7,194 research outputs found

    Redetermination of para-aminopyridine (fampridine, EL-970) at 150 K

    Get PDF
    The structure of fampridine (EL-970) or 4-aminopyridine, C₅H₆N₂, has been redetermined at 150 K. The room-temperature structure has been reported previously [Chao & Schempp (1977). Acta Cryst. B33, 1557-1564]. Pyramidalization at the amine N atom occurs in fampridine, with the N atom 0.133 (11) Å from the plane of the three C/H/H atoms to which it is bonded; the interplanar angle between the pyridyl ring and NH2 group is 21 (2)°. Aggregation in the solid state occurs by N-H...N and N-H...[pi](pyridine) interactions with N...N and N...[pi](centroid) distances of 2.9829 (18) and 3.3954 (15) Å, respectively; a C-H...[pi](pyridine) contact completes the intermolecular interactions [C...[pi](centroid) = 3.6360 (16) Å]

    Ethyl and isopropyl 4-ferrocenylbenzoate.

    Get PDF
    The title compounds, [Fe(C5H5)(C14H13O2)] and [Fe(C5H5)- (C15H15O2)], respectively, contain the ferrocenyl 5(C5H4) and phenylene ±C6H4± rings in a nearly coplanar arrangement, with interplanar angles of 6.88 (12) and 10.5 (2), respectively. Molecules of the ethyl ester form dimers through 5(C5H5)CÐ H O C hydrogen bonds, with graph set R22 (20), and, together with Csp3ÐH (C5H5) interactions, generate a one-dimensional column (irregular ladder). Molecules of the isopropyl ester aggregate through 5(C5H5)CÐH (C6H4) interactions

    Observation of the critical regime near Anderson localization of light

    Full text link
    Diffusive transport is among the most common phenomena in nature [1]. However, as predicted by Anderson [2], diffusion may break down due to interference. This transition from diffusive transport to localization of waves should occur for any type of classical or quantum wave in any media as long as the wavelength becomes comparable to the transport mean free path ℓ∗\ell^* [3]. The signatures of localization and those of absorption, or bound states, can however be similar, such that an unequivocal proof of the existence of wave localization in disordered bulk materials is still lacking. Here we present measurements of time resolved non-classical diffusion of visible light in strongly scattering samples, which cannot be explained by absorption, sample geometry or reduction in transport velocity. Deviations from classical diffusion increase strongly with decreasing ℓ∗\ell^* as expected for a phase transition. This constitutes an experimental realization of the critical regime in the approach to Anderson localization.Comment: 5 pages, 4 figure

    Electric field effect on superconductivity at complex oxide interfaces

    Full text link
    We examine the enhancement of the interfacial superconductivity between LaAlO3_{3} and SrTiO3_{3} by an effective electric field. Through the breaking of inversion symmetry at the interface, we show that a term coupling the superfluid density and an electric field can augment the superconductivity transition temperature. Microscopically, we show that an electric field can also produce changes in the carrier density by relating the measured capacitance to the density of states. Through the electron-phonon induced interaction in bulk SrTiO3_{3}, we estimate the transition temperature.Comment: 7 Pages, Submitted to Physical Revie

    The Profiles of Bars in Spiral Galaxies

    Full text link
    We present an analysis of major-axis surface-brightness profiles of bars in a volume-limited sample of 182 barred spiral galaxies, using Spitzer 3.6 micron images. Unlike most previous studies, we use the entire bar profile, and we classify profiles into four categories. These are "Peak+Shoulders" (P+Sh) -- updating the classic "flat bar" profile -- and three subtypes of the classic "exponential" profile: (true) Exponential, "Two-Slope" (shallow inner slope + steeper outer slope), and "Flat-Top" (constant inner region, steep outer slope). P+Sh profiles are preferentially found in galaxies with high stellar masses, early Hubble types, red colours, and low gas fractions; the most significant factor is stellar mass, and previous correlations with Hubble type can be explained by the tendency of higher-mass galaxies to have earlier Hubble types. The most common type of non-P+Sh profile is Exponential, followed by Flat-Top profiles; all non-P+Sh profiles appear to have similar distributions of stellar mass, Hubble type, colour, and gas fraction. We also morphologically classify the bars of an inclined subsample into those with and without boxy/peanut-shaped (B/P) bulges; as previously reported, the presence of a B/P bulge is very strong function of stellar mass. Essentially all bars with B/P bulges have P+Sh profiles; we associate the profile shoulders with the outer, vertically thin part of the bar. We find a small number of P+Sh profiles in bars without clear B/P bulges, which may indicate that P+Sh formation precedes the formation of B/P bulges.Comment: pdflatex, 21 pages, 12 figures; accepted by MNRAS. Data, code, and Jupyter notebooks available at https://github.com/perwin/barprofiles_pape

    Spin-Orbital Entanglement and Violation of the Goodenough-Kanamori Rules

    Full text link
    We point out that large composite spin-orbital fluctuations in Mott insulators with t2gt_{2g} orbital degeneracy are a manifestation of quantum entanglement of spin and orbital variables. This results in a dynamical nature of the spin superexchange interactions, which fluctuate over positive and negative values, and leads to an apparent violation of the Goodenough-Kanamori rules. [{\it Published in Phys. Rev. Lett. {\bf 96}, 147205 (2006).}]Comment: 4 pages, 2 figure

    Strategic Operations Research and the Edelman Prize Finalist Applications 1989-1998

    Get PDF
    In an earlier study we examined the available evidence on the Edelman Prize finalist applications 1989-1998. This study concluded that 13 of the 42 private sector applications provide examples of strategic operations research (SOR) when SOR is defined as operations research that creates a sustainable competitive advantage. In a follow-up study we tested our classifications, gathering longitudinal information on the continued success of the Edelman applications. We contacted people who were familiar with all the private sector applications that were Edelman finalists 1989-1996 and had at least five years of history since the competition. We describe the post-Edelman history of these applications and use this data to reassess their strategic role. We found that the longitudinal data provides evidence to support our original classification, but also suggests that several additional applications were more strategic than was originally apparent. We conclude that almost 60% (20 of 34) of these applications created a sustainable competitive advantage for their firms and provide examples of SOR

    Agroforestry interactions and soil water use in watersheds under corn-soybean management

    Get PDF
    Paper presented at the 11th North American Agroforesty Conference, which was held May 31-June 3, 2009 in Columbia, Missouri.In Gold, M.A. and M.M. Hall, eds. Agroforestry Comes of Age: Putting Science into Practice. Proceedings, 11th North American Agroforestry Conference, Columbia, Mo., May 31-June 3, 2009.Agroforestry and grass buffer practices reduce non point source pollution from corn-soybean watersheds, yet little is known about the processes and mechanisms involved. The objective of this study was to compare the soil water dynamics in crop, grass, and agroforestry areas throughout the growing season to understand soil water use and recharge differences among the treatments. The study was conducted on two corn (Zea mays L.)-soybean (Glycine max (L.) Merr.) rotational watersheds with grass and agroforestry buffers at the Greenley Research Center, Knox County, MO. Campbell soil moisture sensors were installed in crop, grass, and agroforestry areas with six replications at 5, 10, 20, and 40 cm depths to record volumetric soil water content at 10 minute intervals for 2004 through 2007. Initial soil moisture was lower in tree and grass buffer areas than crop areas probably due to water use by the permanent vegetation before crops were established. The differences were larger for shallower depths as compared to the 40 cm depth. The trend continued throughout the growing season. Weekly soil moisture content was significantly higher in the crop treatment as compared to the buffer treatments. During rain events water content increased in all depths and treatments and the differences in water content among treatments diminished. At the end of the growing season, soil water content increased when water use was low and as the profile recharged by rain events. The results of the study suggest that establishment of grass and agroforestry buffers help reduce non point source pollution from row crop agriculture by using additional water that would have otherwise have been lost in runoff carrying sediments, nutrients, and pesticides.Ranjith P. Udawatta (1,2), Stephen H. Anderson (1), Peter P. Motavalli (1), and Harold E. Garrett (2) ; 1. Department of Soil, Environmental and Atmospheric Sciences. 2. Center for Agroforestry, and University of Missouri, Columbia, MO 65211.Includes bibliographical references

    Correlated Persistent Tunneling Currents in Glasses

    Full text link
    Low temperature properties of glasses are derived within a generalized tunneling model, considering the motion of charged particles on a closed path in a double-well potential. The presence of a magnetic induction field B violates the time reversal invariance due to the Aharonov-Bohm phase, and leads to flux periodic energy levels. At low temperature, this effect is shown to be strongly enhanced by dipole-dipole and elastic interactions between tunneling systems and becomes measurable. Thus, the recently observed strong sensitivity of the electric permittivity to weak magnetic fields can be explained. In addition, superimposed oscillations as a function of the magnetic field are predicted.Comment: 4 page
    • 

    corecore