1,160 research outputs found
A possible cosmological application of some thermodynamic properties of the black body radiation in dimensional Euclidean spaces
In this work we present the generalization of some thermodynamic properties
of the black body radiation (BBR) towards an dimensional Euclidean space.
For this case the Planck function and the Stefan-Boltzmann law have already
been given by Landsberg and de Vos and some adjustments by Menon and Agrawal.
However, since then no much more has been done on this subject and we believe
there are some relevant aspects yet to explore. In addition to the results
previously found we calculate the thermodynamic potentials, the efficiency of
the Carnot engine, the law for adiabatic processes and the heat capacity at
constant volume. There is a region at which an interesting behavior of the
thermodynamic potentials arise, maxima and minima appear for the BBR
system at very high temperatures and low dimensionality, suggesting a possible
application to cosmology. Finally we propose that an optimality criterion in a
thermodynamic framework could have to do with the nature of the universe.Comment: 9 pages, 8 figure
Kinetics of Intramolecular Chemical Exchange by Initial Growth Rates of Spin Saturation Transfer Difference Experiments (SSTD NMR)
We report here the Initial Growth Rates SSTD NMR method, as a new powerful tool to obtain the kinetic parameters of intramolecular chemical exchange in challenging small organic and organometallic molecules
Electron screening in molecular fusion reactions
Recent laboratory experiments have measured fusion cross sections at
center-of-mass energies low enough for the effects of atomic and molecular
electrons to be important. To extract the cross section for bare nuclei from
these data (as required for astrophysical applications), it is necessary to
understand these screening effects. We study electron screening effects in the
low-energy collisions of Z=1 nuclei with hydrogen molecules. Our model is based
on a dynamical evolution of the electron wavefunctions within the TDHF scheme,
while the motion of the nuclei is treated classically. We find that at the
currently accessible energies the screening effects depend strongly on the
molecular orientation. The screening is found to be larger for molecular
targets than for atomic targets, due to the reflection symmetry in the latter.
The results agree fairly well with data measured for deuteron collisions on
molecular deuterium and tritium targets.Comment: 15 Page RevTeX document, twelve postscript figures, now in a uufile
packag
A statistical analysis of electric self-potential time series associated to two 1993 earthquakes in Mexico
Recent studies related with earthquake prediction involve statistical studies of the ground electric self-potential behavior. Published results about the complexity of this kind of processes encourage us to study the statistical behavior of the ground electric self-potential recorded in Guerrero state, Mexico. This region is characterized by high seismicity. The electric self-potential variations were recorded in the Acapulco station directly from the ground. The sampling period was four seconds and the data were stored from March to December of 1993. Two significant earthquakes (EQs) occurred near this station, 15 May and 24 October whose magnitudes were Mw=6.0 and Mw=6.6 respectively. A preliminary processing was carried out consisting of a moving average of the original time series in order to filter the very high frequencies and to complete short lacks of data and outliers. Then, a visual inspection of the complete filtered signal was performed to search some seismic electric signals (SES), which were ambiguously depicted. Subsequently, a detrending of µ=0 was applied with the windows of 3.3, 6.6 and 10 h. Later, the analysis of the spectral exponent β was made, showing changes during the total period examined, and the most evident changes occurred during the preparation mechanism of the Mw=6.6 EQ. Fifteen days before the 24 October EQ, a Brownian-noise like behavior was displayed (β≈2), having a duration of about two days. In addition a Higuchi fractal method and wavelet analysis were made confirming the presence of the β-anomaly
A first--order irreversible thermodynamic approach to a simple energy converter
Several authors have shown that dissipative thermal cycle models based on
Finite-Time Thermodynamics exhibit loop-shaped curves of power output versus
efficiency, such as it occurs with actual dissipative thermal engines. Within
the context of First-Order Irreversible Thermodynamics (FOIT), in this work we
show that for an energy converter consisting of two coupled fluxes it is also
possible to find loop-shaped curves of both power output and the so-called
ecological function against efficiency. In a previous work Stucki [J.W. Stucki,
Eur. J. Biochem. vol. 109, 269 (1980)] used a FOIT-approach to describe the
modes of thermodynamic performance of oxidative phosphorylation involved in
ATP-synthesis within mithochondrias. In that work the author did not use the
mentioned loop-shaped curves and he proposed that oxidative phosphorylation
operates in a steady state simultaneously at minimum entropy production and
maximum efficiency, by means of a conductance matching condition between
extreme states of zero and infinite conductances respectively. In the present
work we show that all Stucki's results about the oxidative phosphorylation
energetics can be obtained without the so-called conductance matching
condition. On the other hand, we also show that the minimum entropy production
state implies both null power output and efficiency and therefore this state is
not fulfilled by the oxidative phosphorylation performance. Our results suggest
that actual efficiency values of oxidative phosphorylation performance are
better described by a mode of operation consisting in the simultaneous
maximization of the so-called ecological function and the efficiency.Comment: 20 pages, 7 figures, submitted to Phys. Rev.
Indirect techniques in nuclear astrophysics. Asymptotic Normalization Coefficient and Trojan Horse
Owing to the presence of the Coulomb barrier at astrophysically relevant
kinetic energies it is very difficult, or sometimes impossible, to measure
astrophysical reaction rates in the laboratory. That is why different indirect
techniques are being used along with direct measurements. Here we address two
important indirect techniques, the asymptotic normalization coefficient (ANC)
and the Trojan Horse (TH) methods. We discuss the application of the ANC
technique for calculation of the astrophysical processes in the presence of
subthreshold bound states, in particular, two different mechanisms are
discussed: direct capture to the subthreshold state and capture to the
low-lying bound states through the subthreshold state, which plays the role of
the subthreshold resonance. The ANC technique can also be used to determine the
interference sign of the resonant and nonresonant (direct) terms of the
reaction amplitude. The TH method is unique indirect technique allowing one to
measure astrophysical rearrangement reactions down to astrophysically relevant
energies. We explain why there is no Coulomb barrier in the sub-process
amplitudes extracted from the TH reaction. The expressions for the TH amplitude
for direct and resonant cases are presented.Comment: Invited talk on the Conference "Nuclear Physics in Astrophysics II",
Debrecen, Hungary, 16-20 May, 200
Large-space cluster model calculations for the He3(He3,2p)He4 and H3(H3,2n)He4 reactions
The He3(He3,2p)He4 and H3(H3,2n)He4 reactions are studied in a microscopic
cluster model. We search for resonances in the He3+He3 and He4+p+p channels
using methods that treat the two- and three-body resonance asymptotics
correctly. Our results show that the existence of a low-energy resonance or
virtual state, which could influence the Be-7 and B-8 solar neutrino fluxes, is
rather unlikely. Our calculated He3(He3,2p)He4 and H3(H3,2n)He4 cross sections
are in a good general agreement with the experimental data.Comment: 12 pages with 3 figures. The postscript file and more information are
available at http://nova.elte.hu/~csot
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