport material to the counter electrode
Challenges for commercializing perovskite solar cells
Perovskite solar cells (PSCs) have witnessed rapidly rising power conversion efficiencies, together with advances in stability and upscaling. Despite these advances, their limited stability and need to prove upscaling remain crucial hurdles on the path to commercialization. We summarize recent advances toward commercially viable PSCs and discuss challenges that remain. We expound the development of standardized protocols to distinguish intrinsic and extrinsic degradation factors in perovskites. We review accelerated aging tests in both cells and modules and discuss the prediction of lifetimes on the basis of degradation kinetics. Mature photovoltaic solutions, which have demonstrated excellent long-term stability in field applications, offer the perovskite community valuable insights into clearing the hurdles to commercialization
Enhanced perovskite electronic properties via A-site cation engineering
Organic-inorganic halide perovskites have emerged as excellent candidates for low-cost photovoltaics and optoelectronics. While the predominant recent trend in designing perovskites for efficient and stable solar cells has been to mix different A-site cations, the role of A-site cations is still limited to tune the lattice and bandgap of perovskites. Herein we compare the optoelectronic properties of acetamidinum (Ace) and guanidinium (Gua) mixed methylammonium lead iodide perovskites and shed a light on the hidden role of A-site cation on the carrier mobility of mixed-cation lead iodide perovskites. The cations do not affect the bandgap of the perovskites since the orbitals from Ace and Gua do not contribute to the band edges of the material. However, the mobility of the Ace mixed perovskite is significantly enhanced to be an order of magnitude higher than that of the pristine perovskite. We apply the Ace mixed perovskite in hole-conductor-free printable mesoscopic perovskite solar cells and obtain a stabilized PCE of over 18% (certified 17.7%), which is the highest certified efficiency so far
Fully Printable Mesoscopic Perovskite Solar Cells with Organic Silane Self-Assembled Monolayer
By the introduction
of an organic silane self-assembled monolayer,
an interface-engineering approach is demonstrated for hole-conductor-free,
fully printable mesoscopic perovskite solar cells based on a carbon
counter electrode. The self-assembled silane monolayer is incorporated
between the TiO<sub>2</sub> and CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub>, resulting in optimized interface band alignments and enhanced
charge lifetime. The average power conversion efficiency is improved
from 9.6% to 11.7%, with a highest efficiency of 12.7%, for this low-cost
perovskite solar cell
A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability
We fabricated a perovskite solar cell that uses a double layer of mesoporous TiO2 and ZrO2 as a scaffold infiltrated with perovskite and does not require a hole-conducting layer. The perovskite was produced by drop-casting a solution of PbI2, methylammonium (MA) iodide, and 5-ammoniumvaleric acid (5-AVA) iodide through a porous carbon film. The 5-AVA templating created mixed-cation perovskite (5-AVA)(x)(MA)(1-x)PbI3 crystals with lower defect concentration and better pore filling as well as more complete contact with the TiO2 scaffold, resulting in a longer exciton lifetime and a higher quantum yield for photoinduced charge separation as compared to MAPbI(3). The cell achieved a certified power conversion efficiency of 12.8% and was stable for >1000 hours in ambient air under full sunlight
Hole-Conductor-Free Mesoscopic TiO<sub>2</sub>/CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> Heterojunction Solar Cells Based on Anatase Nanosheets and Carbon Counter Electrodes
A hole-conductor-free fully printable
mesoscopic TiO<sub>2</sub>/CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> heterojunction solar
cell was developed with TiO<sub>2</sub> nanosheets containing high
levels of exposed (001) facets. The solar cell embodiment employed
a double layer of mesoporous TiO<sub>2</sub> and ZrO<sub>2</sub> as
a scaffold infiltrated by perovskite as a light harvester. No hole
conductor or Au reflector was employed. Instead, the back contact
was simply a printable carbon layer. The perovskite was infiltrated
from solution through the porous carbon layer. The high reactivity
of (001) facets in TiO<sub>2</sub> nanosheets improved the interfacial
properties between the perovskite and the electron collector. As a
result, photoelectric conversion efficiency of up to 10.64% was obtained
with the hole-conductor-free fully printable mesoscopic TiO<sub>2</sub>/CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> heterojunction solar
cell. The advantages of fully printable technology and the use of
low-cost carbon-materials-based counter electrode and hole-conductor-free
structure provide this design a promising prospect to approach low-cost
photovoltaic devices
Efficient Compact-Layer-Free, Hole-Conductor-Free, Fully Printable Mesoscopic Perovskite Solar Cell
A compact-layer-free,
hole-conductor-free, fully printable mesoscopic
perovskite solar cell presents a power conversion efficiency of over
13%, which is comparable to that of the device with a TiO<sub>2</sub> compact layer. The different wettability of the perovskite precursor
solution on the surface of FTO and TiO<sub>2</sub> possesses a significant
effect on realizing efficient mesoscopic perovskite solar cell. This
result shows a promising future in printable solar cells by further
simplifying the fabrication process and lowering the preparation costs