Valley polarization effects on the localization in graphene Landau levels

Effects of disorder and valley polarization in graphene are investigated in the quantum Hall regime. We find anomalous localization properties for the lowest Landau level (LL), where disorder can induce wavefunction delocalization (instead of localization), both for white-noise and gaussian-correlated disorder. We quantitatively identify the contribution of each sublattice to wavefunction amplitudes. Following the valley (sublattice) polarization of states within LLs for increasing disorder we show: (i) valley mixing in the lowest LL is the main effect behind the observed anomalous localization properties, (ii) the polarization suppression with increasing disorder depends on the localization for the white-noise model, while, (iii) the disorder induces a partial polarization in the higher Landau levels for both disorder models.Comment: 5 pages, 6 figures, extended version, with 2 new figures adde

Resonant tunneling through protected quantum dots at phosphorene edges

We theoretically investigate phosphorene zigzag nanorribons as a platform for constriction engineering. In the presence of a constriction at the upper edge, quantum confinement of edge protected states reveals resonant tunnelling Breit-Wigner transmission peaks, if the upper edge is uncoupled to the lower edge. Coupling between edges in thin constrictions gives rise to Fano-like and anti-resonances in the transmission spectrum of the system.Comment: 8 pages,7 figure

Extractability and mobility of mercury from agricultural soils surrounding industrial and mining contaminated areas

This study focussed on a comparison of the extractability of mercury in soils with two different contamination sources (a chlor-alkali plant and mining activities) and on the evaluation of the influence of specific soil properties on the behaviour of the contaminant. The method applied here did not target the identification of individual species, but instead provided information concerning the mobility of mercury species in soil. Mercury fractions were classified as mobile, semi-mobile and non-mobile. The fractionation study revealed that in all samples mercury was mainly present in the semi-mobile phase (between 63 and 97%). The highest mercury mobility (2.7 mg kg-1) was found in soils from the industrial area. Mining soils exhibited higher percentage of non-mobile mercury, up to 35%, due to their elevated sulfur content. Results of factor analysis indicate that the presence of mercury in the mobile phase could be related to manganese and aluminum soil contents. A positive relation between mercury in the semi-mobile fraction and the aluminium content was also observed. By contrary, organic matter and sulfur contents contributed to mercury retention in the soil matrix reducing the mobility of the metal. Despite known limitations of sequential extraction procedures, the methodology applied in this study for the fractionation of mercury in contaminated soil samples provided relevant information on mercury's relative mobility

Competências transversais dos recém-diplomados do ensino superior no mercado global

O mercado de trabalho está a mudar rapidamente e de muitas formas, nomeadamente, a revolução das tecnologias de informação e comunicação, a globalização, a flexibilização e as alterações da estrutura do trabalho, que conduzem a uma crescente imprevisibilidade e à necessidade de lidar com este contexto de incerteza. Estas mudanças, inevitavelmente, têm implicações no conjunto de competências necessárias para que os trabalhadores sejam capazes de funcionar adequadamente num mercado global cada vez mais competitivo e em constante mutação. Desta forma, nos dias de hoje, o mercado de trabalho requer mais do que conhecimentos teóricos e técnicos, reclama por um conjunto de competências transversais que servirão de suporte e ligação entre o conhecimento técnico e a prática profissional. É neste cenário que emergem as competências transversais que cada vez mais assumem uma importância maior. O objetivo deste estudo consiste em identificar as competências transversais requeridas aos recém-diplomados do ensino superior no mercado global. Inicialmente, analisa-se o conceito de competência transversal, apresentando algumas definições e assinalando as suas características comuns, destacando ainda a variedade de designações utilizadas para as nomear. No âmbito do estudo foi realizada revisão da literatura nacional e internacional sobre as competências transversais nos diplomados, quer na perspetiva dos próprios diplomados, quer dos empregadores. Através da análise de conteúdo, foram identificadas as competências transversais mais valorizadas por continente e, a partir da análise das mesmas, definiram-se as competências transversais exigidas no mercado global. Finalmente são discutidas as implicações teóricas e empíricas das conclusões deste trabalho

Multi-target optimization of solid phase microextraction to analyse key flavour compounds in wort and beer

Despite the literature comprises numerous studies dealing with the analysis of wort and beer flavour-related compounds by HS-SPME followed by GC-MS quantification, no generalized consensus exists regarding the optimal conditions for the extraction procedure. The complex chemistry nature of these matrices, the number of analytes, as well as the number and interactions among parameters affecting the extraction performance, requires the adoption of optimal experimental design protocols. This aspect is often overlooked and often not properly addressed in practice. Therefore, in the present work, the optimal conditions under which a range of wort and beer analytes can be extracted and quantified were analysed. The optimal extraction conditions were presented at two levels of aggregation: global (untargeted) and key-flavour analysis. Experimental data was generated by Definitive-Screening-Design, followed by model development and optimization. Both approaches were compared and critically analysed. For vicinal-diketones group, a complete validation study for the optimal conditions is presented.publishe

Periodic vehicle routing problem in a health unit

In logistics of home health care services in the Health Units, the managers and nurses need to carry out the schedule and the vehicles routes for the provision of care at the patients' homes. Currently, in Portugal, these services are increasingly used but the problem is still, usually, solved manually and without computational resources. The increased demand for home health care due to the boost of the elderly people number entails a high associated cost which, sometimes, does not guarantee the quality of the service. In this sense, the periodic vehicle routing problem is a generalization of the classical vehicle routing problem in which routes are determined for a time horizon of several days. In this work, it is provided a periodic vehicle routing problem applied in the Health Unit in Bragança. An integer linear programming formulation for the real database, allowed to solve the problem in an efficient and optimized way using the CPLEXR software.Programa Operacional Temático Factores de Competitividade(POCI-01-0145-FEDER-007043