128 research outputs found
Exploring the atmosphere of Neoproterozoic Earth: The effect of O2 on haze formation and composition
Previous studies of haze formation in the atmosphere of the early Earth have focused on N2/CO2/CH4 atmospheres. Here, we experimentally investigate the effect of O2 on the formation and composition of aerosols to improve our understanding of haze formation on the Neoproterozoic Earth. We obtained in situ size, particle density, and composition measurements of aerosol particles produced from N2/CO2/CH4/O2 gas mixtures subjected to FUV radiation (115â400 nm) for a range of initial CO2/CH4/O2 mixing ratios (O2 ranging from 2 ppm to 0.2%). At the lowest O2 concentration (2 ppm), the addition increased particle production for all but one gas mixture. At higher oxygen concentrations (20 ppm and greater), particles are still produced, but the addition of O2 decreases the production rate. Both the particle size and number density decrease with increasing O2, indicating that O2 affects particle nucleation and growth. The particle density increases with increasing O2. The addition of CO2 and O2 not only increases the amount of oxygen in the aerosol, but it also increases the degree of nitrogen incorporation. In particular, the addition of O2 results in the formation of nitrate-bearing molecules. The fact that the presence of oxygen-bearing molecules increases the efficiency of nitrogen fixation has implications for the role of haze as a source of molecules required for the origin and evolution of life. The composition changes also likely affect the absorption and scattering behavior of these particles but optical property measurements are required to fully understand the implications for the effect on the planetary radiative energy balance and climate
Impacts of Climate Change on Volcanic Stratospheric Injections: Comparison of 1-D and 3-D Plume Model Projections
©2019. American Geophysical Union. All Rights Reserved. Explosive volcanic eruptions are one of the most important driver of climate variability. Yet, we still lack a fundamental understanding of how climate change may affect future eruptions. Here, we use an ensemble of simulations by 1-D and 3-D volcanic plume models spanning a large range of eruption source and atmospheric conditions to assess changes in the dynamics of future eruptive columns. Our results shed new light on differences between the predictions of 1-D and 3-D plume models. Furthermore, both models suggest that as a result of ongoing climate change, for tropical eruptions, (i) higher eruption intensities will be required for plumes to reach the upper troposphere/lower stratosphere and (ii) the height of plumes currently reaching the upper troposphere/lower stratosphere or above will increase. We discuss the implications of these results for the climatic impacts of future eruptions. Our simulations can directly inform climate model experiments on climate-volcano feedback.T.J.A.acknowledges funding from the Royal Society through a Newton International Fellowship (Grant NIF⧔R1⧔-180809).M. C. acknowledges CINECA Award N. HP10BRDK2T (2017) for high-performance computing resources used for testing the ASHEEcode; the FISR 2016 âCentro di studioe monitoraggio dei rischi naturalidellItalia centraleâ project framework,managed by the Italian National Institute of Geophysics and Volcanology (INGV) and funded by the Italian Ministry of Education,University and Research; and the European Unions Horizon 2020 research and innovation program under Grant Agreement 731070. T. J.A. and A.M.J. acknowledge support from the Natural Sciences and Engineering Research Council of Canada during completion of this work
Impact of global warming on the rise of volcanic plumes and implications for future volcanic aerosol forcing
©2016. American Geophysical Union. All Rights Reserved. Volcanic eruptions have a significant impact on climate when they inject sulfur gases into the stratosphere. The dynamics of eruption plumes is also affected by climate itself, as atmospheric stratification impacts plumes' height. We use an integral plume model to assess changes in volcanic plume maximum rise heights as a consequence of global warming, with atmospheric conditions from an ensemble of global climate models, using three representative concentration pathways (RCP) scenarios. Predicted changes in atmospheric temperature profiles decrease the heights of tropospheric and lowermost stratospheric volcanic plumes and increase the tropopause height, for the RCP4.5 and RCP8.5 scenarios in the coming three centuries. Consequently, the critical mass eruption rate required to cross the tropopause increases by up to a factor of 3 for tropical regions and up to 2 for high-latitude regions. A number of recent lower stratospheric plumes, mostly in the tropics (e.g., Merapi, 2010), would be expected to not cross the tropopause starting from the late 21st century, under RCP4.5 and RCP8.5 scenarios. This effect could result in a â5â25% decrease in the average SO2 flux into the stratosphere carried by small plumes, the frequency of which is larger than the rate of decay of volcanic stratospheric aerosol, and a â2â12% decrease of the total flux. Our results suggest the existence of a positive feedback between climate and volcanic aerosol forcing. Such feedback may have minor implications for global warming rate but can prove to be important to understand the long-term evolution of volcanic atmospheric inputs
Quantifying erosion rates and weathering pathways that maximize soil organic carbon storage
Primary minerals that enter soils through bedrock weathering and atmospheric deposition can generate poorly crystalline minerals (PCM) that preferentially associate with soil organic carbon (SOC). These associations hinder microbial decomposition and the release of COâ from soils to the atmosphere, making them a critical geochemical control on terrestrial carbon abundance and persistence. Studies that explore these relationships are typically derived from soil chronosequences that experience negligible erosion and thus do not readily translate to eroding landscapes. Here, we propose a theoretical framework to estimate steady-state PCM density and stocks for hilly and mountainous settings by coupling geochemical and geomorphic mass balance equations that account for soil production from bedrock and dust, soil erosion, PCM formation from weathering, and the transformation of PCMs into crystalline phases. We calculate an optimal erosion rate for maximum PCM abundance that arises because PCMs are limited by insufficient weathering at faster erosion rates and loss via âripeningâ into more crystalline forms at slower erosion rates. The optimal erosion rate for modeled hilltop soil is modulated by reaction rate constants that govern the efficiency of primary mineral weathering and PCM ripening. By comparing our analysis with global compilations of erosion and soil production rates derived from cosmogenic nuclides, we show that landscapes with slow-to-moderate erosion rates may be optimal for harboring abundant PCM stocks that can facilitate SOC sequestration and limit turnover. Given the growing array of erosion-topography metrics and the widespread availability of high-resolution topographic data, our framework demonstrates how weathering and critical zone processes can be coupled to inform landscape prioritization for persistent SOC storage potential across a broad range of spatial and temporal scales
Decadal to monthly timescales of magma transfer and reservoir growth at a caldera volcano
International audienceCaldera-forming volcanic eruptions are low-frequency, highimpact events capable of discharging tens to thousands of cubic kilometres of magma explosively on timescales of hours to days, with devastating effects on local and global scales1. Because no such eruption has been monitored during its long build-up phase, the precursor phenomena are not well understood. Geophysical signals obtained during recent episodes of unrest at calderas such as Yellowstone, USA, and Campi Flegrei, Italy, are difficult to interpret, and the conditions necessary for large eruptions are poorly constrained2,3. Here we present a study of pre-eruptive magmatic processes and their timescales using chemically zoned crystals from the 'Minoan' caldera-formingeruption of Santorini volcano,Greece4, which occurred in the late 1600s BC. The results provide insights into how rapidly large silicic systems may pass from a quiescent state to one on the edge of eruption5,6. Despite the large volume of erupted magma4 (40-60 cubic kilometres), and the 18,000-year gestation period between the Minoan eruption and the previous major eruption, most crystals in the Minoan magma record processes that occurred less than about 100 years before the eruption. Recharge of the magma reservoir by large volumes of silicic magma (and some mafic magma) occurred during the century before eruption, and mixing between different silicicmagmabatches was still taking place during the final months. Final assembly of large silicic magma reservoirs may occur on timescales that are geologically very short by comparison with the preceding repose period, with major growth phases immediately before eruption. These observations have implications for the monitoring of long-dormant, but potentially active, caldera systems
Continuous long-term array analysis of seismic records observed during the 2011 Shinmoedake eruption activity of Kirishima volcano, southwest Japan
Ice, fire, or fizzle: The climate footprint of Earth's supercontinental cycles
Supercontinent assembly and breakup can influence the rate and global extent to which insulated and relatively warm subcontinental mantle is mixed globally, potentially introducing lateral oceanicâcontinental mantle temperature variations that regulate volcanic and weathering controls on Earth's longâterm carbon cycle for a few hundred million years. We propose that the relatively warm and unchanging climate of the Nuna supercontinental epoch (1.8â1.3 Ga) is characteristic of thorough mantle thermal mixing. By contrast, the extreme coolingâwarming climate variability of the Neoproterozoic Rodinia episode (1â0.63 Ga) and the more modest but similar climate change during the Mesozoic Pangea cycle (0.3â0.05 Ga) are characteristic features of the effects of subcontinental mantle thermal isolation with differing longevity. A tectonically modulated carbon cycle model coupled to a oneâdimensional energy balance climate model predicts the qualitative form of Mesozoic climate evolution expressed in tropical seaâsurface temperature and ice sheet proxy data. Applied to the Neoproterozoic, this supercontinental control can drive Earth into, as well as out of, a continuous or intermittently panglacial climate, consistent with aspects of proxy data for the CryogenianâEdiacaran period. The timing and magnitude of this coolingâwarming climate variability depends, however, on the detailed character of mantle thermal mixing, which is incompletely constrained. We show also that the predominant modes of chemical weathering and a tectonically paced abiotic methane production at midâocean ridges can modulate the intensity of this climate change. For the Nuna epoch, the model predicts a relatively warm and iceâfree climate related to mantle dynamics potentially consistent with the intense anorogenic magmatism of this period
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Impacts of Climate Change on Volcanic Stratospheric Injections: Comparison of 1-D and 3-D Plume Model Projections
©2019. American Geophysical Union. All Rights Reserved. Explosive volcanic eruptions are one of the most important driver of climate variability. Yet, we still lack a fundamental understanding of how climate change may affect future eruptions. Here, we use an ensemble of simulations by 1-D and 3-D volcanic plume models spanning a large range of eruption source and atmospheric conditions to assess changes in the dynamics of future eruptive columns. Our results shed new light on differences between the predictions of 1-D and 3-D plume models. Furthermore, both models suggest that as a result of ongoing climate change, for tropical eruptions, (i) higher eruption intensities will be required for plumes to reach the upper troposphere/lower stratosphere and (ii) the height of plumes currently reaching the upper troposphere/lower stratosphere or above will increase. We discuss the implications of these results for the climatic impacts of future eruptions. Our simulations can directly inform climate model experiments on climate-volcano feedback.T.J.A.acknowledges funding from the Royal Society through a Newton International Fellowship (Grant NIF⧔R1⧔-180809).M. C. acknowledges CINECA Award N. HP10BRDK2T (2017) for high-performance computing resources used for testing the ASHEEcode; the FISR 2016 âCentro di studioe monitoraggio dei rischi naturalidellItalia centraleâ project framework,managed by the Italian National Institute of Geophysics and Volcanology (INGV) and funded by the Italian Ministry of Education,University and Research; and the European Unions Horizon 2020 research and innovation program under Grant Agreement 731070. T. J.A. and A.M.J. acknowledge support from the Natural Sciences and Engineering Research Council of Canada during completion of this work
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Impact of global warming on the rise of volcanic plumes and implications for future volcanic aerosol forcing
©2016. American Geophysical Union. All Rights Reserved. Volcanic eruptions have a significant impact on climate when they inject sulfur gases into the stratosphere. The dynamics of eruption plumes is also affected by climate itself, as atmospheric stratification impacts plumes' height. We use an integral plume model to assess changes in volcanic plume maximum rise heights as a consequence of global warming, with atmospheric conditions from an ensemble of global climate models, using three representative concentration pathways (RCP) scenarios. Predicted changes in atmospheric temperature profiles decrease the heights of tropospheric and lowermost stratospheric volcanic plumes and increase the tropopause height, for the RCP4.5 and RCP8.5 scenarios in the coming three centuries. Consequently, the critical mass eruption rate required to cross the tropopause increases by up to a factor of 3 for tropical regions and up to 2 for high-latitude regions. A number of recent lower stratospheric plumes, mostly in the tropics (e.g., Merapi, 2010), would be expected to not cross the tropopause starting from the late 21st century, under RCP4.5 and RCP8.5 scenarios. This effect could result in a â5â25% decrease in the average SO2 flux into the stratosphere carried by small plumes, the frequency of which is larger than the rate of decay of volcanic stratospheric aerosol, and a â2â12% decrease of the total flux. Our results suggest the existence of a positive feedback between climate and volcanic aerosol forcing. Such feedback may have minor implications for global warming rate but can prove to be important to understand the long-term evolution of volcanic atmospheric inputs
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External Surface Water Influence on Explosive Eruption Dynamics, With Implications for Stratospheric Sulfur Delivery and Volcano-Climate Feedback
Explosive volcanic eruptions can inject sulfur dioxide (SO2) into the stratosphere to form aerosol particles that modify Earthâs radiation balance and drive surface cooling. Eruptions involving interactions with shallow layers (â€500 m) of surface water and ice modify the eruption dynamics that govern the delivery of SO2 to the stratosphere. External surface water controls the evolution of explosive eruptions in two ways that are poorly understood: 1) by modulating the hydrostatic pressure within the conduit and at the vent, and 2) through the ingestion and mixing of external water, which governs fine ash production and eruption column buoyancy flux. To make progress, we couple one-dimensional models of conduit flow and atmospheric column rise through a novel âmagma-water interactionâ model that simulates the occurrence, extent and consequences of water entrainment depending on the depth of a surface water layer. We explore the effects of hydrostatic pressure on magma ascent in the conduit and gas decompression at the vent, and the conditions for which water entrainment drives fine ash production by quench fragmentation, eruption column collapse, or outright failure of the jet to breach the water surface. We show that the efficiency of water entrainment into the jet is the predominant control on jet behavior. For an increase in water depth of 50â100 m, the critical magma mass eruption rate required for eruption columns to reach the tropopause increases by an order of magnitude. Finally, we estimate that enhanced emission of fine ash leads to up to a 2-fold increase in the mass flux of particles < 125 Όm to spreading umbrella clouds, together with up to a 10-fold increase in water mass flux, conditions that can enhance the removal of SO2 via chemical scavenging and ash sedimentation. On average, compared to purely magmatic eruptions, we suggest that hydrovolcanic eruptions will be characterized by reduced climate forcing. Our results suggest one possible mechanism for volcano-climate feedback: temporal changes with climate in surface distributions of water and ice may modify the relative global frequency or dominance of hydrovolcanic eruption processes, modulating, in turn, global patterns in volcano-climate forcing.</jats:p
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