Optimization of Friction Stir Welding Parameters of AA5052-H32 Aluminium Alloy using Taguchi and Taguchi-Pareto Methods

It is difficult to improve the quality of friction stir welded joints of AA5052-H32 material because of scarce metrics on its concurrent optimization and prioritization. However, the objective of this article is to obtain optimal parametric values and identify important parameters using the Taguchi-Pareto method during the friction stir welding process of AA5052-H32 material. Then the ranks, delta values and optimal parameters are determined. The critical parameters identified for the friction stir welding process are the tool pin, rotational speed, welding speed and tool angle. When comparing the results of these parameters using the Taguchi method and Taguchi-Pareto method, the rotational speed retained its first position in both methods; the tool tilt angle gained the second position in the Taguchi-Pareto method from its third position when only the Taguchi method was considered. The welding speed became the third position in the Taguchi-Pareto method against the second position that it had in the Taguchi method. However, the tool pin profile retained its last position in both methods. Consequently, the rotational speed is the best parameter while the tool pin profile is the worst parameter. For the Taguchi-Pareto method, the optimal parametric setting is TPP2/TPP4RS1WS4TTA3. This is interpreted as cylindrical tapered or square tapered for the tool profile, 40 rpm of rotational speed, 75 mm/min of welding speed and 1.5° of tool tilt angle. The novelty of this study is the scope of analysis of the AA5052-H32 material that extends beyond the Taguchi method to the Taguchi-Pareto method where the concurrent optimization and prioritization of friction welding parameters are achieved

Cu and Ni Co-Sputtered Heteroatomic Thin Film for Enhanced Nonenzymatic Glucose Detection

In this work, we report a wafer-scale and chemical-free fabrication of nickel (Ni) and copper (Cu) heteroatomic Cu–Ni thin films using RF magnetron sputtering technique for non-enzymatic glucose sensing application. The as-prepared wafer-scale Cu–Ni thin films exhibits excellent electrocatalytic activity toward glucose oxidation with a 1.86 μM detection limit in the range of 0.01 mM to 20 mM range. The Cu–Ni film shows 1.3- and 5.4-times higher glucose oxidation activity in comparison to the Cu and Ni electrodes, respectively. The improved electrocatalytic activity is attributed to the synergistic effect of the bimetallic catalyst and high density of grain boundaries. The Cu–Ni electrodes also possessed excellent anti-interference characteristics. These results indicate that Cu–Ni heteroatomic thin film can be a potential candidate for the development of non-enzymatic glucose biosensor because of its chemical free synthesis, excellent reproducibility, reusability, and long-term stability

Cu and Ni Co-sputtered heteroatomic thin film for enhanced nonenzymatic glucose detection

In this work, we report a wafer-scale and chemical-free fabrication of nickel (Ni) and copper (Cu) heteroatomic Cu–Ni thin films using RF magnetron sputtering technique for non-enzymatic glucose sensing application. The as-prepared wafer-scale Cu–Ni thin films exhibits excellent electrocatalytic activity toward glucose oxidation with a 1.86 μM detection limit in the range of 0.01 mM to 20 mM range. The Cu–Ni film shows 1.3- and 5.4-times higher glucose oxidation activity in comparison to the Cu and Ni electrodes, respectively. The improved electrocatalytic activity is attributed to the synergistic effect of the bimetallic catalyst and high density of grain boundaries. The Cu–Ni electrodes also possessed excellent anti-interference characteristics. These results indicate that Cu–Ni heteroatomic thin film can be a potential candidate for the development of non-enzymatic glucose biosensor because of its chemical free synthesis, excellent reproducibility, reusability, and long-term stability

Reduced metal nanocatalysts for selective electrochemical hydrogenation of biomass-derived 5-(hydroxymethyl)furfural to 2,5-bis(hydroxymethyl)furan in ambient conditions

Selective electrochemical hydrogenation (ECH) of biomass-derived unsaturated organic molecules has enormous potential for sustainable chemical production. However, an efficient catalyst is essential to perform an ECH reaction consisting of superior product selectivity and a higher conversion rate. Here, we examined the ECH performance of reduced metal nanostructures, i.e., reduced Ag (rAg) and reduced copper (rCu) prepared via electrochemical or thermal oxidation and electrochemical reduction process, respectively. Surface morphological analysis suggests the formation of nanocoral and entangled nanowire structure formation for rAg and rCu catalysts. rCu exhibits a slight enhancement in ECH reaction performance in comparison to the pristine Cu. However, the rAg exhibits more than two times higher ECH performance without compromising the selectivity for 5-(HydroxyMethyl) Furfural (HMF) to 2,5-bis(HydroxyMethyl)-Furan (BHMF) formation in comparison to the Ag film. Moreover, a similar ECH current density was recorded at a reduced working potential of 220 mV for rAg. This high performance of rAg is attributed to the formation of new catalytically active sites during the Ag oxidation and reduction processes. This study demonstrates that rAg can potentially be used for the ECH process with minimum energy consumption and a higher production rate

Optimization of graphene oxide through various Hummers' methods and comparative reduction using green approach

Graphene oxide (GO) was synthesized using three techniques and was reduced using two reducers' extracts from neem and pumpkin leaves. The obtained GOs and RGOs were characterized using Fourier infra-red (FTIR) spectroscopy, Raman spectroscopy, UV–visible spectrophotometry, energy dispersive x-ray spectroscopy (EDX) and scanning electron microscopy (SEM). Results revealed that all the three methods used are capable of producing GO with various levels of oxidation. FTIR spectra of RGOs showed that the Cdouble bondO signature of GOs at 1730–1740 cm−1 were eliminated after reduction. Other characterization results of the RGOs revealed that both the neem and pumpkin extracts are capable of reducing the synthesized GO. With all these, it can be concluded that the extracts of neem and pumpkin are good reducing agents. The neem and pumpkin extracts, which are ecofriendly can replace the use of hazardous chemicals that are not ecofriendly.http://www.elsevier.com/locate/diamond2023-05-18hj2022Physic

Low Platinum-Loaded Molybdenum Co-catalyst for the Hydrogen Evolution Reaction in Alkaline and Acidic Media

Developing an efficient catalytic system for electrolysis with reduced platinum (Pt) loading while maintaining performance comparable to bulk platinum metal is important to decrease costs and improve scalability of the hydrogen fuel economy. Here we report the performance of a novel sputter-deposited molybdenum (Mo) thin film with an extremely low co-loading of Pt, where Pt atoms were dispersed on Mo (Ptd-Mo) as an electrocatalyst for the hydrogen evolution reaction (HER) in either alkaline or acidic media. The Ptd-Mo electrocatalyst presents similar catalytic activity to bulk Pt in alkaline media, while the performance is only slightly decreased in acidic media. Differential electrochemical mass spectrometry (DEMS) results confirm that the Ptd-Mo electrocatalyst produced hydrogen at a rate comparable with that of a pristine Pt sample at the same potential. A comparison with Pt-loaded degenerately doped p-type doped silicon (Ptd-Si) suggests that Mo and Pt work synergistically to boost the performance of Ptd-Mo catalysts. Cyclic voltammetry (CV) and X-ray photoelectron spectroscopy (XPS) before and after 1000 cycles of continuous operation confirm the significant durability of the Ptd-Mo performance. Overall, the Ptd-Mo electrocatalyst, with comparable HER activity to bulk Pt despite an ultra-low Pt loading, could be a strong candidate for hydrogen production in either acidic or basic conditions

Nanocoral Ag for nonenzymatic glucose detection at extremely low operational potential

Silver (Ag) metal has excellent antibacterial properties, which makes it an ideal candidate for nonenzymatic glucose sensing devices. However, Ag nonenzymatic glucose sensors function at significantly high operating potential and suffer from poor selectivity. Here, we report that nanocoral reduced Ag (R-Ag) based nonenzymatic glucose sensors can be operated at potential as low as 0.1 V vs. Ag/AgCl and exhibits more than one order magnitude higher sensitivity in comparison to the Ag film. The R-Ag sensors can detect glucose in a wide range of concentrations varying from 100 u M to 2.5 mM linearly. The R-Ag sensors are also very robust, as performance remains unchanged even if sensors are stored under ambient conditions for 45 days.B.K. and J. H. designed and supervised manuscript. J. H. and A.H. prepared the sensors and J.H. performed all sensing experiments. W.C. and J.H. perform SEM, EDS and XRD experiments and H.E. analyzed the material characterization data. J. H., and B.K. wrote the manuscript and G.S. assisted with data interpretation. All authors reviewed the manuscript. All authors have also read and approved the final manuscript. K.S. efforts were supported by the NPRP11S-0110-180247 , Qatar national foundation , respectively. B.K. efforts were supported by the Office of Naval Research ( N00014-17-1-2331 ) grant, NPRP11S-0110-180247, Qatar national foundation grant National Science Foundaion-major research instrument grant ( N 1920108 ) and Department of national Nuclear Security Administration grant ( NA0003979 ) awarded to Elizabeth City State University, respectively.Scopu

Tri-Molybdenum Phosphide (Mo\u3csub\u3e3\u3c/sub\u3eP) and Multi-Walled Carbon Nanotube Junctions for Volatile Organic Compounds (VOCs) Detection

Detection and analysis of volatile organic compounds’ (VOCs) biomarkers lead to improvement in healthcare diagnosis and other applications such as chemical threat detection and food quality control. Here, we report on tri-molybdenum phosphide (Mo3P) and multi- walled carbon nanotube (MWCNT) junction-based vapor quantum resistive sensors (vQRSs), which exhibit more than one order of magni- tude higher sensitivity and superior selectivity for biomarkers in comparison to pristine MWCNT junctions based vQRSs. Transmission electron microscope/scanning tunneling electron microscope with energy dispersive x-ray spectroscopy, x-ray diffraction, and x-ray photo- electron spectroscopy studies reveal the crystallinity and the presence of Mo and P elements in the network. The presence of Mo3P clearly enhanced the performance of vQRS as evidenced in sensitivity and selectivity studies. The vQRSs are stable over extended periods of time and are reproducible, making them a potential candidate for sensing related applications

Tri-molybdenum phosphide (Mo3P) and multi-walled carbon nanotube junctions for volatile organic compounds (VOCs) detection

Detection and analysis of volatile organic compounds' (VOCs) biomarkers lead to improvement in healthcare diagnosis and other applications such as chemical threat detection and food quality control. Here, we report on tri-molybdenum phosphide (Mo3P) and multiwalled carbon nanotube (MWCNT) junction-based vapor quantum resistive sensors (vQRSs), which exhibit more than one order of magnitude higher sensitivity and superior selectivity for biomarkers in comparison to pristine MWCNT junctions based vQRSs. Transmission electron microscope/scanning tunneling electron microscope with energy dispersive x-ray spectroscopy, x-ray diffraction, and x-ray photoelectron spectroscopy studies reveal the crystallinity and the presence of Mo and P elements in the network. The presence of Mo3P clearly enhanced the performance of vQRS as evidenced in sensitivity and selectivity studies. The vQRSs are stable over extended periods of time and are reproducible, making them a potential candidate for sensing related applications.All authors have read and approved the final manuscript. Research at the Elizabeth City State University was supported by the National Science Foundation?Major Research Instrument Grant (No. 1920108), Department of National Nuclear Security Administration Grant (No. NA0003979), the Office of Naval Research (No. N00014-17-1-2331), and Qatar National Foundation Grant No. NPRP11S-0110-180247.Scopu