569 research outputs found
A study of spectrum fatigue crack propagation in two aluminum alloys. 1: Spectrum simplification
The fatigue crack propagation behavior of two commercial Al alloys was studied using spectrum loading conditions characteristics of those encountered at critical locations in high performance fighter aircraft. A tension dominated (TD) and tension compression (TC) spectrum were employed for each alloy. Using a mechanics-based analysis, it was suggested that negative loads could be eliminated for the TC spectrum for low to intermediate maximum stress intensities. The suggestion was verified by subsequent testing. Using fractographic evidence, it was suggested that a further similification in the spectra could be accomplished by eliminating low and intermediate peak load points resulting in near or below threshold maximum peak stress intensity values. It is concluded that load interactions become more important at higher stress intensities and more plasticity at the crack tip. These results suggest that a combined mechanics/fractographic mechanisms approach can be used to simplify other complex spectra
Deformation mechanisms of NiAl cyclicly deformed near the brittle-to-ductile transition temperature
The intermetallic compound NiAl is one of many advanced materials which is being scrutinized for possible use in high temperature, structural applications. Stoichiometric NiAl has a high melting temperature, excellent oxidation resistance, and good thermal conductivity. Past research has concentrated on improving monotonic properties. The encouraging results obtained on binary and micro-alloyed NiAl over the past ten years have led to the broadening of NiAl experimental programs. The purpose of this research project was to determine the low cycle fatigue properties and dislocation mechanisms of stoichiometric NiAl at temperatures near the monotonic brittle-to-ductile transition. The fatigue properties were found to change only slightly in the temperature range of 600 to 700 K; a temperature range over which monotonic ductility and fracture strength increase markedly. The shape of the cyclic hardening curves coincided with the changes observed in the dislocation structures. The evolution of dislocation structures did not appear to change with temperature
Micromechanics of cyclic deformation in SSME turbopump blade materials
Current and candidate Space Shuttle Main Engine (SSME) turbopump blade materials are anisotropic, both in their elastic and plastic response. The major objective is to characterize the plastic deformation behavior of a typical single crystal nickel-base superalloy, PWA 1480, and to use this information to help guide the development of anisotropic constitutive models
Deformation mechanisms of NiAl cyclicly deformed near the brittle-to-ductile transformation temperature
One of the ongoing challenges of the aerospace industry is to develop more efficient turbine engines. Greater efficiency entails reduced specific strength and larger temperature gradients, the latter of which means higher operating temperatures and increased thermal conductivity. Continued development of nickel-based superalloys has provided steady increases in engine efficiency and the limits of superalloys have probably not been realized. However, other material systems are under intense investigation for possible use in high temperature engines. Ceramic, intermetallic, and various composite systems are being explored in an effort to exploit the much higher melting temperatures of these systems. NiAl is considered a potential alternative to conventional superalloys due to its excellent oxidation resistance, low density, and high melting temperature. The fact that NiAl is the most common coating for current superalloy turbine blades is a tribute to its oxidation resistance. Its density is one-third that of typical superalloys and in most temperature ranges its thermal conductivity is twice that of common superalloys. Despite these many advantages, NiAl requires more investigation before it is ready to be used in engines. Binary NiAl in general has poor high-temperature strength and low-temperature ductility. On-going research in alloy design continues to make improvements in the high-temperature strength of NiAl. The factors controlling low temperature ductility have been identified in the last few years. Small, but reproducible ductility can now be achieved at room temperature through careful control of chemical purity and processing. But the mechanisms controlling the transition from brittle to ductile behavior are not fully understood. Research in the area of fatigue deformation can aid the development of the NiAl system in two ways. Fatigue properties must be documented and optimized before NiAl can be applied to engineering systems. More importantly though, probing the deformation mechanisms operating in fatigue will lead to a better understanding of NiAl's unique characteristics. Low cycle fatigue properties have been reported on binary NiAl in the past year, yet those studies were limited to two temperature ranges: room temperature and near 1000 K. Eventually, fatigue property data will be needed for a wide range of temperatures and compositions. The intermediate temperature range near the brittle-to-ductile transition was chosen for this study to ascertain whether the sharp change occurring in monotonic behavior also occurs under cyclic conditions. An effort was made to characterize the dislocation structures which evolved during fatigue testing and comment on their role in the deformation process
Deformation and fatigue behavior of SSME turbopump blade materials
Directionally solidified and single crystal superalloys which are intended for use as turbopump blade materials are anisotropic both elastically and plastically. Therefore, isotropic constitutive models must be modified. Several models which are now being developed are based on metallurgical theories of deformation in these types of alloys. However, these theories have not been fully justified, and the temperature and strain regimes over which they may be valid are poorly defined. The objective of this work is to study the deformation behavior of the alloys, in order to determine the validity of these models and to thereby support the ongoing research efforts in solid mechanics
Deformation modeling and constitutive modeling for anisotropic superalloys
A study of deformation mechanisms in the single crystal superalloy PWA 1480 was conducted. Monotonic and cyclic tests were conducted from 20 to 1093 C. Both (001) and near-(123) crystals were tested, at strain rates of 0.5 and 50 percent/minute. The deformation behavior could be grouped into two temperature regimes: low temperatures, below 760 C; and high temperatures, above 820 to 950 C depending on the strain rate. At low temperatures, the mechanical behavior was very anisotropic. An orientation dependent CRSS, a tension-compression asymmetry, and anisotropic strain hardening were all observed. The material was deformed by planar octahedral slip. The anisotropic properties were correlated with the ease of cube cross-slip, as well as the number of active slip systems. At high temperatures, the material was isotropic, and deformed by homogeneous gamma by-pass. It was found that the temperature dependence of the formation of superlattice-intrinsic stacking faults was responsible for the local minimum in the CRSS of this alloy at 400 C. It was proposed that the cube cross-slip process must be reversible. This was used to explain the reversible tension-compression asymmetry, and was used to study models of cross-slip. As a result, the cross-slip model proposed by Paidar, Pope and Vitek was found to be consistent with the proposed slip reversibility. The results were related to anisotropic viscoplastic constitutive models. The model proposed by Walter and Jordan was found to be capable of modeling all aspects of the material anisotropy. Temperature and strain rate boundaries for the model were proposed, and guidelines for numerical experiments were proposed
On thermo-mechanical fatigue in single crystal Ni-base superalloys
AbstractThermo-mechanical fatigue (TMF) is a critical damage process in gas turbine jet engines. Reliable life prediction methodologies are required both for design and life management. Current life estimation approaches are computationally burdensome and/or semi-empirical, significantly limiting their application. Complexity comes about from the multiplicity of damage processes which occur during the simultaneously changing temperatures and loads, characteristic of TMF. Furthermore, these processes interact in ways that are not observed for isothermal LCF. These interactions usually accelerate damage processes and result in significantly reduced TMF life, when compared to other fatigue scenarios. The results of a multiphased approach to life prediction will be presented. In phase I the Neu-Sehitoglu (N-S) cumulative damage model was used to: a) provide initial life predictions and b) identify processes and interactions which most significantly control the life under TMF loading. The N-S model is based on a linear damage summation rule which both explicitly and implicitly includes damage interactions. In phase II a sensitivity analysis incorporating statistical concepts was performed on the N-S model parameters. Specifically a nonlinear optimization was performed to determine optimal parameter values in order to maximize agreement with experimental results (well within 2X). In phase III, informed by phases I and II, a physics-based fatigue/oxidation (also recognizing creep effects) model was developed which correctly predicts effects of frequency, hold-time, temperature, and strain range and oxidation kinetics
Effect of Grain Boundary Character Distribution on the Impact Toughness of 410NiMo Weld Metal
Grain boundary character distributions in 410NiMo weld metal were studied in the as-welded, first-stage, and second-stage postweld heat treatment (PWHT) conditions, and these were correlated with the Charpy-V impact toughness values of the material. The high impact toughness values in the weld metal in the as-welded and first-stage PWHT conditions compared to that in the second-stage condition are attributed to the higher fraction of low-energy I pound boundaries. A higher volume fraction of retained austenite and coarser martensite after second-stage PWHT accompanied by the formation of the ideal cube component in the 2-hour heat-treated specimen led to a reduction in the toughness value. A subsequent increase in the PWHT duration at 873 K (600 A degrees C) enhanced the formation of {111}aOE (c) 112 >, which impedes the adverse effect of the cubic component, resulting in an increase in the impact toughness. In addition to this, grain refinement during 4-hour PWHT in the second stage also increased the toughness of the weld metal
Reducing antioxidant capacity evaluated by means of a controlled potential oxidative attack
An analytical method suitable for an antioxidant sensor is presented following the response of these substances to an extensive oxidative attack imposed by electrochemical means. The electrochemical assay simulates the action of a reactive oxygen species (ROS) by means of electrolyses carried out at a potential which is settled at the formal potential of the ROS.
The antioxidant activities of trolox and ascorbic, gallic and caffeic acids and of mixtures these antioxidants was estimated from the charge required for the complete oxidation of the antioxidants from assays where the oxidative attack by O2 and by O2 were simulated.FundaĆ§Ć£o para a CiĆŖncia e Tecnologia (FCT)Centro de QuĆmica da Universidade do Minh
The powerful in vitro bioactivity of Euterpe oleracea Mart. seeds and related phenolic compounds
The Euterpe oleracea Mart. (aƧaĆ) is a plant from the Amazon region, classified as
"super fruit" because of its various functional properties. However, limited investigation
has been performed on aƧaĆ by-products, such as seeds. Therefore, the aim of this work
was to characterized the phenolic compounds of the aqueous extract of aƧaĆ seeds and
further evaluate its bioactivity (antioxidant and cytotoxic activities. Only
proanthocyanidins were detected, being a B-type (epi)catechin tetramer the most
abundant; however, procyanidin trimmers were the most predominant form. AƧaĆ seeds
extract revealed a high antioxidant (EC50 ranging from 3.6 to 19.4 Ī¼g/mL) and cytotoxic
activity, being more effective in the cervical carcinoma cell line (HeLa; GI50 = 18
Ī¼g/mL); it did not show toxicity for non-tumor cells. AƧaĆ seeds are considered a waste
and could have an added economic benefit, through the extraction of natural
antioxidants, particularly proanthocyanidins, that could find applications in food and
pharmaceutical industries.The authors are grateful to Foundation for Science and Technology (FCT, Portugal) for
financial support to the research centre CIMO (strategic project PEst
OE/AGR/UI0690/2011) and L. Barros researcher contract under āPrograma
Compromisso com CiĆŖncia - 2008ā. The authors are also grateful to Jamil S. Oliveira by
the initial discussions on the preparation of samples
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