Deuterium distribution in two major products obtained during the cyclic dimerisation of methyloxirane over acidic molecular sieves

The ring-transformation reactions of methyloxirane on DZSM-5 and DAlMCM-41 aluminosilicates were studied in a pulse microreactor at 363 K. Cyclic dimerisation was found to be the major reaction pathway. Deuterium distribution in two important products of this reaction route was monitored. The positions of the deuterium atoms were determined giving help in proposing a more accurate dimerisation mechanism

Star-galaxy separation strategies for WISE-2MASS all-sky infrared galaxy catalogs

We combine photometric information of the WISE and 2MASS all-sky infrared databases, and demonstrate how to produce clean and complete galaxy catalogs for future analyses. Adding 2MASS colors to WISE photometry improves star-galaxy separation efficiency substantially at the expense of loosing a small fraction of the galaxies. We find that 93% of the WISE objects within W1<15.2 mag have a 2MASS match, and that a class of supervised machine learning algorithms, Support Vector Machines (SVM), are efficient classifiers of objects in our multicolor data set. We constructed a training set from the SDSS PhotoObj table with known star-galaxy separation, and determined redshift distribution of our sample from the GAMA spectroscopic survey. Varying the combination of photometric parameters input into our algorithm we show that W1 - J is a simple and effective star-galaxy separator, capable of producing results comparable to the multi-dimensional SVM classification. We present a detailed description of our star-galaxy separation methods, and characterize the robustness of our tools in terms of contamination, completeness, and accuracy. We explore systematics of the full sky WISE-2MASS galaxy map, such as contamination from Moon glow. We show that the homogeneity of the full sky galaxy map is improved by an additional J<16.5 mag flux limit. The all-sky galaxy catalog we present in this paper covers 21,200 sq. degrees with dusty regions masked out, and has an estimated stellar contamination of 1.2% and completeness of 70.1% among 2.4 million galaxies with $z_{med}= 0.14$. WISE-2MASS galaxy maps with well controlled stellar contamination will be useful for spatial statistical analyses, including cross correlations with other cosmological random fields, such as the Cosmic Microwave Background. The same techniques also yield a statistically controlled sample of stars as well.Comment: 10 pages, 11 figures. Accepted for publication in MNRA

Superradiance or total reflection?

Numerical evolution of massless scalar fields on Kerr background is studied. The initial data specifications are chosen to have compact support separated from the ergoregion and to yield nearly monochromatic incident wave packets. The initial data is also tuned to maximize the effect of superradiance. Evidences are shown indicating that instead of the anticipated energy extraction from black hole the incident radiation fail to reach the ergoregion rather it suffers a nearly perfect reflection.Comment: 8 pages, 6 figures, contribution to the proceedings of the conference on Relativity and Gravitation: 100 Years after Einstein in Pragu

On the Coherence of WMAP and Planck Temperature Maps

The recent data release of ESA's Planck mission together with earlier WMAP releases provide the first opportunity to compare high resolution full sky Cosmic Microwave Background temperature anisotropy maps. To quantify the coherence of these maps beyond the power spectrum we introduce Generalized Phases, unit vectors in the (2l+1) dimensional representation spaces. For a Gaussian distribution, Generalized Phases are random and if there is non-Gaussianity, they represent most of the non-Gaussian information. The alignment of these unit vectors from two maps can be characterized by their angle, 0 deg expected for full coherence, and 90 deg for random vectors. We analyze maps from both missions with the same mask and Nside=512 resolution, and compare both power spectra and Generalized Phases. We find excellent agreement of the Generalize Phases of Planck Smica map with that of the WMAP Q,V,W maps, rejecting the null hypothesis of no correlations at 5 sigma for l's l<700, l<900 and l<1100, respectively, except perhaps for l<10. Using foreground reduced maps for WMAP increases the phase coherence. The observed coherence angles can be explained with a simple assumption of Gaussianity and a WMAP noise model neglecting Planck noise, except for low-intermediate l's there is a slight, but significant off-set, depending on WMAP band. On the same scales WMAP power spectrum is about 2.6% higher at a very high significance, while at higher l's there appears to be no significant bias. Using our theoretical tools, we predict the phase alignment of Planck with a hypothetical perfect noiseless CMB experiment, finding decoherence at l > 2900; below this value Planck can be used most efficiently to constrain non-Gaussianity.Comment: 8 pages, 8 figures, accepted for publication in MNRAS; minor modifications and 2 new figures adde

Phase statistics of the WMAP 7 year data

We performed a comprehensive statistical analysis using complex phases of the a_lm coefficients computed from the most recent data of the Wilkinson Microwave Anisotropy Probe (WMAP). Our aim was to confirm or constrain the presence of non-Gaussianities in the data. We found phase correlations - that suggest non-Gaussianity - at high-l in a_lm coefficients by applying various statistical tests. Most of all, we detected a non-Gaussian signal reaching a significance of 4.7 sigma using random walk statistics and simulations. However, our conclusion is that the non-Gaussian behavior is due to contamination from galactic foregrounds that show up in small scales only. When masked out the contaminated regions, we found no significant non-Gaussianity. Furthermore, we constrained the f_NL parameter using CMB simulations that mimic primordial non-Gaussianity. Our estimate is f_NL=40 +/- 200, in agreement with previous measurements and inflationary expectations.Comment: 4 pages, 4 figures, Accepted for Publication in A