Fabrication of thin film solar cell materials by APCVD

Thin film solar cells are currently being implemented commercially as they reduce the amount of semiconductor material required for each cell when compared to silicon wafers, thereby lowering the cost of production. Currently two direct band gap chalcogenide thin-film technologies, CdTe and CuInGa(S,Se)2 (CIGS), yield the highest reported power conversion efficiencies of 16.5% and 20.3%, respectively. In addition, Cu2ZnSnS4 (CZTS) is one of the most promising chalcogenide thin film photovoltaic absorber materials; with an optimal band gap of about 1.5 eV. More importantly, CZTS consists of abundant and non-toxic elements, so research on CZTS thin-film solar cells has been increasing significantly in recent years. Moreover, Sb2S3 based chalcogenide thin films have been proposed for use in photovoltaic applications. The preparation of chalcogenide thin films solar cells commonly use physical vapour deposition methods including thermal/e-beam evaporation, sputtering, and pulsed laser deposition, electrochemical deposition, spray pyrolysis, solution-based synthesis, followed by the sulfurization or selenization annealing process. In this paper, we report a non-vacuum process, using atmospheric pressure chemical vapour deposition (APCVD), to fabricate chalcogenide thin film solar cell materials as well as transparent conductive oxide (TCO) thin films. The optical, electrical, and structural properties of these materials were characterized by UV-VIS-NIR, four-point probes, SEM, EDX, XRD, Micro-Raman

Dynamic whole-body motion generation under rigid contacts and other unilateral constraints

The most widely used technique for generating wholebody motions on a humanoid robot accounting for various tasks and constraints is inverse kinematics. Based on the task-function approach, this class of methods enables the coordination of robot movements to execute several tasks in parallel and account for the sensor feedback in real time, thanks to the low computation cost. To some extent, it also enables us to deal with some of the robot constraints (e.g., joint limits or visibility) and manage the quasi-static balance of the robot. In order to fully use the whole range of possible motions, this paper proposes extending the task-function approach to handle the full dynamics of the robot multibody along with any constraint written as equality or inequality of the state and control variables. The definition of multiple objectives is made possible by ordering them inside a strict hierarchy. Several models of contact with the environment can be implemented in the framework. We propose a reduced formulation of the multiple rigid planar contact that keeps a low computation cost. The efficiency of this approach is illustrated by presenting several multicontact dynamic motions in simulation and on the real HRP-2 robot

Strain engineering in graphene by laser irradiation

We demonstrate that the Raman spectrum of graphene on lithium niobate can be controlled locally by continuous exposure to laser irradiation. We interpret our results in terms of changes to doping and mechanical strain and show that our observations are consistent with light-induced gradual strain relaxation in the graphene layer

Chilled Water Storage Feasibility with District Cooling Chiller in Tropical Environment

The difficulties of efficiently operating a chiller cooling system are manifest in the high-energy consumption under partial-cooling loads. The performance of a chiller cooling system declines when operating away from the optimal design conditions, which is typically 75% of chiller capacity. One pathway has been found to overcome this problem using multiple smaller chillers within the same chiller plant, accompanied by a smart control system that is designed and constructed based on the cooling demand profile. Thermal energy storage integration with chiller cooling system is proposed to shave the cooling peak demand. This can be achieved by storing chilled water during the lower electricity-tariff period by the thermal energy storage system, which will then be discharged during the higher tariff-rate, thus, aiming for sustainable operating cost. The present paper studies the feasibility of sensible thermal energy storage to be integrated with two chillers, of 30-ton capacity each, under hot-and-humid climates. A computational model validated with experimental results is developed for three chiller cooling system case scenarios. The smart control scenario, as well as the thermal energy storage scenario results, showed great potential for energy and electricity cost saving. In addition, the carbon dioxide emissions reduction is calculated based on the amount of energy saving

IDENTIFICATION AND QUANTIFICATION OF PHOSPHODIESTERASE-5 INHIBITORS AS ADULTERANTS IN DIETARY SUPPLEMENTS MARKED FOR SEXUAL ENHANCEMENT IN THE LEBANESE MARKET

Objective: Ultraviolet Visible spectrophotometric was adopted to identify and quantify any adulteration with PDE-5 inhibitors (Sildenafil and Tadalafil) in selected dietary supplements used for sexual enhancement in the Lebanese market Methods: Nine dietary supplements, randomly collected from Lebanese pharmacies, were screened for Sildenafil and Tadalafil using UV-spectrophotometry for both qualitative and quantitative detection. Results: Tadalafil was detected in one sample at a dose of 59 mg/dosage unit, with the maximal recommended dose being 20 mg. Sildenafil was detected in five samples at doses ranging from 11.7 to 188.2 mg/dosage unit, with the maximal recommended dose being 100 mg. Conclusion: This study demonstrates that regular analysis of supposed dietary supplements is needed for more effective quality control and health promotion. The method described for the extraction, identification and quantification of Tadalafil and Sildenafil would be useful for regulatory detection of adulterations

ZODIAC LIGHT DETECTION BASED ON SKY QUALITY METER (SQM) DATA: PRELIMINARY STUDY

Zodiacal light is a night sky phenomenon that can occur before or after dusk. Additionally, zodiacal light is referred to as false dawn (fajar kadzib) or false dusk. Zodiacal light is emitted by the dust leftovers of asteroids, comets, and other extraterrestrial objects colliding along the planet Mercury's orbit to Mars. This remaining material orbits the Sun in the same direction as the four planets. When the Sun illuminates the leftover dust, it appears as a zodiacal light in the hemisphere that experiences dawn or dusk. By using linear fittings we detect the presence of zodiacal light on the light curve of the night skybrightness. The Observations were made using a digital camera and SQM. From a number of observational data obtained at six locations, it shows that there is an identical linear pattern. From this linear model, it can be seen that the zodiacal light has been observed since the sun's position at -60 degrees below the horizon. Recognizing the presence of the zodiacal light is very important to know the time of the appearance of true dawn which is the beginning of the time for the dawn prayer

ZODIAC LIGHT DETECTION BASED ON SKY QUALITY METER (SQM) DATA: PRELIMINARY STUDY

Zodiacal light is a night sky phenomenon that can occur before or after dusk. Additionally, zodiacal light is referred to as false dawn (fajar kadzib) or false dusk. Zodiacal light is emitted by the dust leftovers of asteroids, comets, and other extraterrestrial objects colliding along the planet Mercury's orbit to Mars. This remaining material orbits the Sun in the same direction as the four planets. When the Sun illuminates the leftover dust, it appears as a zodiacal light in the hemisphere that experiences dawn or dusk. By using linear fittings we detect the presence of zodiacal light on the light curve of the night skybrightness. The Observations were made using a digital camera and SQM. From a number of observational data obtained at six locations, it shows that there is an identical linear pattern. From this linear model, it can be seen that the zodiacal light has been observed since the sun's position at -60 degrees below the horizon. Recognizing the presence of the zodiacal light is very important to know the time of the appearance of true dawn which is the beginning of the time for the dawn prayer

Crystallisation study of the Cu₂ZnSnS₄ chalcogenide material for solar applications

Second generation thin-film chalcogenide materials, in particular CuInGa(S,Se)2 (CIGS) and CdTe, have been among the most promising and quickly became commercial candidates for large-scale PV manufacturing. These materials offer stable and efficient (above 10%) photovoltaic modules fabricated by scalable thin-film technologies and cell efficiencies above 20 % (CIGS). Indium-free kesterite-related materials such as Cu2ZnSnS4 have attracted significant research interest due to their similar properties to CIGS. In these materials, indium is replaced with earth-abundant zinc and tin metals. The quaternary semiconductor Cu2ZnSnS4(CZTS) is a relatively new photovoltaic material and is expected to be interesting for environmentally amenable solar cells, as its constituents are nontoxic and abundant in the Earth's crust. The CZTS thin films show p-type conductivity, a band gap of 1.44–1.51 eV that is ideal to achieve the highest solar-cell conversion efficiency, and relatively high optical absorption in the visible light range

Ultra low power consuming thermally stable sulphide materials for resistive and phase change memristive application

The use of conventional chalcogenide alloys in rewritable optical disks and the latest generation of electronic memories (phase change and nano-ionic memories) has provided clear commercial and technological advances for the field of data storage, by virtue of the many well-known attributes, in particular scaling, cycling endurance and speed, that these chalcogenide materials offer. While the switching power and current consumption of established germanium antimony telluride based phase change memory cells are a major factor in chip design in real world applications, the thermal stability and high on-state power consumption of these device can be a major obstacle in the path to full commercialization. In this work we describe our research in material discovery and prototype device fabrication and characterization, which through high throughput screening has demonstrated thermally stable, low current consuming chalcogenides for applications in PCRAM and oxygen doped chalcogenides for RRAM which significantly outperform the current contenders