Spin-strain coupling in NiCl2-4SC(NH2)2

We report results of ultrasonic investigations of the quantum S = 1 spin-chain magnet NiCl2-4SC(NH2)2, also known as DTN, in magnetic fields up to 18 T and temperatures down to 0.3 K. A field H along the [001] direction induces a transition into an antiferromagnetic phase with T(N)max ≈ 1.2 K. Accordingly, at T = 0 there are two quantum critical points at ~2.1 T and at ~12.6 T. The acoustic c33 mode, propagating along the spin chains, shows a pronounced softening close to the phase transition, accompanied by energy dissipation of the sound wave. The H-T phase diagram obtained from our measurements is compared with results from other experimental investigations and the low-temperature acoustic anomalies are traced up to T > T(N). We also report frequency-dependent effects, which open the possibility to investigate the spin fluctuations in the critical regions. Our observations show an important role of the spin-phonon coupling in DTN

Magnetic excitations in the spin-1 anisotropic antiferromagnet NiCl2−4SC(NH2)2NiCl_2-4SC(NH_2)_2

The spin-1 anisotropic antiferromagnet NiCl_2-4SC(NH2)_2 exhibits a field-induced quantum phase transition that is formally analogous to Bose-Einstein condensation. Here we present results of systematic high-field electron spin resonance (ESR) experimental and theoretical studies of this compound with a special emphasis on single-ion two-magnon bound states. In order to clarify some remaining discrepancies between theory and experiment, the frequency-field dependence of magnetic excitations in this material is reanalyzed. In particular, a more comprehensive interpretation of the experimental signature of single-ion two-magnon bound states is shown to be fully consistent with theoretical results. We also clarify the structure of the ESR spectrum in the so-called intermediate phase.Comment: 9 pages, 10 figure

Structural and magnetic behavior of the S=2 layered ferromagnet CsMnF4 under hydrostatic pressure

Under the terms of the Creative Commons Attribution License 3.0 (CC-BY).Pressure-induced transformations in the structural and magnetic properties of CsMnF4 are reported. This behavior is analyzed in the framework of magnetostructural correlations within the layered perovskite AMnF4 (A=Cs,Rb,K) series by using magnetic susceptibility and synchrotron x-ray powder-diffraction techniques as a function of temperature and hydrostatic pressure.We would like to thank C.I.C.Y.T. for Grants Nos. MAT94-43 and MAT91-681, U.K. Science Ez. Engineering Research Council for providing Synchrotron Radiation beam time under the E.C. Large Scale Facilities Programme, CNPq and the Programa de Cooperacion Cientifica con Iberoamerica.Peer Reviewe

Magnetoelectric effects in an organo-metallic quantum magnet

We observe a bilinear magnetic field-induced electric polarization of 50 $\mu C/m^2$ in single crystals of NiCl$_2$-4SC(NH$_2$)$_2$ (DTN). DTN forms a tetragonal structure that breaks inversion symmetry, with the highly polar thiourea molecules all tilted in the same direction along the c-axis. Application of a magnetic field between 2 and 12 T induces canted antiferromagnetism of the Ni spins and the resulting magnetization closely tracks the electric polarization. We speculate that the Ni magnetic forces acting on the soft organic lattice can create significant distortions and modify the angles of the thiourea molecules, thereby creating a magnetoelectric effect. This is an example of how magnetoelectric effects can be constructed in organo-metallic single crystals by combining magnetic ions with electrically polar organic elements.Comment: 3 pages, 3 figure

Character of magnetic excitations in a quasi-one-dimensional antiferromagnet near the quantum critical points: Impact on magneto-acoustic properties

We report results of magneto-acoustic studies in the quantum spin-chain magnet NiCl$_2$-4SC(NH$_2$)$_2$ (DTN) having a field-induced ordered antiferromagnetic (AF) phase. In the vicinity of the quantum critical points (QCPs) the acoustic $c_{33}$ mode manifests a pronounced softening accompanied by energy dissipation of the sound wave. The acoustic anomalies are traced up to $T > T_N$, where the thermodynamic properties are determined by fermionic magnetic excitations, the "hallmark" of one-dimensional (1D) spin chains. On the other hand, as established in earlier studies, the AF phase in DTN is governed by bosonic magnetic excitations. Our results suggest the presence of a crossover from a 1D fermionic to a 3D bosonic character of the magnetic excitations in DTN in the vicinity of the QCPs.Comment: 5 pages, 4 figures. Accepted for publication by Phys. Rev

The effects of disorder in dimerized quantum magnets in mean field approximations

We study theoretically the effects of disorder on Bose-Einstein condensates (BEC) of bosonic triplon quasiparticles in doped dimerized quantum magnets. The condensation occurs in a strong enough magnetic field Hc, where the concentration of bosons in the random potential is sufficient to form the condensate. The effect of doping is partly modeled by delta - correlated disorder potential, which (i) leads to the uniform renormalization of the system parameters and (ii) produces disorder in the system with renormalized parameters. These approaches can explain qualitatively the available magnetization data in the Tl_(1-x)K_(x)CuCl_3 compound taken as an example. In addition to the magnetization, we found that the speed of the Bogoliubov mode has a peak as a function of doping parameter, x. No evidence of the pure Bose glass phase has been obtained in the BEC regime.Comment: Includes 19 pages, 5 figure