Activity of alumina supported fe catalysts for N2O decomposition: Effects of the iron content and thermal treatment

Indexación: Scopus.The activity of Fe2O3/Al2O3 catalysts prepared by impregnation of Al2O3 with different amounts of Fe and calcination temperatures (650 and 900 °C) in the direct N2O decomposition reaction was studied. High calcination temperature was introduced to study the effect of "aging", which are the conditions prevailing in the process-gas option for N2O abatement. The catalysts were characterized by BET, XRD, UV-DRS, and H2-TPR. The incorporation of Fe promotes the alumina phase transition (g-Al2O3 to a-Al2O3) when the catalysts are calcined at 900 °C, which is accompanied by a decrease in the specifc area. The activity of the catalysts and the specifc surface area depend on Fe loading and calcination temperature. It was found that highly dispersed Fe species are more active than bulk type Fe2O3 particles. We conclude that Fe2O3/Al2O3 catalysts prepared by impregnation method are active in the decomposition of N2O, to be used at low or high reaction temperatures (tail-gas or process-gas treatments, respectively), as part of nitric acid production plant. © 2018 Sociedad Chilena de Quimica. All rights reserved.https://scielo.conicyt.cl/pdf/jcchems/v62n4/0717-9324-jcchems-62-04-3752.pd

Short-Range Ordered Phase of the Double-Exchange Model in Infinite Dimensions

Using dynamical mean-field theory, we have evaluated the magnetic instabilities and T=0 phase diagram of the double-exchange model on a Bethe lattice in infinite dimensions. In addition to ferromagnetic (FM) and antiferromagnetic (AF) phases, we also study a class of disordered phases with magnetic short-range order (SRO). In the weak-coupling limit, a SRO phase has a higher transition temperature than the AF phase for all fillings p below 1 and can even have a higher transition temperature than the FM phase. At T=0 and for small Hund's coupling J_H, a SRO state has lower energy than either the FM or AF phases for 0.26\le p 0 limit but appears for any non-zero value of J_H.Comment: 11 pages, 3 figures, published versio

The Equivalence Principle in the Non-baryonic Regime

We consider the empirical validity of the equivalence principle for non-baryonic matter. Working in the context of the TH\epsilon\mu formalism, we evaluate the constraints experiments place on parameters associated with violation of the equivalence principle (EVPs) over as wide a sector of the standard model as possible. Specific examples include new parameter constraints which arise from torsion balance experiments, gravitational red shift, variation of the fine structure constant, time-dilation measurements, and matter/antimatter experiments. We find several new bounds on EVPs in the leptonic and kaon sectors.Comment: 22 pages, late

Revised Pulsar Spindown

We address the issue of electromagnetic pulsar spindown by combining our experience from the two limiting idealized cases which have been studied in great extent in the past: that of an aligned rotator where ideal MHD conditions apply, and that of a misaligned rotator in vacuum. We construct a spindown formula that takes into account the misalignment of the magnetic and rotation axes, and the magnetospheric particle acceleration gaps. We show that near the death line aligned rotators spin down much slower than orthogonal ones. In order to test this approach, we use a simple Monte Carlo method to simulate the evolution of pulsars and find a good fit to the observed pulsar distribution in the P-Pdot diagram without invoking magnetic field decay. Our model may also account for individual pulsars spinning down with braking index n < 3, by allowing the corotating part of the magnetosphere to end inside the light cylinder. We discuss the role of magnetic reconnection in determining the pulsar braking index. We show, however, that n ~ 3 remains a good approximation for the pulsar population as a whole. Moreover, we predict that pulsars near the death line have braking index values n > 3, and that the older pulsar population has preferentially smaller magnetic inclination angles. We discuss possible signatures of such alignment in the existing pulsar data.Comment: 8 pages, 7 figures; accepted to Ap

A Simulated Microgravity Environment Causes a Sustained Defect in Epithelial Barrier Function.

Intestinal epithelial cell (IEC) junctions constitute a robust barrier to invasion by viruses, bacteria and exposure to ingested agents. Previous studies showed that microgravity compromises the human immune system and increases enteropathogen virulence. However, the effects of microgravity on epithelial barrier function are poorly understood. The aims of this study were to identify if simulated microgravity alters intestinal epithelial barrier function (permeability), and susceptibility to barrier-disrupting agents. IECs (HT-29.cl19a) were cultured on microcarrier beads in simulated microgravity using a rotating wall vessel (RWV) for 18 days prior to seeding on semipermeable supports to measure ion flux (transepithelial electrical resistance (TER)) and FITC-dextran (FD4) permeability over 14 days. RWV cells showed delayed apical junction localization of the tight junction proteins, occludin and ZO-1. The alcohol metabolite, acetaldehyde, significantly decreased TER and reduced junctional ZO-1 localization, while increasing FD4 permeability in RWV cells compared with static, motion and flask control cells. In conclusion, simulated microgravity induced an underlying and sustained susceptibility to epithelial barrier disruption upon removal from the microgravity environment. This has implications for gastrointestinal homeostasis of astronauts in space, as well as their capability to withstand the effects of agents that compromise intestinal epithelial barrier function following return to Earth

Feynman Path Integral on the Noncommutative Plane

We formulate Feynman path integral on a non commutative plane using coherent states. The propagator for a free particle exhibits UV cut-off induced by the parameter of non commutativity.Comment: 7pages, latex 2e, no figures. Accepted for publication on J.Phys.

What makes slow samples slow in the Sherrington-Kirkpatrick model

Using results of a Monte Carlo simulation of the Sherrington-Kirkpatrick model, we try to characterize the slow disorder samples, namely we analyze visually the correlation between the relaxation time for a given disorder sample $J$ with several observables of the system for the same disorder sample. For temperatures below $T_c$ but not too low, fast samples (small relaxation times) are clearly correlated with a small value of the largest eigenvalue of the coupling matrix, a large value of the site averaged local field probability distribution at the origin, or a small value of the squared overlap $$. Within our limited data, the correlation remains as the system size increases but becomes less clear as the temperature is decreased (the correlation with$$ is more robust) . There is a strong correlation between the values of the relaxation time for two distinct values of the temperature, but this correlation decreases as the system size is increased. This may indicate the onset of temperature chaos

Differential geometry construction of anomalies and topological invariants in various dimensions

In the model of extended non-Abelian tensor gauge fields we have found new metric-independent densities: the exact (2n+3)-forms and their secondary characteristics, the (2n+2)-forms as well as the exact 6n-forms and the corresponding secondary (6n-1)-forms. These forms are the analogs of the Pontryagin densities: the exact 2n-forms and Chern-Simons secondary characteristics, the (2n-1)-forms. The (2n+3)- and 6n-forms are gauge invariant densities, while the (2n+2)- and (6n-1)-forms transform non-trivially under gauge transformations, that we compare with the corresponding transformations of the Chern-Simons secondary characteristics. This construction allows to identify new potential gauge anomalies in various dimensions.Comment: 27 pages, references added, matches published versio