Impact of work from home on work-life balance: Mediating effects of work-family conflict and work motivation

In the aftermath of the recent pandemic, organizations around the world had the opportunity to assess the benefits and drawbacks of allowing the bulk of their employees to work from home (WFH). As a result, many organizations realize that by using technology, it is possible to shift a significant percentage of their workforce to permanently function from any location without being physically present at a designated workplace. Although the economic benefits for organizations that allow WFH seem to be clear, how factors related to perceptions of employees such as their work motivation (WM) and their work-life balance (WLB) caused by blurred boundaries between work and family at home are not clearly understood. Therefore, the primary goal of this study is to determine how WFH impacts WLB through the possible mediating effects of work-family conflict (WFC) and WM. A cross-sectional survey instrument was developed using Likert type measurement scales that were adopted from top-tier journals. The data was collected through convenient sampling from 249 managerial and non-managerial employees in Omani business organizations. The relationships were tested through structural equation modeling. The results indicate that WFH increases WFC and WM, while the relationship between WFH and WLB is mediated by WFC, but not by WM. The findings of this study have implications for both theory and practice

Epidemiology of End Stage Renal Disease (ESRD) of Oman since 1983 to 2018: a secondary data analysis study

No abstract available

CLINICAL AND LABORATORY FEATURES OF SICKLE CELL DISEASE S/D PUNJAB: IMPACT OF HBF AND HYDROXYUREA

Background: Sickle cell disease (SCD) is a major public health issue worldwide with high morbidity and mortality. SCD SD Punjab is the third most common genotype of SCD in Oman and is associated with several serious complications. The aim of the study is to establish the clinical and laboratory features of SCD patients with SD double heterozygotes and study the impact of haemoglobin F, hydroxyurea, and other modulators on the disease severity. Methods: We analyzed the electronic medical records of 52 consecutive SCD patients who were diagnosed as double heterozygote SD Punjab between 2006 and 2022. The study was approved by the local medical research and ethics committee. The data captured included SCD-related complications and current clinical and laboratory indices. Data from other studies on other SCD genotypes were used as historical controls.   Results: 52 patients (31 males, 21 females) who formed this cohort had a median age of 32 years with an interquartile range (IQR) of 21-39.8 years. 37(71.2%) had 3 vasooclusive (VOC) episodes per year. SCD-related complications included Acute Chest Syndrome (ACS) (48%), Gall stones (26.9%), Avascular necrosis (AVN) (28.8%), Stroke (13.5%) and splenic sequestration (7.7%), whereas 5 (9.6%) patients of this cohort died. Surgical and Autosplenectomy were seen in 18 (34.6%). These findings were similar to other SCD genotypes in this community.19 (57.6%) were taking Hydroxyurea (HU) amongst the 33 patients who were prescribed HU. Haematological parameters showed a median (IQR) Hb (g/dl), MCV (fl), Retic count (%), WBC count(X109/L) and Platelet count(X109/L) of 9.7 (8.5-11.3), 74.9 (68.4-79.8), 4 (3.2-5.7), 9.9 (8.1-12.6) and 309 (239-428) respectively. The haemoglobin electrophoresis showed an elevated HbF, whereas serum bilirubin and LDH were elevated amongst the biochemical parameters. The use of hydroxyurea showed no impact on VOC, ACS, AVN, Stroke or mortality.   Conclusion: SD Punjab is the third most common SCD genotype in Oman and was associated with recurrent VOC, ACS, AVN, and gall stones comparable to other SCD genotypes. Patients with > 3 VOC/year had significantly increased incidence of Stroke, AVN, and gallstones. However, HU was not associated with improved prognosis and better survival in this cohort of patients. Keywords: Sickle Cell Disease; Haemoglobin SD Punjab; vaso-occlusive crises; acute chest syndrome; Avascular Necrosis; HbF; hydroxyurea

First record of Gymnocranius griseus (Temminck & Schlegel, 1843) (family Lethrinidae) from southern Oman, Western Indian Ocean

Primer registre de Gymnocranius griseus (Temminck & Schlegel, 1843) (família Lethrinidae) del sud d’Oman, oest de l’oceà Índic Es va recol·lectar un únic espècimen (285 mm longitud estàndard) de Gymnocranius griseus (Temminck & Schlegel, 1843) a la ciutat de Salalah (Oman), a la costa del mar d’Aràbia. És el primer registre d’aquesta espècie a les aigües d’Oman. Presenta característiques específiques: cos alt (2,17 vegades la longitud estàndard); els perfils dorsal i ventral del cap són uniformement convexos; el perfil de la part ventral del cos és recte; la vora inferior de l’ull se situa lleugerament per sota de la línia que uneix la part anterior de la boca amb el centre de l’aleta caudal lobulada; l’ull és relativament ample, de diàmetre pràcticament igual o lleugerament superior a les distàncies preorbitària i interorbitària; la boca és relativament petita i la part posterior dels maxil·lars arriba pràcticament al nivell dels orificis nasals anteriors; presenta tres parells de fines canines a la part anterior del maxil·lar superior i un parell a la part anterior de l’inferior, com també altres dents vil·liformes que adquireixen forma cònica a les parts laterals. L’espècimen va ser identificat com un G. griseus atès que les seves característiques corresponen a la descripció diagnòstica de Carpenter & Allen (1989). Palabras clave: Gymnocranius griseus, Salalah, Mar de Arabia, Primer registro.A single specimen (285 mm SL) of Gymnocranius griseus (Temminck & Schlegel, 1843) was collected from Salalah, Arabian Sea coast of Oman. It is the first record of this species from the Omani waters. It shows specific characters: deep body (2.17 times SL); evenly convex dorsal and ventral profile of head; ventral part of body profile straight; lower edge of eye slightly above a line from tip of snout to middle of caudal fin fork; eye relatively large, its diameter about equal to or slightly larger than preorbital and interorbital widths; mouth relatively small, posterior part of jaws reaching to about level of anterior nostrils; three pair and one pair of slender canines at front of upper and lower jaw, respectively, other teeth villiform, becoming conical on lateral sections. The specimen was identified as G. griseus as these characters fit the diagnostic description of Carpenter & Allen (1989). Key words: Gymnocranius griseus, Salalah, Arabian Sea, First record.Primer registre de Gymnocranius griseus (Temminck & Schlegel, 1843) (família Lethrinidae) del sud d’Oman, oest de l’oceà Índic Es va recol·lectar un únic espècimen (285 mm longitud estàndard) de Gymnocranius griseus (Temminck & Schlegel, 1843) a la ciutat de Salalah (Oman), a la costa del mar d’Aràbia. És el primer registre d’aquesta espècie a les aigües d’Oman. Presenta característiques específiques: cos alt (2,17 vegades la longitud estàndard); els perfils dorsal i ventral del cap són uniformement convexos; el perfil de la part ventral del cos és recte; la vora inferior de l’ull se situa lleugerament per sota de la línia que uneix la part anterior de la boca amb el centre de l’aleta caudal lobulada; l’ull és relativament ample, de diàmetre pràcticament igual o lleugerament superior a les distàncies preorbitària i interorbitària; la boca és relativament petita i la part posterior dels maxil·lars arriba pràcticament al nivell dels orificis nasals anteriors; presenta tres parells de fines canines a la part anterior del maxil·lar superior i un parell a la part anterior de l’inferior, com també altres dents vil·liformes que adquireixen forma cònica a les parts laterals. L’espècimen va ser identificat com un G. griseus atès que les seves característiques corresponen a la descripció diagnòstica de Carpenter & Allen (1989). Palabras clave: Gymnocranius griseus, Salalah, Mar de Arabia, Primer registro

Synthesis, optical spectroscopy, structural, and DFT studies on dimeric iodo-bridged Copper(I)complexes

Three new iodo-bridged copper(I)complexes of the type [CuI(PPh 3 )L] 2 , where L = Ar–≡–C 5 H 4 N, Ar = phenyl (C 1 ), biphenyl (C 2 )and flourenyl (C 3 )have been synthesized via coordination-driven self-assembly processes. Two of Cu(I)complexes, C 2 and C 3 , have been characterized by single-crystal X-ray diffraction studies. The complexes have two molecules of the P-donor ligand and two molecules of the N-donor ligand in trans configurations, supporting the central Cu 2 I 2 unit. Absorption properties of the complexes have been investigated. Extensive DFT calculation has been carried out to delineate the influence of aromatic spacers on the optical properties and the nature of excited states. The ease of synthesis of these Cu(I)dimers and the wide range of ethynylpyridine supporting ligands that can be incorporated highlights the potential for these materials to form polymers by linking through the ethylylpyridine ligands. </p

Extended use of grey water for irrigating home gardens in an arid environment

The use of treated grey water (GW) for home gardens, peri-urban agriculture and landscaping is becoming popular in many water stressed countries such as Oman. This study aims to investigate the treatment efficacy, health and chemical concerns, cost-benefits and maintenance protocol of a GW treatment system as well as the effect of irrigation with GW on crop yield. Therefore, a decentralized homemade GW treatment system was installed in a newly constructed house in Muscat, Oman and studied over a 2-year period. The treated GW was found to be suitable for irrigation as per Omani standards. GW when mixed with kitchen effluent substituted the use of nutrient supplements for plants and did not show any harmful chemical or biological contamination. The capital cost of the system was around US $980, and the annual operating cost was US$78 with annual income and savings from the system being around US $572 indicating a payback period of nearly 2 years. It was found that the system required simple but regular maintenance particularly cleaning of the top layer of the filter. It can be concluded from this study that such a GW system should be technically, economically and environmentally feasible in Oman. Also, wider acceptance by the general public to the idea of GW reuse will help in mitigating the water shortage problem of the country to some extent

Synthesis, characterization, and optoelectronic properties of phenothiazine-based organic co-poly-ynes

We present the synthesis and characterization of seven new organic co-poly-ynes P1-P7 incorporating the phenothiazine (PTZ) motif and evaluate their optoelectronic properties and performance in polymer light-emitting diodes and polymer solar cells (PLEDs/PSCs). The co-poly-ynes were obtained in moderate to high yields via Sonogashira coupling reactions and characterized using analytical, spectroscopic and electrochemical techniques and complementary quantum-chemical modelling. The materials show strong optical absorption in the visible region of the spectrum and most also show strong emission with quantum yields in the range of 13-41% relative to rhodamine 6G (R6G). PLED devices based on the co-poly-ynes were prepared and the most promising was measured to have a brightness of up to 1.10 × 104 cd m-2. PSCs based on donor materials incorporating some of the polymers were prepared and demonstrated power conversion efficiencies of up to 0.24%. This journal is </p

Health risk assessment of instant noodles commonly consumed in Port Harcourt, Nigeria

The current study investigated the levels of some heavy metals [Lead (Pb), Arsenic (As), Nickel (Ni), Mercury (Hg), Copper (Cu), Cadmium (Cd), Aluminium (Al) and Chromium (Cr)] and Polycyclic Aromatic Hydrocarbons (PAHs) in six brands of instant noodles (CFN, GFC, NGP, GAA, CUN and FCS) commonly consumed in Port Harcourt, Nigeria. Risks of consumption of contaminated noodles were also assessed. Heavy metals content and PAHs were determined using Flame Atomic Absorption Spectrophotometer (AAS) and Gas Chromatography (GC), respectively. Concentration of heavy metals as Pb, Ni, Cu, Al and Cr were detected while As, Hg and Cd were not detected in noodles. High average concentration (mean ± SD mg/kg) of Pb were observed in brands CFN (3.163 ± 0.21) and GFC (1.022 ± 0.08) which were significantly higher (P≤0.05) than in NGP (0.043 ± 0.15) and GAA (0.276 ± 0.18), although all were above WHO permissible limits (0.025 mg/kg). Target Hazard Quotient and Hazard Index for Pb were >1 in brands CFN and GFC indicating unacceptable risk. Results of PAHs showed brands had total PAHs (mg/kg) in the order: CFN >CUN >GAA >NGP >FCS > GFC. Although Carcinogenic Risks associated with these noodles are within permissible range, consumption of CFN and GFC could pose greater health risk to consumers. Long term consumption of brands CUN, CFN and GAA may have higher probability of carcinogenesis among consumers. We therefore recommend more diligent regulatory policies and monitoring by relevant Government agencies (WHO, NAFDAC, CPC and SON) to ensure wholesome noodles get to consumers

“So what if ChatGPT wrote it?” Multidisciplinary perspectives on opportunities, challenges and implications of generative conversational AI for research, practice and policy

Transformative artificially intelligent tools, such as ChatGPT, designed to generate sophisticated text indistinguishable from that produced by a human, are applicable across a wide range of contexts. The technology presents opportunities as well as, often ethical and legal, challenges, and has the potential for both positive and negative impacts for organisations, society, and individuals. Offering multi-disciplinary insight into some of these, this article brings together 43 contributions from experts in fields such as computer science, marketing, information systems, education, policy, hospitality and tourism, management, publishing, and nursing. The contributors acknowledge ChatGPT's capabilities to enhance productivity and suggest that it is likely to offer significant gains in the banking, hospitality and tourism, and information technology industries, and enhance business activities, such as management and marketing. Nevertheless, they also consider its limitations, disruptions to practices, threats to privacy and security, and consequences of biases, misuse, and misinformation. However, opinion is split on whether ChatGPT's use should be restricted or legislated. Drawing on these contributions, the article identifies questions requiring further research across three thematic areas: knowledge, transparency, and ethics; digital transformation of organisations and societies; and teaching, learning, and scholarly research. The avenues for further research include: identifying skills, resources, and capabilities needed to handle generative AI; examining biases of generative AI attributable to training datasets and processes; exploring business and societal contexts best suited for generative AI implementation; determining optimal combinations of human and generative AI for various tasks; identifying ways to assess accuracy of text produced by generative AI; and uncovering the ethical and legal issues in using generative AI across different contexts