Estudo e caracterização de espécies portuguesas de madeira termicamente modificada

A modificação térmica tem-se revelado um método eficaz na melhoria da durabilidade de elementos de madeira. Até ao momento, as aplicações da madeira termicamente modificada (MTM) têm sido limitadas a revestimentos já que o tratamento térmico de tratamento conduz a uma redução significativa das resistências mecânicas da madeira. Contudo, este tratamento térmico poderá valorizar e potenciar a utilização de espécies de madeira menos utilizadas na construção, como são o Eucalipto e o Pinho bravo nacional. Com o objetivo de avaliar o efeito do tratamento térmico nas espécies referidas e, complementarmente, na madeira de Faia e Freixo, realizou-se uma campanha experimental composta por ensaios de caracterização mecânica (compressão paralela às fibras e flexão) e de estabilidade dimensional (retração, inchamento e teor de água de equilíbrio (TAE)). Para efeitos de comparação, todos os ensaios envolveram séries de provetes de cada espécie de madeira natural e MTM. Os resultados obtidos são coerentes com a bibliografia disponível, o aumento da estabilidade dimensional, assim como a diminuição do TAE e das propriedades mecânicas de flexão foram verificadas, permitindo, assim, avaliar a influência da modificação térmica nas propriedades de espécies de madeira presentes em Portugal.The thermal modification has proved to be an effective method to improve the durability of wood elements. Until the moment, applications of thermally modified wood (MTM) have been limited to non-structural applications, because the heat treatment leads to a significant reduction in the mechanical performance of wood. However, this heat treatment can promote the use of less used wood species in construction, as the national Eucalyptus and Pine. In order to evaluate the effect of heat treatment on the species of Pine, Eucalyptus, Beech and Ash, was held an experimental program that consisted in mechanical characterization tests (compression parallel to grain and flexion) and tests of dimensional stability (shrinkage, swelling and equilibrium moisture content (EMC)). For comparison, all tests were made with samples of non-modified and thermally modified wood. The results are consistent with the available literature, the dimensional stability increased, as well as the reduction of TAE and mechanical properties, allowing the evaluation of the thermal modification on the properties of wood species present in Portugal

Systems for superficial protection of concretes

Nowadays, it is consensual that the biggest degradation of concrete happens from outside to inside actions, due to the penetration of moisture, active gases and aggressive ions, by mechanical, physical and chemical causes that frequently act together. A low porosity, permeability and concrete penetration to moisture and gases are the first lines of defence against several deterioration mechanisms. The durability of concrete depends largely on how hard or easy fluids (water, carbon dioxide, oxygen) in liquid or gas form can migrate through the concrete hardened mass. When selecting the paint coating for concrete protection, importance is given to the properties of diffusion and permeability resistance, besides the properties of durability and chemical resistance. The paint coatings must stop the penetration of water and delay the influence of aggressive agents (CO2, SO2, Cl- ions), allowing the structure to breathe by a water vapour diffusion mechanism. Through tests of capillarity absorption, immersion absorption, porosity, water and oxygen permeability, a comparison was made between painted and non painted concrete specimens. Three different coating types were tested: silicon varnish; acrylic and epoxy paints. The results showed that, in general, all coatings reduce the porosity and the permeability. The epoxy paints proved to be the best ones

Unified description of the dc conductivity of monolayer and bilayer graphene at finite densities based on resonant scatterers

We show that a coherent picture of the dc conductivity of monolayer and bilayer graphene at finite electronic densities emerges upon considering that strong short-range potentials are the main source of scattering in these two systems. The origin of the strong short-range potentials may lie in adsorbed hydrocarbons at the surface of graphene. The equivalence among results based on the partial-wave description of scattering, the Lippmann-Schwinger equation, and the T-matrix approach is established. Scattering due to resonant impurities close to the neutrality point is investigated via a numerical computation of the Kubo formula using a kernel polynomial method. We find that relevant adsorbate species originate impurity bands in monolayer and bilayer graphene close to the Dirac point. In the midgap region, a plateau of minimum conductivity of about $e^2/h$ (per layer) is induced by the resonant disorder. In bilayer graphene, a large adsorbate concentration can develop an energy gap between midgap and high-energy states. As a consequence, the conductivity plateau is supressed near the edges and a "conductivity gap" takes place. Finally, a scattering formalism for electrons in biased bilayer graphene, taking into account the degeneracy of the spectrum, is developed and the dc conductivity of that system is studied.Comment: 25 pages, 13 figures. published version: appendixes improved, references added, abstract and title slightly changed, plus other minor revision

Designer spin-orbit superlattices: symmetry-protected Dirac cones and spin Berry curvature in two-dimensional van der Waals metamaterials

The emergence of strong relativistic spin-orbit effects in low-dimensional systems provides a rich opportunity for exploring unconventional states of matter. Here, we present a route to realise tunable relativistic band structures based on the lateral patterning of proximity-induced spin-orbit coupling. The concept is illustrated on a patterned graphene–transition metal dichalcogenide heterostructure, where the spatially periodic spin-orbit coupling induces a rich mini-band structure featuring massless and massive Dirac bands carrying large spin Berry curvature. The envisaged systems support robust and gate-tunable spin Hall responses driven by the quantum geometry of mini-bands, which can be tailored through metasurface fabrication methods and twisting effects. These findings open pathways to two-dimensional quantum material design and low-power spintronic applications

Avaliação do módulo de elasticidade de betões de elevado desempenho com cinzas volantes

Os betões de elevado desempenho (BED) geralmente recorrem a materiais e a processos de fabrico de custo mais elevado que o dos betões correntes. Este facto tem condicionado a aplicação destes betões a obras especiais, apesar dos benefícios mecânicos e físicos que resultam a longo prazo poderem superar o maior investimento inicial. Nos últimos anos tem-se desenvolvido BED de custo controlado, substituindo-se parte de cimento por cinzas volantes e adoptando-se materiais e procedimentos de fabrico correntes. Neste trabalho, o módulo de elasticidade dos BED desenvolvidos é determinado experimentalmente e comparado com o obtido com formulações regulamentares e aplicando modelos baseados na teoria dos materiais compósitos

Considerações gerais sobre organogênese.

bitstream/CNPA/18322/1/DOC150.pd