196 research outputs found

    The ontological argument

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    The thesis of this essay is that the pursuit of a reality in general or appearance in general is barren. The only reality there can be, it is held, is the reality of this or that appearance. There is no reality in general because there is no appearance in general. Any reality is real only in its relation to a given appearance. Apart from that appearance, it may and will be equally well regarded as the appearance of another reality. Hence any attempt to establish an absolute reality, that is, such a reality as is the reality of all appearance and the appearance of no reality, ends in self- contradiction.The absolute reality, during the greater part of the development of European philosophy, has been envisaged as God. Even when this has not been so, still the arguments by which it has been upheld have been borrowed from Christian theology. Thus, for example,even when Hegelian absolutism has diverged from Christianity, its basis has always been the Christian arguments for the existence of God. And the same may be said of Spinoza, who, although certainly not a Christian, is yet a Scholastic. Thus any examination of the tenability of the concept of an absolute reality must centre round the Christian proofs of the existence of God. And since, as it will be argued, the final form of these proofs is the Ontological argument, it is through a detailed consideration of the thought of Anselm - the first and greatest of the exponents of that argument - that the thesis of this essay is to be made out

    Anoxic nitrification in marine sediments

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    Nitrate peaks are found in pore-water profiles in marine sediments at depths considerably below the conventional zone of oxic nitrification. These have been interpreted to represent nonsteady- state effects produced by the activity of nitrifying bacteria, and suggest that nitrification occurs throughout the anoxic sediment region. In this study, ΣNO3 peaks and molecular analysis of DNA and RNA extracted from anoxic sediments of Loch Duich, an organic-rich marine fjord, are consistent with nitrification occurring in the anoxic zone. Analysis of ammonia oxidiser 16S rRNA gene fragments amplified from sediment DNA indicated the abundance of autotrophic ammonia-oxidising bacteria throughout the sediment depth sampled (40 cm), while RT-PCR analysis indicated their potential activity throughout this region. A large non-steady-state pore-water ΣNO3 peak at ~21 cm correlated with discontinuities in this ammonia-oxidiser community. In addition, a subsurface nitrate peak at ~8 cm below the oxygen penetration depth, correlated with the depth of a peak in nitrification rate, assessed by transformation of 15N-labelled ammonia. The source of the oxidant required to support nitrification within the anoxic region is uncertain. It is suggested that rapid recycling of N is occurring, based on a coupled reaction involving Mn oxides (or possibly highly labile Fe oxides) buried during small-scale slumping events. However, to fully investigate this coupling, advances in the capability of high-resolution pore-water techniques are required

    Tidal sands as biogeochemical reactors

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    Sandy sediments of continental shelves and most beaches are often thought of as geochemical deserts because they are usually poor in organic matter and other reactive substances. The present study focuses on analyses of dissolved biogenic compounds of surface seawater and pore waters of Aquitanian coastal beach sediments. To quantitatively assess the biogeochemical reactions, we collected pore waters at low tide on tidal cross-shore transects unaffected by freshwater inputs. We recorded temperature, salinity, oxygen saturation state, and nutrient concentrations. These parameters were compared to the values recorded in the seawater entering the interstitial environment during floods. Cross-shore topography and position of piezometric level at low tide were obtained from kinematics GPS records. Residence time of pore waters was estimated by a tracer approach, using dissolved silica concentration and kinetics estimate of quartz dissolution with seawater. Kinetics parameters were based on dissolved silica concentration monitoring during 20-day incubations of sediment with seawater. We found that seawater that entered the sediment during flood tides remained up to seven tidal cycles within the interstitial environment. Oxygen saturation of seawater was close to 100%, whereas it was as low as 80% in pore waters. Concentrations of dissolved nutrients were higher in pore waters than in seawater. These results suggest that aerobic respiration occurred in the sands. We propose that mineralised organic matter originated from planktonic material that infiltrated the sediment with water during flood tides. Therefore, the sandy tidal sediment of the Aquitanian coast is a biogeochemical reactor that promotes or accelerates remineralisation of coastal pelagic primary production. Mass balance calculations suggest that this single process supplies about 37 kmol of nitrate and 1.9 kmol of dissolved inorganic phosphorus (DIP) to the 250-km long Aquitanian coast during each semi-diurnal tidal cycle. It represents about 1.5% of nitrate and 5% of DIP supplied by the nearest estuary

    Recent turbidite deposition in the eastern Atlantic: Early diagenesis and biotic recovery

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    An interface core taken in Capbreton canyon shows a succession of sedimentary facies interpreted as classical Bouma turbiditic sequences. Activities of 234Th and 210Pb suggest that the deposition of the most recent turbidite was triggered by the violent storm that affected the Atlantic coast of southern France on the 27th of December 1999, about four months before the sampling of the core. This turbidite allows us to study the ongoing diagenesis of the new sediment layer and of the previous sediment-water interface, which has been buried and only slightly eroded. A study of benthic foraminiferal populations informs us about the rate of benthic ecosystem recovery after such a major ecosystem disturbance event. The composition of the benthic foraminiferal fauna suggests that the benthic ecosystem in Capbreton canyon remains in an early stage of colonization. The rare agglutinant taxon Technitella melo appears to be the first colonizing species. It is suggested that Technitella melo is advantaged by the food-impoverished conditions in the days following turbidite deposition. Almost all of the turbidite layer and the previous oxic sediment-water interface contain reduced dissolved metal species and were anoxic. The buried interface contains Fe- and Mn-oxides inherited from its recent oxic past. The reduction of manganese oxides was in progress at the time of core collection. The reduced Mn remained trapped in the sediment as Mn-containing carbonates. Iron-oxides did not undergo significant reductive dissolution. The top of the newly deposited turbidite formed an oxic layer, which was rapidly enriched in metal-oxides. The enrichment of manganese oxides was mostly due to the oxidation of dissolved Mn2+, which diffused from below. The enrichment of iron oxides is explained both by the oxidation of the upward flux of dissolved Fe2+, and by the input of detrital iron oxide after, or as a result of the turbidite deposition

    Terrestrial groundwater and nutrient discharge along the 240-km-long Aquitanian coast

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    We collected samples from sea water, runnel water, beach pore waters, water from the unconfined surficial aquifer discharging at the beach face, groundwater, and rainwater from the Aquitanian coast in order to determine the flux of dissolved inorganic nitrogen (DIN), phosphorus and silica from terrestrial submarine groundwater discharge (SGD). The flux of fresh groundwater was obtained from a water balance calculation based on precipitation and evapotranspiration and assessment of the coastal watershed from hydrograph separation. Waters with intermediate salinities between sea water and freshwaters are found all along the 240-km-long coast, indicating that SGD is ubiquitous. The estimated fresh water flux is 2.25 m3 d− 1 m− 1 longshore. Terrestrial SGD provides a DIN flux of 9·106 mol each year to the adjacent coastal zone. This flux is about four times lower than the release of DIN due to tidally driven saline SGD. The freshwater DIN flux is low because the upland land use consists almost exclusively of pine forest. Dissolved organic nitrogen represents more than 60% of the total dissolved nitrogen flux. Dissolved iron, phosphorus and silica have much higher concentrations in the anoxic forest aquifer than in the fresh-water end-member of the subterranean estuary sampled in the upper beach aquifer. This suggests that the salinity gradient of the estuary does not correspond to a redox gradient. The redox front between anoxic groundwater and fresh oxic waters occurs below the soil-depleted foredune/yellow dune. Anoxic P- and Si-rich waters seep directly on the beach face only in the north Gironde, where the foredunes are eroded. This study reveals the role of the sandy foredune aquifer in biogeochemical fluxes from SGD, which is to dilute and oxidize waters from the unconfined surficial upland aquifer

    Impact of solid waste disposal on nutrient dynamics in a sandy catchment

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    Groundwaters impacted by mature landfill leachate are generally enriched in ammonium. In order to assess the dynamics of ammonium exchanges between leachates and the water system inside a sandy permeable catchment we measured ammonium, nitrate and chloride concentrations in the stream and in sediment pore waters of the streambed of a landfill impacted aquifer. Geophysical investigation methods complemented the biogeochemical survey. The studied zone is a 23 km² catchment located in a coastal lagoon area sensitive to eutrophication risk. Ammonium concentrations in the river were up to 800 µmol l−1 during low water period in summer. Three surveys of the river chemistry showed a regular increase in ammonium, nitrate and chloride concentrations along a 1 km section of the watercourse, downstream the landfill, implying that the leachate plume exfiltrates along this section. Sediment cores collected within this section showed all an increase in ammonium concentrations with depth in pore waters as a consequence of the landfill leachate dispersion, as attested by a simultaneous increase in chloride concentrations. Nitrate enrichment in the river water was due to nitrification of ammonium at the interface between groundwater and streamwater. The apparent nitrification rate obtained was within values reported for turbid estuaries, although the river contained very little suspended particulate matter. Actually, pore water chemistry suggests that nitrification occurred for the most part in subsurface permeable sediments, rather than in stream water. The overall topographic, hydrological, geochemical, and geoelectrical data set permit to estimate the extension of the chloride and ammonium plume. The estimation of the apparent ammonium plume velocity is 23 m year−1 whereas the chloride plume velocity should be 50 m year−1. The river is the outlet of the impacted groundwaters. Considering that the input of ammonium from the landfill is balanced by the present day output via the river, the residence time of ammonium in the aquifer is between 7 and 18 years

    Vertical distribution and respiration rates of benthic foraminifera: Contribution to aerobic remineralization in intertidal mudflats covered by Zostera noltei meadows

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    The present study investigates the influence of seagrass root systems on benthic hard-shelled meiofauna (foraminifera). In February and July 2011, sediment cores were collected at low tide at two sites in Arcachon lagoon, a vegetated site with Zostera noltei and a second site with bare sediments. We used the highly discriminative CellTracker™ Green fluorogenic probe technique to recognize living foraminifera and to describe foraminiferal density and diversity. Three dominant species of foraminifera were observed: Ammonia tepida, Haynesina germanica and Eggerella scabra. The two calcareous species, A. tepida and H. germanica, were preferentially found in the upper half to 1 cm of the sediment. At the vegetated site, these two species had a slightly deeper microhabitat. In the literature, both species have been described alive in much deeper sediment layers, possibly due to false positives from the Rose Bengal staining method. These two species also showed 1) higher densities at the site with Z. noltei, 2) a higher density in February when conditions were supposed optimal due to a microphytobenthos bloom, and 3) dissolved calcitic shells in July, probably resulting from a lower pH. The agglutinated species E. scabra was present alive down to at least 7 cm depth. E. scabra showed high densities in the anoxic part of the sediment at both the vegetated and bare sites, with a substantially higher density in summer at the site with bare sediments. Its presence at depth may be related to its trophic requirements; this species could be less dependent on labile organic matter than A. tepida and H. germanica. On this intertidal mudflat, the foraminiferal contribution to aerobic carbon remineralization, based on respiration rate measurements, can account for up to 7% of the diffusive oxygen uptake, almost five times more than the maximum contribution recorded in open marine environments (300 m depth) in the Bay of Biscay
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