Theory of coherent phonons in carbon nanotubes and graphene nanoribbons

We survey our recent theoretical studies on the generation and detection of coherent radial breathing mode (RBM) phonons in single-walled carbon nanotubes and coherent radial breathing like mode (RBLM) phonons in graphene nanoribbons. We present a microscopic theory for the electronic states, phonon modes, optical matrix elements and electronﾖphonon interaction matrix elements that allows us to calculate the coherent phonon spectrum. An extended tight-binding (ETB) model has been used for the electronic structure and a valence force field (VFF) model has been used for the phonon modes. The coherent phonon amplitudes satisfy a driven oscillator equation with the driving term depending on the photoexcited carrier density. We discuss the dependence of the coherent phonon spectrum on the nanotube chirality and type, and also on the graphene nanoribbon mod number and class (armchair versus zigzag). We compare these results with a simpler effective mass theory where reasonable agreement with the main features of the coherent phonon spectrum is found. In particular, the effective mass theory helps us to understand the initial phase of the coherent phonon oscillations for a given nanotube chirality and type. We compare these results to two different experiments for nanotubes: (i) micelle suspended tubes and (ii) aligned nanotube films. In the case of graphene nanoribbons, there are no experimental observations to date. We also discuss, based on the evaluation of the electronﾖphonon interaction matrix elements, the initial phase of the coherent phonon amplitude and its dependence on the chirality and type. Finally, we discuss previously unpublished results for coherent phonon amplitudes in zigzag nanoribbons obtained using an effective mass theory

Strategies for ideal indoor environments towards low/zero carbon buildings through a biomimetic approach

Biomimicry is a relatively new discipline of applied science that seeks inspiration from natural systems for innovative solutions to human problems. Taking nature as ‘model, mentor and measure’ receives wide acceptance in the field of architecture but predominantly in conceptualising novel forms. The biomimicry concept is comprehensively analysed for its ability to provide more sustainable and possibly even regenerative built environments. As part of this study, first, various frameworks for approaching ‘biomimicry’ in general are discussed and then relevant examples pertaining to architecture are evaluated. Case studies are critiqued with respect to varied levels of sustainability achieved and its causative factors. In the second part, an approach model for ‘biomimetic architecture’ in the context of Mumbai is presented and applicable strategies based on climatic adaptation are suggested using local biodiversity as a library of organisms. The generic example of ‘human skin’ addressing the same adaptation is analysed and complemented by a state-of-the-art case study on similar lines. The results achieved clearly reveal that biomimicry is a successful approach to design and operate the sustainable built environments for the buildings of the future

Redesigning production systems

If it was possible to wind back the clock on the first Industrial Revolution, then a redesign of production systems, based on the information available now, would focus on reducing environmental impacts, maximising resources and adding value to all products created, as well as taking into account the health and wellbeing of workers and the distribution of populations. Additive manufacturing, combined with digital communication technologies, delivers the possibility that many of the goals can be achieved—leading to a much healthier planet. Based on current research into sustainability and additive manufacturing outcomes, this chapter provides a vision for the redesign of current production systems, supply chains and values that serves as starting point for re-establishing the human relationship with manufacturing and business practice. Current drivers for change are discussed and opportunities for reducing the environmental impact of production systems directly enabled by additive manufacturing are then considered. These are based on integrating additive manufacturing into the supply chain and the potential impact on the development cycle, inventory management, logistic postponement and the management of spare parts