The variation of the magnetic field of the Ap star HD~50169 over its 29 year rotation period

Context. The Ap stars that rotate extremely slowly, with periods of decades to centuries, represent one of the keys to the understanding of the processes leading to the differentiation of stellar rotation. Aims. We characterise the variations of the magnetic field of the Ap star HD 50169 and derive constraints about its structure. Methods. We combine published measurements of the mean longitudinal field of HD 50169 with new determinations of this field moment from circular spectropolarimetry obtained at the 6-m telescope BTA of the Special Astrophysical Observatory of the Russian Academy of Sciences. For the mean magnetic field modulus , literature data are complemented by the analysis of ESO spectra, both newly acquired and from the archive. Radial velocities are also obtained from these spectra. Results. We present the first determination of the rotation period of HD 50169, Prot = (29.04+/-0.82) y. HD 50169 is currently the longest-period Ap star for which magnetic field measurements have been obtained over more than a full cycle. The variation curves of both and have a significant degree of anharmonicity, and there is a definite phase shift between their respective extrema. We confirm that HD 50169 is a wide spectroscopic binary, refine its orbital elements, and suggest that the secondary is probably a dwarf star of spectral type M. Conclusions. The shapes and mutual phase shifts of the derived magnetic variation curves unquestionably indicate that the magnetic field of HD 50169 is not symmetric about an axis passing through its centre. Overall, HD 50169 appears similar to the bulk of the long-period Ap stars.Comment: 10 pages, 3 figures, accepted for publication in A&

Complex Estimation of Physical Capacity of Volley-Ballers.

У статті висвітлено особливості прояву фізичної працездатності юнаків і дівчат-волейболістів. На основі встановлених кількісних величин фізичної працездатності розроблено нормативи її комплексної оцінки. The features of display of physical capacity and girls of volley-ballers youth are reflected in the article. On the basis of the set quantitative sizes of physical capacity the norms of its complex estimation are developed

Possible detection of a magnetic field in T Tauri

Medium-resolution $(R\simeq 15000)$ circular spectropolarimetry of T Tauri is presented. The star was observed twice: on November 11, 1996 and January 22, 2002. Weak circular polarization has been found in photospheric absorption lines, indicating a mean surface longitudinal magnetic field $B_{\|}$ of $160\pm 40$ G and $140\pm 50$ G at the epoch of the first and second observations respectively. While these values are near the detection limit of our apparatus, we belive that they are real. In any case one can conclude from our data that $B_{\|}$ of T Tau does not significantly exceed 200 G, which is much less than surface magnetic field strength of the star ($>2.3$ kG) found by Guenther et al. (1999) and Johns-Krull et al. (2000). We discuss possible reasons of this difference.Comment: 5 pages, 3 figure

Photoemission study and band alignment of GaN passivation layers on GaInP heterointerface

III-V semiconductor-based photoelectrochemical (PEC) devices show the highest solar-to-electricity or solar-to-fuel conversion efficiencies. GaInP is a relevant top photoabsorber layer or a charge-selective contact in PEC for integrated and direct solar fuel production, due to its tunable lattice constant, electronic band structure, and favorable optical properties. To enhance the stability of its surface against chemical corrosion which leads to decomposition, we deposit a GaN protection and passivation layer. The n-doped GaInP(100) epitaxial layers were grown by metalorganic chemical vapor deposition on top of GaAs(100) substrate. Subsequently, thin 1-20 nm GaN films were grown on top of the oxidized GaInP surfaces by atomic layer deposition. We studied the band alignment of these multi-junction heterostructures by X-ray and ultraviolet photoelectron spectroscopy. Due to the limited emission depth of photoelectrons, we determined the band alignment by a series of separate measurements in which we either modified the GaInP(100) surface termination or the film thickness of the grown GaN on GaInP(100) buffer layers. On n-GaInP(100) surfaces prepared with the well-known phosphorus-rich (2x2)/c(4x2) reconstruction we found up-ward surface band bending (BB) of 0.34 eV, and Fermi level pinning due to the present surface states. Upon oxidation, the surface states are partially passivated resulting in a reduction of BB to 0.12 eV and a valence band offset (VBO) between GaInP and oxide bands of 2.0 eV. Between the GaInP(100) buffer layer and the GaN passivation layer, we identified a VBO of 1.8 eV. The corresponding conduction band offset of -0.2 eV is found to be rather small. Therefore, we evaluate the application of the GaN passivation layer as a promising technological step not only to reduce surface states but also to increase the stability of the surfaces of photoelectrochemical devices

HD 965: An extremely peculiar A star with an extremely long rotation period

Context. One of the keys to understanding the origin of the Ap stars and their significance in the general context of stellar astrophysics is the consideration of the most extreme properties displayed by some of them. In that context, HD 965 is particularly interesting, as it combines some of the most pronounced chemical peculiarities with one of the longest rotation periods known. Aims. We characterise the variations of the magnetic field of the Ap star HD 965 and derive constraints about its structure. Methods. We combine published measurements of the mean longitudinal field of HD 965 with new determinations of this field moment from circular spectropolarimetry obtained at the 6-m telescope BTA of the Special Astrophysical Observatory of the Russian Academy of Sciences. For the mean magnetic field modulus , literature data are complemented by the analysis of ESO archive spectra. Results. We present the first determination of the rotation period of HD 965, P = (16.5+/-0.5) y. HD 965 is only the third Ap star with a period longer than 10 years for which magnetic field measurements have been obtained over more than a full cycle. The variation curve of is well approximated by a cosine wave. does not show any significant variation. The observed behaviour of these field moments is well represented by a simple model consisting of the superposition of collinear dipole, quadrupole and octupole. The distribution of neodymium over the surface of HD 965 is highly non-uniform. The element appears concentrated around the magnetic poles, especially the negative one. Conclusions. The shape of the longitudinal magnetic variation curve of HD 965 indicates that its magnetic field is essentially symmetric about an axis passing through the centre of the star. Overall, as far as its magnetic field is concerned, HD 965 appears similar to the bulk of the long-period Ap stars.Comment: 7 pages, 4 figures, accepted for publication in Astronomy & Astrophysics. arXiv admin note: text overlap with arXiv:1902.0586

Time resolved in situ spectroscopy during formation of the GaP Si 100 heterointerface

Though III V Si 100 heterointerfaces are essential for future epitaxial high performance devices, their atomic structure is an open historical question. Benchmarking of transient optical in situ spectroscopy during chemical vapor deposition to chemical analysis by X ray photoelectron spectroscopy enables us to distinguish between formation of surfaces and of the heterointerface. A terrace related optical anisotropy signal evolves during pulsed GaP nucleation on single domain Si 100 surfaces. This dielectric anisotropy agrees well with the one calculated for buried GaP Si 100 interfaces from differently thick GaP epilayers. X ray photoelectron spectroscopy reveals a chemically shifted contribution of the P and Si emission lines, which quantitatively corresponds to one monolayer and establishes simultaneously with the nucleation related optical in situ signal. We attribute that contribution to the existence of Si P bonds at the buried heterointerface. During further pulsing and annealing in phosphorus ambient, dielectric anisotropies known from atomically well ordered GaP 100 surfaces super impose the nucleation related optical in situ spectra. Figure Presente

Electrodialysis Concentration of Sulfuric Acid

Received: 31.12.2020. Revised: 30.03.2021. Accepted: 30.03.2021. Available online: 31.03.2021.This article belongs to the PCEE-2020 Special Issue.An urgent task is the development of new resource-saving technologies for deep processing of wastes from the hydrometallurgical industry for the purpose of their reuse. Membrane technologies make it possible to create closed technological cycles with the reuse of recovered components in production, which allows solving many environmental problems. At the Abinsk Electric Steel Works Ltd. (Russia), during the production of copper-coated steel wire, a large amount of waste containing sulfuric acid and heavy metal salts is generated. The chemical treatment of such effluents with slaked lime and alkali produces a large amount of sludge, which causes environmental problems and leads to the irreversible loss of sulfuric acid. The problem of separating acids and salts can be solved using diffusion dialysis through anion-exchange membranes, however, to return the acid to the production cycle, the purified acid must be additionally concentrated. In this work, we studied the process of electrodialysis concentration of sulfuric acid using heterogeneous ion-exchange membranes Ralex® CMHPP and Ralex® AMHPP (manufactured by MEGA a.s., Czech Republic) which have a polypropylene reinforcing mesh resistant to acids. The main parameters of the electrodialysis concentration process have been determined – the dependence of the concentration of the regenerated sulfuric acid on the concentration at the inlet to the electrodialysis cell and on the current density, as well as the energy consumption for the process. It is shown that with the help of electrodialysis concentration it is possible to obtain sulfuric acid with a concentration of up to 180 g/L, which makes it possible to return it to the production cycle.This study was funded by the Ministry of Education and Science of the Russian Federation (project No. FZEN-2020-0022)