Calibración con parámetros de los ítems fijos para la evaluación del funcionamiento diferencial del ítem en tests adaptativos informatizados

In computerized adaptive testing pretest items are presented in conjunction with operational items to renew the item bank. Pretest items are calibrated, and possible differential item functioning (DIF) is analyzed. Some difficulties arise due to the large amount of missing responses, which can be avoided by the use of fixed item parameter calibration (FIPC; Kim, 2006) methods. In this study, we applied the multiple weights updating and multiple EM cycles method, with response imputation (as suggested by Lei, Chen, & Yu, 2006) and without response imputation for non-applied items. The IRT likelihood ratio test (IRT-LRT) was used for DIF detection. The manipulated factors were type of DIF, DIF size, impact size, test length, and sample size. The results showed that the FIPC method is suitable for detecting large-size DIF in large samples. In the presence of impact the use of imputation led to a bias in the effect-size measure of the DIFEn tests adaptativos informatizados los ítems pretest se presentan junto con los ítems operativos para renovar el banco de ítems. Los ítems pretest se calibran y se analiza el posible funcionamiento diferencial de los ítems (FDI). Este análisis presenta algunos problemas debido a la gran cantidad de respuestas faltantes, una de las posibles soluciones es el uso de métodos de calibración con parámetros fijos (Kim, 2006). En este estudio, aplicamos el método de múltiples actualizaciones de los pesos y múltiples ciclos EM con imputación de respuestas (tal y como propusieron Lei, Chen, y Yu, 2006) y sin imputación de respuesta para los ítems no aplicados. Empleamos el test de razón de verosimilitudes de la TRI para la detección del FDI. Los factores manipulados fueron el tipo de FDI, el tamaño del FDI, el tamaño del impacto, la longitud del test, y el tamaño de las muestras. Los resultados señalan que el método de calibración con parámetros fijos es una alternativa adecuada para la detección de un FDI grande cuando se utilizaron muestras grandes. En presencia de impacto el uso de imputación de respuestas introdujo un sesgo en las medidas del tamaño del efecto del FDIThis research was partly supported by a grant from the Spanish Ministry of Education and Science [PSI2009-10341

Stabilisation of mixed peptide/lipid complexes in selective antifungal hexapeptides

AbstractThe design of antimicrobial peptides could have benefited from structural studies of known peptides having specific activity against target microbes, but not toward other microorganisms. We have previously reported the identification of a series of peptides (PAF-series) active against certain postharvest fungal phytopathogens, and devoid of toxicity towards E. coli and S. cerevisiae [López-Garcı́a et al. Appl. Environ. Microbiol. 68 (2002) 2453]. The peptides inhibited the conidia germination and hyphal growth. Here, we present a comparative structural characterisation of selected PAF peptides obtained by single-amino-acid replacement, which differ in biological activity. The peptides were characterised in solution using fluorescence and circular dichroism (CD) spectroscopies. Membrane and membrane mimetic–peptide interactions and the lipid-bound structures were studied using fluorescence with the aid of extrinsic fluorescent probes that allowed the identification of mixed peptide/lipid complexes. A direct correlation was found between the capability of complex formation and antifungal activity. These studies provide a putative structural basis for the mechanism of action of selective antifungal peptides

Theory of lasing action in plasmonic crystals

We theoretically investigate lasing action in plasmonic crystals incorporating optically pumped four-level gain media. By using detailed simulations based on a time-domain generalization of the finite-element method, we show that the excitation of dark plasmonic resonances (via the gain medium) enables accessing the optimal lasing characteristics of the considered class of systems. Moreover, our study reveals that, in general, arrays of nanowires feature lower lasing thresholds and larger slope efficiencies than those corresponding to periodic arrays of subwavelength apertures. These findings are of relevance for further engineering of active devices based on plasmonic crystal

Resonant transmission of light through finite chains of subwavelength holes

In this paper we show that the extraordinary optical transmission phenomenon found before in 2D hole arrays is already present in a linear chain of subwavelength holes, which can be considered as the basic geometrical unit showing this property. In order to study this problem we have developed a new theoretical framework, able to analyze the optical properties of finite collections of subwavelength apertures and/or dimples (of any shape and placed in arbitrary positions) drilled in a metallic film.Comment: Accepted for publication in Phys. Rev. Let

NuIl sex differences in General Intelligence: Evidence from the WAIS-III.

Sin resume

Transmission properties of a single metallic slit: From the subwavelength regime to the geometrical-optics limit

In this work we explore the transmission properties of a single slit in a metallic screen. We analyze the dependence of these properties on both slit width and angle of incident radiation. We study in detail the crossover between the subwavelength regime and the geometrical-optics limit. In the subwavelength regime, resonant transmission linked to the excitation of waveguide resonances is analyzed. Linewidth of these resonances and their associated electric field intensities are controlled by just the width of the slit. More complex transmission spectra appear when the wavelength of light is comparable to the slit width. Rapid oscillations associated to the emergence of different propagating modes inside the slit are the main features appearing in this regime.Comment: Accepted for publication in Phys. Rev.

Cross-Cultural Measurement Invariance in the Personality Inventory for DSM-5

The validity of cross-cultural comparisons of test scores requires that scores have the same meaning across cultures, which is usually tested by checking the invariance of the measurement model across groups. In the last decade, a large number of studies were conducted to verify the equivalence across cultures of the dimensional Alternative Model of Personality Disorders (DSM-5 Section III). These studies have provided information on configural invariance (i.e., the facets that compose the domains are the same) and metric invariance (i.e., facet-domain relationships are equal across groups), but not on the stricter scalar invariance (i.e., the baseline levels of the facets are the same), which is a prerequisite for meaningfully comparing group means. The present study aims to address this gap. The Personality Inventory for DSM-5 (PID-5) was administered to five samples differing on country and language (Belgium, Catalonia, France, Spain, and Switzerland), with a total of 4,380 participants. Configural and metric invariance were supported, denoting that the model structure was stable across samples. Partial scalar invariance was supported, being minimal the influence of non-invariant facets. This allowed cross-cultural mean comparisons. Results are discussed in light of the sample composition and a possible impact of culture on development of psychopathologyPreparation of this manuscript was supported by Grant PSI2017–85022-P (Ministerio de Ciencia, Innovacion ´ y Universidades, Spain) and the UAM-IIC Chair "Psychometric Models and Applications

Evaluation of (MnxFe1-x)2TiyOz Particles as Oxygen Carrier for Chemical Looping Combustion

The present work accomplishes a screening of the performance of Mn-Fe-Ti based oxygen carriers, prepared with different Mn/(Mn+Fe) molar ratios in the general formula (MnyFe1-y)Ti0.15Ox. The oxygen carriers were prepared by physical mixing followed by pelletizing under pressure, calcining, crushing and sieving in the 100-300 µm particle size interval. The characterization of the carriers is based on the evaluation of their crushing strength, magnetic properties and reduction and oxidation behavior through TGA experiments at temperatures suitable for the CLC process (i.e. 850-950 °C). In addition, the main chemical structures of the Mn-Fe-Ti system were identified as a function of the Mn/(Mn+Fe) molar ratio. Oxygen uncoupling property was analyzed by reduction under a N2 atmosphere and the capability to interact with fuel gases was analyzed by using CH4, H2 and CO. Results indicate that the (MnyFe1-y)Ti0.15Ox oxygen carriers with Mn/(Mn+Fe) molar ratios of 0.55-0.87 have very promising properties for the CLC process with solid fuels

Calcination of calcium-based sorbents at pressure in a broad range of CO2 concentrations

11 figures, 3 tablesThe calcination reaction of two limestones and a dolomite with different porous structures was studied by thermogravimetric analysis. The effects of calcination temperature (1048-1173 K), particle size (0.4 2.0 mm), CO2 concentration (0 80%) and total pressure (0.1 1.5 MPa) were investigated. SEM analysis indicated the existence of two different particle calcination models depending on the sorbent type: a shrinking core model with a sharp limit between the uncalcined and calcined parts of the particle and a grain model with changing calcination conversion at the particle radial position. The appropriate reaction model was used to determine the calcination kinetic parameters of each sorbent. Chemical reaction and mass transport in the particle porous system were the main limiting factors of the calcination reaction at the experimental conditions. A Langmuir-Hinshelwood-type kinetic model using the Freundlich isotherm was proposed to account for the effect of the CO2 during sorbent calcination. This allowed us to predict the calcination conversion of very different sorbents in a broad range of CO2 partial pressures. Total pressure also inhibited the sorbent calcination. This fact was accounted for by an additional decrease in the molecular diffusion coefficient with increasing total pressure with respect to that indicated by Fuller's equation.This research was carried out with the financial support from the Comisión Interministerial de Ciencia y Tecnología (CICYT) (Project No. AMB 98-0883). The authors thank Dr. Diego Alvárez for his assistance with the SEM technique.Peer Reviewe