Design and Optimisation of Optical Metasurfaces Using Deep Learning

This thesis centres on the design, processing, and fabrication of tunable optical metamaterials. It incorporates physics-based simulation, deep learning (DL), and thin film fabrication techniques to offer a comprehensive exploration of the field of optical metamaterials. Placing stiff resonators on a flexible substrate is a common type of mechanically tunable metasurface, whose optical responses are tuned by dynamically adjusting the spacing between resonators by applying mechanical force. However, the significant modulus mismatch between materials causes stress concentration at the interface, leading to crack propagation and delamination at lower strain levels (20-50%), and limiting the optical tunability of the structure. To address this challenge, we propose two designs to manipulate stress distribution. Under mechanical force, the structure enables localised deformation, redirecting stress from critical areas. This mechanism minimises the accumulation of stress in the interface, thereby diminishing the risk of material failure and improving stretchability up to 120% compared to traditional designs. This extreme stretchability leads to a 143 nm resonance shift, which is almost twice as large as that of conventional geometry. A universal machine learning (ML)-based approach was developed to optimise the metasurface design across three key aspects: geometric parameters, material development, and free-form shape configuration. In design parameters optimisation, a fully connected neural network (FCNN) was developed with a mean absolute error (MAE) of 0.0051, recommending a single geometry with a 104 order of magnitude decrease in computational time when compared to finite element method (FEM) simulations used for data generation. The suggested structure provides extensive coverage of the colour space, encompassing 27.65% of the standard RGB (sRGB) space. For the materials development part, an inverse design (ID) network was combined with effective medium approximation (EMA), navigating infinite materials composition space to identify new compositions for custom applications. The last network was tasked to explore boundless free-form shape space to propose the one for the on-demand optical properties with MAE of 0.21. The accuracy of all networks was experimentally validated

Interference and X Networks with Noisy Cooperation and Feedback

The Gaussian $K$-user interference and $M\times K$ X channels are investigated with no instantaneous channel state information (CSI) at transmitters. First, it is assumed that the CSI is fed back to all nodes after a finite delay (delayed CSIT), and furthermore, the transmitters operate in full-duplex mode, i.e., they can transmit and receive simultaneously. Achievable results are obtained on the degrees of freedom (DoF) of these channels under the above assumption. It is observed that, in contrast with no CSIT and full CSIT models, when CSIT is delayed, the achievable DoFs for both channels with full-duplex transmitter cooperation are greater than the best available achievable results on their DoF without transmitter cooperation. Our results are the first to show that the full-duplex transmitter cooperation can potentially improve the channel DoF with delayed CSIT. Then, $K$-user interference and $K\times K$ X channels are considered with output feedback, wherein the channel output of each receiver is causally fed back to its corresponding transmitter. Our achievable results with output feedback demonstrate strict DoF improvements over those with the full-duplex delayed CSIT when $K>5$ in the $K$-user interference channel and $K>2$ in the $K\times K$ X channel. Next, the combination of delayed CSIT and output feedback, known as Shannon feedback, is studied and strictly higher DoFs compared to the output feedback model are achieved in the $K$-user interference channel when K=5 or $K>6$, and in the $K\times K$ X channel when $K>2$. Although being strictly greater than 1 and increasing with size of the networks, the achievable DoFs in all the models studied in this paper approach limiting values not greater than 2.Comment: 53 pages, 15 figures; Submitted to IEEE Transactions on Information Theory, May 2012. To be presented in part in ISIT 2012, Cambridge, MA, US

Reinforcement Sensitivity, Moral Cognition, Moral Identity, and Moral Judgment among College students

Introduction: Morality and moral behavior are one of the main themes of psychology. The aim of the present study was to investigate the relationship between reinforcement sensitivity و moral identity, moral cognition and utilitarianism in personal and impersonal moral judgments. Method: Statistical population consisted of 303 students (only males) were randomly selected through multi-stage cluster random sampling method. Results: Results showed a strong relationship between Reinforcement Sensitivity dimensions with moral identity, moral cognition and personal and impersonal moral judgment. The series of multiple regression analyses showed that Fight-Flight-Freeze systems (FFFS) were strongly able to predict moral dimensions of cognition, identity and moral judgment. FFFS were strong predictors in all of moral dimensions. Conclusion: The results expand the understanding of the moral dimensions and indicate how domains of reinforcement sensitivity could explain the moral identity, moral cognition and utilitarianism in moral judgments. Declaration of Interest: None

In Vitro Microleakage of Bulk Fill and Conventional Composites and a Hybrid Glass Ion-omer in Primary Molars

Objectives The main disadvantage of composite resins is their polymerization shrinkage, which can lead to microleakage. The purpose of this in vitro study was to evaluate the microleakage of bulk fill and conventional composites and a new hybrid glass ionomer (GI) in class II restorations of primary molar teeth. Methods In this in vitro study, 51 primary molar teeth were randomly divided into three groups. Standard class II cavities were then prepared. In group 1 the cavities were restored with Filtek bulk fill composite; in group 2, the cavities were incrementally filled with Z250 conventional composite and in group 3, EQUIA Forte hybrid GI resin was used to fill the cavities. The teeth were subjected to thermal and then mechanical thermocycling. Afterwards, the teeth were immersed in 1% methylene blue solution. The teeth were then mesiodistally sectioned, and microleakage was evaluated at the occlusal and gingival margins under a stereomicroscope and a scanning electron microscope (SEM). The Shapiro-Wilk and Kruskal-Wallis tests were used to statistically analyze the data. Results There was no statistically significant difference in the mean microleakage of bulk fill and conventional composites and hybrid GI in the occlusal (P=0.495) or gingival (P=0.293) margins. The gingival microleakage was significantly higher than occlusal microleakage in all three groups (P<0.05). Conclusion Based on the results of the present study, microleakage of Filtek bulk fill composite is the same as that of Z250 conventional composite and EQUIA Forte hybrid GI

A novel method to design water spray cooling system to protect floating roof atmospheric storage tanks against fires

Hydrocarbon bulk storage tank fires are not very common, but their protection is essential due to severe consequences of such fires. Water spray cooling system is one of the most effective ways to reduce damages to a tank from a fire. Many codes and standards set requirements and recommendations to maximize the efficiency of water spray cooling systems, but these are widely different and still various interpretations and methods are employed to design such systems. This article provides a brief introduction to some possible design methods of cooling systems for protection of storage tanks against external non-contacting fires and introduces a new method namely “Linear Density Method” and compares the results from this method to the “Average Method” which is currently in common practice. The average Method determines the flow rate for each spray nozzle by dividing the total water demand by the number of spray nozzles while the Linear Density Method determines the nozzle flow rate based on the actual flow over the surface to be protected. The configuration of the system includes a one million barrel crude oil floating roof tank to be protected and which is placed one half tank diameter from a similar adjacent tank with a full surface fire. Thermal radiation and hydraulics are modeled using DNV PHAST Version 6.53 and Sunrise PIPENET Version 1.5.0.2722 software respectively. Spray nozzles used in design are manufactured by Angus Fire and PNR Nozzles companies. Schedule 40 carbon steel pipe is used for piping. The results show that the cooling system using the Linear Density Method consumes 3.55% more water than the design using the average method assuming a uniform application rate of 4.1 liters per minute. Despite higher water consumption the design based on Linear Density Method alleviates the problems associated with the Average Method and provides better protection

Ultraviolet-induced Surface Grafting of Octafluoropentyl Methacrylate on Polyether Ether Ketone for Inducing Antibiofilm Properties

Since octafluoropentyl methacrylate is an antifouling polymer, surface modification of polyether ether ketone with octafluoropentyl methacrylate is a practical approach to obtaining anti-biofilm biocompatible devices. In the current study, the surface treatment of polyether ether ketone by the use of ultraviolet irradiation, so as to graft (octafluoropentyl methacrylate) polymer chains, was initially implemented and then investigated. The Fourier-transform infrared and nuclear magnetic resonance spectra corroborated the appearance of new signals associated with the fluoroacrylate group. Thermogravimetric curves indicated enhanced asymmetry in the polymer structure due to the introduction of the said new groups. Measuring the peak area in differential scanning calorimetry experiments also showed additional bond formation. Static water contact angle measurements indicated a change in wettability to the more hydrophobic surface. The polyether ether ketone–octafluoropentyl methacrylate surface greatly reduced the protein adsorption. This efficient method can modulate and tune the surface properties of polyether ether ketone according to specific applications

Effect of cusp coverage and water storage on compressive strength of composite restorations of premolars

The aim of this study was to assess the effect of cusp coverage and water storage on compressive strength of composite restorations. This in vitro experimental study was conducted on 40 extracted human maxillary premolar teeth, which were randomly divided into four groups of 10. Mesio-occluso-distal (MOD) cavities were prepared in all teeth. The thickness of composite for cusp coverage was 1.5 mm in groups 1 and 3 and 2.5 mm in groups 2 and 4. Compressive strength (CS) was measured after 24 hours in groups 1 and 2 and after six months of water storage in groups 3 and 4. Two-way ANOVA was used to statistically analyze the data. The mean and standard error (SE) of compressive strength was 795.23 ± 35.18N in Group 1, 1232.52 ± 78.01N in Group 2, 617.18 ± 40.19N in Group 3 and 963.22 ± 50.05N in Group 4. Statistical analysis showed a significant difference in compressive strength measured after 24 hours (groups 1 and 3) and after six months of water storage (groups 2 and 4). The compressive strength of groups with 2.5 mm cusp coverage was significantly greater than that of groups with 1.5 mm cusp coverage

On the Degrees of Freedom of KK-User SISO Interference and X Channels with Delayed CSIT

The $K$-user single-input single-output (SISO) AWGN interference channel and $2\times K$ SISO AWGN X channel are considered where the transmitters have the delayed channel state information (CSI) through noiseless feedback links. Multi-phase transmission schemes are proposed for both channels which possess novel ingredients, namely, multi-phase partial interference nulling, distributed interference management via user scheduling, and distributed higher-order symbol generation. The achieved degrees of freedom (DoF) values are greater than the best previously known DoFs for both channels with delayed CSI at transmitters.Comment: 30 pages, 6 figures, 2 tables; Published in IEEE Transactions on Information Theory, Oct. 201