A Rapid Method of Crude Oil Analysis Using FT-IR Spectroscopy

This study determines the viability of the use of Fourier Transform Infrared (FTIR) spectroscopy as a substitute to traditional petroleum geochemical methods for crude oil characterisation. IR spectra of Crude oil sample containing a mixture of both degraded (sample 151) and non-degraded (sample 145) oils at different concentrations were determined. The IR fingerprints agree with results obtained from GC analysis. Partial least square regression analysis was used to predict saturates for omitted mixtures (10 and 80% 151) and also saturates of five other samples (i.e. 145, 149, 172, H1 and AL10) within acceptable error limits. It therefore, follows, that although some improvements might still need to be made, FTIR spectroscopy can indeed be a viable, simple, cheaper and faster technique of crude oil characterisation compared with the traditional fractionation methods.Keywords: FTIR-ATR spectroscopy; GC-MS; Partial least squares (PLSR). Rapid analysis

Microwave assisted biodiesel production from Lagenaria vulgaris seed oil using amberlyst 15 ion exchange resin and eggshell as catalysts

The study involves the extraction of oil from the seeds of lagenaria vulgaris (Calabash) using soxhlet apparatus. The physicochemical properties of the calabash seeds oil analyzed were; crude oil yield (37.8%), density of oil (0.925g/cm3), acid value of oil (5.6mgKOH/g) and saponification value (190.1mgKOH/g).Catalytic transesterification was carried out using the oil produced in a microwave to yield biodiesel. A comparative analysis of the biodiesel produced from the extracted oil using two different catalysts; Amberlyst 15 ion exchange resin and calcium oxide (waste eggshell) was carried out. The biodiesel production was conducted under different catalyst concentrations, different temperature range and different time (minutes). The best yield of 95.07% was achieved with treated waste eggshell at 600C, 5% catalyst to oil ratio and 40% methanol to oil volume ratio after 40 minutes. Biodiesel characterization showed; specific gravity (0.890g/cm3), acid value (0.7mgKOH/g), API gravity (27.5g/cm3), kinematic viscosity (5.6mm2/s), cloud point (3.50C), pour point (-30C), copper strip corrosion test (1b), flash point (1380C), cetane/diesel index (35.1). The result shows that the biodiesel quality parameters were within the acceptable limits set by ASTM, although blends and additives maybe needed to improve performance.Keywords: Biodiesel, Transesterification, Amberlyst 15, Eggshel

In-situ regeneration of activated carbon with electric potential swing desorption (EPSD) for the H 2 S removal from biogas

In-situ regeneration of a granular activated carbon was conducted for the first time using electric potential swing desorption (EPSD) with potentials up to 30 V. The EPSD system was compared against a standard non-potential system using a fixed-bed reactor with a bed of 10 g of activated carbon treating a gas mixture with 10,000 ppm H2S. Breakthrough times, adsorption desorption volume, capacities, effect of regeneration and desorption kinetics were investigated. The analysis showed that desorption of H2S using the new EPSD system was 3 times quicker compared with the no potential system. Hence, physical adsorption using EPSD over activated carbon is efficient, safe and environmental friendly and could be used for the in-situ regeneration of granular activated carbon without using a PSA and/or TSA system. Additionally, adsorption and desorption cycles can be obtained with a classical two column system, which could lead towards a more efficient and economic biogas to biomethane process