61 research outputs found
Quaterpyridine Ligands for Panchromatic Ru(II) Dye Sensitizers
A new general synthetic access to carboxylated quaterpyridines (qpy), of interest as ligands for panchromatic dyesensitized solar cell organometallic sensitizers, is presented. The strategic step is a Suzuki−Miyaura cross-coupling reaction,
which has allowed the preparation of a number of representative unsubstituted and alkyl and (hetero)aromatic substituted qpys.
To bypass the poor inherent stability of 2-pyridylboronic acid derivatives, we successfully applied N-methyliminodiacetic acid
(MIDA) boronates as key reagents, obtaining the qpy ligands in good yields up to (quasi)gram quantities. The structural,
spectroscopic (NMR and UV−vis), electrochemical, and electronic characteristics of the qpy have been experimentally and
computationally (DFT) investigated. The easy access to the bis-thiocyanato Ru(II) complex of the parent species of the qpy
series, through an efficient route which bypasses the use of Sephadex column chromatography, is shown. The bis-thiocyanato
Ru(II) complex has been spectroscopically (NMR and UV−vis), electrochemically, and computationally investigated, relating its
properties to those of previously reported Ru(II)−qpy complexes.“This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Organic Chemistry], copyright © American Chemical Society after peer review and technical editing by the publisher
Design of Ru(II) sensitizers endowed by three anchoring units for adsorption mode and light harvesting optimization
We report the design, synthesis and computational investigation of a class of Ru(II)-dyes based on mixed bipyridine ligands for use in dye-sensitized solar cells. These dyes are designed to preserve the optimal anchoring mode of the prototypical N719 sensitizer by three carboxylic groups, yet allowing for tunable optimization of their electronic and optical properties by selective substitution at one of the 4-4′ positions of a single bipyridine ligand with π-excessive heteroaromatic groups. We used Density Functional Theory/Time Dependent Density Functional Theory calculations to analyze the electronic structure and optical properties of the dye and to investigate the dye adsorption mode on a TiO2 nanoparticle model. Our results show that we are effectively able to introduce three carboxylic anchoring units into the dye and achieve at the same time an enhanced dye light harvesting, demonstrating the design concept. As a drawback of this type of dyes, the synthesis leads to a mixture of dye isomers, which are rather tedious to separate
NUOVI COMPOSTI OTTICAMENTE SENSIBILI AI COMPOSTI ELETTRONÂPOVERI
sintesi di nuove molecole organiche per applicazioni sensoristich
NUOVI COMPOSTI OTTICAMENTE SENSIBILI AI COMPOSTI ELETTRON-POVERI
sintesi di nuove molecole organiche per applicazioni sensoristich
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