3,487 research outputs found
Flexible substrate for printed wiring
A very flexible substrate for printed wiring is disclosed which is composed of a blend of phenoxy resin-polyisocyanate-brominated epoxy resin in which the equivalent ration of the functional groups is hydroxyl grouped: isocyanate group: epoxy group = 1:0.2 to 2:0.5 to 3. The product has outstanding solder resistance and is applied to metal without using adhesives
Flexible composite film for printed circuit board
A flexible printed circuit for a printed circuit board in which layers of reaction product composed of a combination of phenoxy resin - polyisocyanate - brominated epoxy resin, and in which the equivalent ratio of those functional groups is hydroxyl group: isocyanate group: epoxy group - 1 : 0.2 to 2 : 0.5 to 3 are laminated on at least one side of saturated polyester film is discussed
Equilibrium properties of highly asymmetric star-polymer mixtures
We employ effective interaction potentials to study the equilibrium structure
and phase behavior of highly asymmetric mixtures of star polymers. We consider
in particular the influence of the addition of a component with a small number
of arms and a small size on a concentrated solution of large stars with a high
functionality. By employing liquid integral equation theories we examine the
evolution of the correlation functions of the big stars upon addition of the
small ones, finding a loss of structure that can be attributed to a weakening
of the repulsions between the large stars due to the presence of the small
ones. We analyze this phenomenon be means of a generalized depletion mechanism
which is supported by computer simulations. By applying thermodynamic
perturbation theory we draw the phase diagram of the asymmetric mixture,
finding that the addition of small stars melts the crystal formed by the big
ones. A systematic comparison between the two- and effective one-component
descriptions of the mixture that corroborates the reliability of the
generalized depletion picture is also carried out.Comment: 26 pages, 9 figures, submitted to Phys. Rev.
Crystallization and gelation in colloidal systems with short-ranged attractive interactions
We systematically study the relationship between equilibrium and
non-equilibrium phase diagrams of a system of short-ranged attractive colloids.
Using Monte Carlo and Brownian dynamics simulations we find a window of
enhanced crystallization that is limited at high interaction strength by a
slowing down of the dynamics and at low interaction strength by the high
nucleation barrier. We find that the crystallization is enhanced by the
metastable gas-liquid binodal by means of a two-stage crystallization process.
First, the formation of a dense liquid is observed and second the crystal
nucleates within the dense fluid. In addition, we find at low colloid packing
fractions a fluid of clusters, and at higher colloid packing fractions a
percolating network due to an arrested gas-liquid phase separation that we
identify with gelation. We find that this arrest is due to crystallization at
low interaction energy and it is caused by a slowing down of the dynamics at
high interaction strength. Likewise, we observe that the clusters which are
formed at low colloid packing fractions are crystalline at low interaction
energy, but glassy at high interaction energy. The clusters coalesce upon
encounter.Comment: 8 pages, 8 figure
Supersaturated dispersions of rod-like viruses with added attraction
The kinetics of isotropic-nematic (I-N) and nematic-isotropic (N-I) phase
transitions in dispersions of rod-like {\it fd}-viruses are studied.
Concentration quenches were applied using pressure jumps in combination with
polarization microscopy, birefringence and turbidity measurements. The full
biphasic region could be accessed, resulting in the construction of a first
experimental analogue of the bifurcation diagram. The N-I spinodal points for
dispersions of rods with varying concentrations of depletion agents (dextran)
were obtained from orientation quenches, using cessation of shear flow in
combination with small angle light scattering. We found that the location of
the N-I spinodal point is independent of the attraction, which was confirmed by
theoretical calculations. Surprisingly, the experiments showed that also the
absolute induction time, the critical nucleus and the growth rate are
insensitive of the attraction, when the concentration is scaled to the distance
to the phase boundaries.Comment: 13 pages, 14 figures. accepted in Phsical Review
Structure and thermodynamics of colloid-polymer mixtures: a macromolecular approach
The change of the structure of concentrated colloidal suspensions upon
addition of non-adsorbing polymer is studied within a two-component,
Ornstein-Zernicke based liquid state approach. The polymers' conformational
degrees of freedom are considered and excluded volume is enforced at the
segment level. The polymer correlation hole, depletion layer, and excess
chemical potentials are described in agreement with polymer physics theory in
contrast to models treating the macromolecules as effective spheres. Known
depletion attraction effects are recovered for low particle density, while at
higher densities novel many-body effects emerge which become dominant for large
polymers.Comment: 7 pages, 4 figures; to be published in Europhys. Let
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