33,531 research outputs found
Activity of alumina supported fe catalysts for N2O decomposition: Effects of the iron content and thermal treatment
Indexación: Scopus.The activity of Fe2O3/Al2O3 catalysts prepared by impregnation of Al2O3 with different amounts of Fe and calcination temperatures (650 and 900 °C) in the direct N2O decomposition reaction was studied. High calcination temperature was introduced to study the effect of "aging", which are the conditions prevailing in the process-gas option for N2O abatement. The catalysts were characterized by BET, XRD, UV-DRS, and H2-TPR. The incorporation of Fe promotes the alumina phase transition (g-Al2O3 to a-Al2O3) when the catalysts are calcined at 900 °C, which is accompanied by a decrease in the specifc area. The activity of the catalysts and the specifc surface area depend on Fe loading and calcination temperature. It was found that highly dispersed Fe species are more active than bulk type Fe2O3 particles. We conclude that Fe2O3/Al2O3 catalysts prepared by impregnation method are active in the decomposition of N2O, to be used at low or high reaction temperatures (tail-gas or process-gas treatments, respectively), as part of nitric acid production plant. © 2018 Sociedad Chilena de Quimica. All rights reserved.https://scielo.conicyt.cl/pdf/jcchems/v62n4/0717-9324-jcchems-62-04-3752.pd
Short-Range Ordered Phase of the Double-Exchange Model in Infinite Dimensions
Using dynamical mean-field theory, we have evaluated the magnetic
instabilities and T=0 phase diagram of the double-exchange model on a Bethe
lattice in infinite dimensions. In addition to ferromagnetic (FM) and
antiferromagnetic (AF) phases, we also study a class of disordered phases with
magnetic short-range order (SRO). In the weak-coupling limit, a SRO phase has a
higher transition temperature than the AF phase for all fillings p below 1 and
can even have a higher transition temperature than the FM phase. At T=0 and for
small Hund's coupling J_H, a SRO state has lower energy than either the FM or
AF phases for 0.26\le p 0 limit
but appears for any non-zero value of J_H.Comment: 11 pages, 3 figures, published versio
The Equivalence Principle in the Non-baryonic Regime
We consider the empirical validity of the equivalence principle for
non-baryonic matter. Working in the context of the TH\epsilon\mu formalism, we
evaluate the constraints experiments place on parameters associated with
violation of the equivalence principle (EVPs) over as wide a sector of the
standard model as possible. Specific examples include new parameter constraints
which arise from torsion balance experiments, gravitational red shift,
variation of the fine structure constant, time-dilation measurements, and
matter/antimatter experiments. We find several new bounds on EVPs in the
leptonic and kaon sectors.Comment: 22 pages, late
Revised Pulsar Spindown
We address the issue of electromagnetic pulsar spindown by combining our
experience from the two limiting idealized cases which have been studied in
great extent in the past: that of an aligned rotator where ideal MHD conditions
apply, and that of a misaligned rotator in vacuum. We construct a spindown
formula that takes into account the misalignment of the magnetic and rotation
axes, and the magnetospheric particle acceleration gaps. We show that near the
death line aligned rotators spin down much slower than orthogonal ones. In
order to test this approach, we use a simple Monte Carlo method to simulate the
evolution of pulsars and find a good fit to the observed pulsar distribution in
the P-Pdot diagram without invoking magnetic field decay. Our model may also
account for individual pulsars spinning down with braking index n < 3, by
allowing the corotating part of the magnetosphere to end inside the light
cylinder. We discuss the role of magnetic reconnection in determining the
pulsar braking index. We show, however, that n ~ 3 remains a good approximation
for the pulsar population as a whole. Moreover, we predict that pulsars near
the death line have braking index values n > 3, and that the older pulsar
population has preferentially smaller magnetic inclination angles. We discuss
possible signatures of such alignment in the existing pulsar data.Comment: 8 pages, 7 figures; accepted to Ap
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A Simulated Microgravity Environment Causes a Sustained Defect in Epithelial Barrier Function.
Intestinal epithelial cell (IEC) junctions constitute a robust barrier to invasion by viruses, bacteria and exposure to ingested agents. Previous studies showed that microgravity compromises the human immune system and increases enteropathogen virulence. However, the effects of microgravity on epithelial barrier function are poorly understood. The aims of this study were to identify if simulated microgravity alters intestinal epithelial barrier function (permeability), and susceptibility to barrier-disrupting agents. IECs (HT-29.cl19a) were cultured on microcarrier beads in simulated microgravity using a rotating wall vessel (RWV) for 18 days prior to seeding on semipermeable supports to measure ion flux (transepithelial electrical resistance (TER)) and FITC-dextran (FD4) permeability over 14 days. RWV cells showed delayed apical junction localization of the tight junction proteins, occludin and ZO-1. The alcohol metabolite, acetaldehyde, significantly decreased TER and reduced junctional ZO-1 localization, while increasing FD4 permeability in RWV cells compared with static, motion and flask control cells. In conclusion, simulated microgravity induced an underlying and sustained susceptibility to epithelial barrier disruption upon removal from the microgravity environment. This has implications for gastrointestinal homeostasis of astronauts in space, as well as their capability to withstand the effects of agents that compromise intestinal epithelial barrier function following return to Earth
Feynman Path Integral on the Noncommutative Plane
We formulate Feynman path integral on a non commutative plane using coherent
states. The propagator for a free particle exhibits UV cut-off induced by the
parameter of non commutativity.Comment: 7pages, latex 2e, no figures. Accepted for publication on J.Phys.
What makes slow samples slow in the Sherrington-Kirkpatrick model
Using results of a Monte Carlo simulation of the Sherrington-Kirkpatrick
model, we try to characterize the slow disorder samples, namely we analyze
visually the correlation between the relaxation time for a given disorder
sample with several observables of the system for the same disorder sample.
For temperatures below but not too low, fast samples (small relaxation
times) are clearly correlated with a small value of the largest eigenvalue of
the coupling matrix, a large value of the site averaged local field probability
distribution at the origin, or a small value of the squared overlap is more robust) . There is a strong correlation between the values of
the relaxation time for two distinct values of the temperature, but this
correlation decreases as the system size is increased. This may indicate the
onset of temperature chaos
Differential geometry construction of anomalies and topological invariants in various dimensions
In the model of extended non-Abelian tensor gauge fields we have found new
metric-independent densities: the exact (2n+3)-forms and their secondary
characteristics, the (2n+2)-forms as well as the exact 6n-forms and the
corresponding secondary (6n-1)-forms. These forms are the analogs of the
Pontryagin densities: the exact 2n-forms and Chern-Simons secondary
characteristics, the (2n-1)-forms. The (2n+3)- and 6n-forms are gauge invariant
densities, while the (2n+2)- and (6n-1)-forms transform non-trivially under
gauge transformations, that we compare with the corresponding transformations
of the Chern-Simons secondary characteristics. This construction allows to
identify new potential gauge anomalies in various dimensions.Comment: 27 pages, references added, matches published versio
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