Thin films of unsubstituted and fluorinated palladium phthalocyanines: structure and sensor response toward ammonia and hydrogen

In the present work, we study and compare the structure and sensing properties of thin films of unsubstituted palladium phthalocyanine (PdPc) and hexadecafluorosubstituted palladium phthalocyanine (PdPcF16). Thin films of PdPc and PdPcF16 were obtained by the method of organic molecular beam deposition and their structure was studied using UV-visible spectroscopy, X-ray diffraction and atomic force microscopy techniques. The electrical sensor response of PdPc films toward ammonia and hydrogen was investigated and compared with that of PdPcF16 films. The nature of interaction between the phthalocyanines films and some gaseous analyte molecules has been clarified using Quantum chemical (DFT) calculations

Effect of fluorosubstitution on the structure of single crystals, Effect of fluorosubstitution on the structure of single crystals,thin films and spectral properties of palladium phthalocyanines

In this work, the crystalline structure of single crystals grown by vacuum sublimation of unsubstituted palladium phthalocyanines (PdPc), its tetrafluorinated (PdPcF4) and hexadecafluorinated (PdPcF16) derivatives have been investigated using X-ray diffraction measurements. Two crystalline phases have been identified for PdPc; the molecules in both phases crystallize in stacks with herringbone arrangement in the monoclinic space groups (C2/c for -PdPc; P21/n for -PdPc). Both PdPcF4 and PdPcF16 crystallize in the triclinic P-1 space group, forming stacks of molecules in columnar arrangement with molecules in adjacent columns are aligned parallel to one another. X-ray diffraction measurements have also been used to elucidate the structural features and molecular orientation of thin films of PdPc, PdPcF4 and PdPcF16, grown by organic molecular beam deposition at different substrate temperatures. The effect of fluorosubstitution on UV-visible optical absorption and vibrational spectra of palladium phthalocyanine derivatives is also discussed

In-medium modification of dijets in PbPb collisions at √sNN = 5.02 TeV

Modifications to the distribution of charged particles with respect to high transverse momentum (pT) jets passing through a quark-gluon plasma are explored using the CMS detector. Back-to-back dijets are analyzed in lead-lead and proton-proton collisions at √sNN = 5.02 TeV via correlations of charged particles in bins of relative pseudorapidity and angular distance from the leading and subleading jet axes. In comparing the lead-lead and proton-proton collision results, modifications to the charged-particle relative distance distribution and to the momentum distributions around the jet axis are found to depend on the dijet momentum balance xj , which is the ratio between the subleading and leading jet pT. For events with xj ≈ 1, these modifications are observed for both the leading and subleading jets. However, while subleading jets show significant modifications for events with a larger dijet momentum imbalance, much smaller modifications are found for the leading jets in these events

Search for top squark pair production using dilepton final states in pp collision data collected at √s=13TeV

A search is presented for supersymmetric partners of the top quark (top squarks) in final states with two oppositely charged leptons (electrons or muons), jets identified as originating from bbquarks, and missing transverse momentum. The search uses data from proton-proton collisions at √s=13TeV collected with the CMS detector, corresponding to an integrated luminosity of 137fb−1. Hypothetical signal events are efficiently separated from the dominant top quark pair production background with requirements on the significance of the missing transverse momentum and on transverse mass variables. No significant deviation is observed from the expected background. Exclusion limits are set in the context of simplified supersymmetric models with pair-produced lightest top squarks. For top squarks decaying exclusively to a top quark and a lightest neutralino, lower limits are placed at 95% confidence level on the masses of the top squark and the neutralino up to 925 and 450GeV, respectively. If the decay proceeds via an intermediate chargino, the corresponding lower limits on the mass of the lightest top squark are set up to 850GeV for neutralino masses below 420GeV. For top squarks undergoing a cascade decay through charginos and sleptons, the mass limits reach up to 1.4TeV and 900GeV respectively for the top squark and the lightest neutralino

Measurements of the differential cross sections of the production of Z + jets and γ + jets and of Z boson emission collinear with a jet in pp collisions at √s = 13 TeV

Measurements of the differential cross sections of Z + jets and γ + jets production, and their ratio, are presented as a function of the boson transverse momentum. Measurements are also presented of the angular distribution between the Z boson and the closest jet. The analysis is based on pp collisions at a center-of-mass energy of 13 TeV corresponding to an integrated luminosity of 35.9 fb−1 recorded by the CMS experiment at the LHC. The results, corrected for detector effects, are compared with various theoretical predictions. In general, the predictions at higher orders in perturbation theory show better agreement with the measurements. This work provides the first measurement of the ratio of the differential cross sections of Z + jets and γ + jets production at 13 TeV, as well as the first direct measurement of Z bosons emitted collinearly with a jet

Measurements of pp→ZZ production cross sections and constraints on anomalous triple gauge couplings at √s=13TeV

The production of Z boson pairs in proton-proton (pppp) collisions, pp→(Z/γ∗)(Z/γ∗)→2ℓ2ℓ′, where ℓ,ℓ′=e or μ, is studied at a center-of-mass energy of 13TeV with the CMS detector at the CERN LHC. The data sample corresponds to an integrated luminosity of 137fb−1, collected during 2016-2018. The ZZ production cross section, σtot(pp→ZZ)=17.4±0.3(stat)±0.5(syst)±0.4(theo)±0.3(lumi) pb, measured for events with two pairs of opposite-sign, same-flavor leptons produced in the mass region 60<mℓ+ℓ−<120GeV is consistent with standard model predictions. Differential cross sections are also measured and agree with theoretical predictions. The invariant mass distribution of the four-lepton system is used to set limits on anomalous ZZZ and ZZγ couplings

Search for dark matter produced in association with a leptonically decaying Z boson in proton-proton collisions at √s=13TeV

A search for dark matter particles is performed using events with a Z boson candidate and large missing transverse momentum. The analysis is based on proton-proton collision data at a center-of-mass energy of 13TeV, collected by the CMS experiment at the LHC in 2016-2018, corresponding to an integrated luminosity of 137fb−1. The search uses the decay channels Z→ee and Z→μμ. No significant excess of events is observed over the background expected from the standard model. Limits are set on dark matter particle production in the context of simplified models with vector, axial-vector, scalar, and pseudoscalar mediators, as well as on a two-Higgs-doublet model with an additional pseudoscalar mediator. In addition, limits are provided for spin-dependent and spin-independent scattering cross sections and are compared to those from direct-detection experiments. The results are also interpreted in the context of models of invisible Higgs boson decays, unparticles, and large extra dimensions

Study of Drell-Yan dimuon production in proton-lead collisions at √sNN = 8.16 TeV

Differential cross sections for the Drell-Yan process, including Z boson production, using the dimuon decay channel are measured in proton-lead (pPb) collisions at a nucleon-nucleon centre-of-mass energy of 8.16 TeV. A data sample recorded with the CMS detector at the LHC is used, corresponding to an integrated luminosity of 173 nb−1. The differential cross section as a function of the dimuon mass is measured in the range 15-600 GeV, for the first time in proton-nucleus collisions. It is also reported as a function of dimuon rapidity over the mass ranges 15-60 GeV and 60-120 GeV, and ratios for the p-going over the Pb-going beam directions are built. In both mass ranges, the differential cross sections as functions of the dimuon transverse momentum pT and of a geometric variable ϕ* are measured, where ϕ* highly correlates with pT but is determined with higher precision. In the Z mass region, the rapidity dependence of the data indicate a modification of the distribution of partons within a lead nucleus as compared to the proton case. The data are more precise than predictions based upon current models of parton distributions

Evidence for Higgs boson decay to a pair of muons

Evidence for Higgs boson decay to a pair of muons is presented. This result combines searches in four exclusive categories targeting the production of the Higgs boson via gluon fusion, via vector boson fusion, in association with a vector boson, and in association with a top quark-antiquark pair. The analysis is performed using proton-proton collision data at √s = 13 TeV, corresponding to an integrated luminosity of 137 fb−1, recorded by the CMS experiment at the CERN LHC. An excess of events over the back- ground expectation is observed in data with a significance of 3.0 standard deviations, where the expectation for the standard model (SM) Higgs boson with mass of 125.38 GeV is 2.5. The combination of this result with that from data recorded at √s = 7 and 8 TeV, corresponding to integrated luminosities of 5.1 and 19.7 fb−1, respectively, increases both the expected and observed significances by 1%. The measured signal strength, relative to the SM prediction, is 1.19+0.40−0.39(stat)+0.15−0.14(syst). This result constitutes the first evidence for the decay of the Higgs boson to second generation fermions and is the most precise measurement of the Higgs boson coupling to muons reported to date

Search for the lepton flavor violating decay τ → 3μ in proton-proton collisions at √s = 13 TeV

Results are reported from a search for the lepton flavor violating decay τ → 3μ in proton-proton collisions at √s = 13 TeV. The data sample corresponds to an integrated luminosity of 33.2 fb−1 recorded by the CMS experiment at the LHC in 2016. The search exploits τ leptons produced in both W boson and heavy-flavor hadron decays. No significant excess above the expected background is observed. An upper limit on the branching fraction ℬ(τ → 3μ) of 8.0 × 10−8 at 90% confidence level is obtained, with an expected upper limit of 6.9 × 10−8