The diffusion of police innovation: A case study of problem-oriented policing in England and Wales

There is significant evidence demonstrating that when done well, problem-oriented policing is associated with meaningful reductions in crime and public safety concerns. And yet, history shows that the implementation and delivery of problem-oriented policing is challenging, and that police organisations have generally not adopted it and even when they try to it is often rejected over time. This article draws on the concept of ‘diffusion of innovation’ (Rogers, E. (2003) Diffusion of Innovations, 5th edn. New York: Free Press) to unpick aspects of the processes through which problem-oriented policing has been adopted or otherwise among police forces in England and Wales. This article shows how factors related to the nature of problem-oriented policing – notably its incompatibility with prevailing norms and values of the police service, its complexity and unobservability – have influenced its adoption. Implications are also discussed

Si photocathode with Ag-supported dendritic Cu catalyst for CO2 reduction

Si photocathodes integrated with Ag-supported dendritic Cu catalysts are used to perform light-driven reduction of CO2 to C2 and C3 products in aqueous solution. A back illumination geometry with an n-type Si absorber was used to permit the use of absorbing metallic catalysts. Selective carrier collection was accomplished by a p+ implantation on the illumination side and an n+ implantation followed by atomic layer deposition of TiO2 on the electrolyte site. The Ag-supported dendritic Cu CO2 reduction catalyst was formed by evaporation of Ag followed by high-rate electrodeposition of Cu to form a high surface area structure. Under simulated 1 sun illumination in 0.1 M CsHCO3 saturated with CO2, the photovoltage generated by the Si (∼600 mV) enables C2 and C3 products to be produced at -0.4 vs. RHE. Texturing of both sides of the Si increases the light-limited current density, due to reduced reflection on the illumination side, and also deceases the onset potential. Under simulated diurnal illumination conditions photocathodes maintain over 60% faradaic efficiency to hydrocarbon and oxygenate products (mainly ethylene, ethanol, propanol) for several days. After 10 days of testing, contamination from the counter electrode is observed, which causes an increase in hydrogen production. This effect is mitigated by a regeneration procedure which restores the original catalyst selectivity. A tandem, self-powered CO2 reduction device was formed by coupling a Si photocathode with two series-connected semitransparent CH3NH3PbI3 perovskite solar cells, achieving an efficiency for the conversion of sunlight to hydrocarbons and oxygenates of 1.5% (3.5% for all products)

Tracing Galaxy Formation with Stellar Halos II: Relating Substructure in Phase- and Abundance-Space to Accretion Histories

This paper explores the mapping between the observable properties of a stellar halo in phase- and abundance-space and the parent galaxy's accretion history in terms of the characteristic epoch of accretion and mass and orbits of progenitor objects. The study utilizes a suite of eleven stellar halo models constructed within the context of a standard LCDM cosmology. The results demonstrate that coordinate-space studies are sensitive to the recent (0-8 Gyears ago) merger histories of galaxies (this timescale corresponds to the last few to tens of percent of mass accretion for a Milky-Way-type galaxy). Specifically, the {\it frequency, sky coverage} and {\it fraction of stars} in substructures in the stellar halo as a function of surface brightness are indicators of the importance of recent merging and of the luminosity function of infalling dwarfs. The {\it morphology} of features serves as a guide to the orbital distribution of those dwarfs. Constraints on the earlier merger history (> 8 Gyears ago) can be gleaned from the abundance patterns in halo stars: within our models, dramatic differences in the dominant epoch of accretion or luminosity function of progenitor objects leave clear signatures in the [alpha/Fe] and [Fe/H] distributions of the stellar halo - halos dominated by very early accretion have higher average [alpha/Fe], while those dominated by high luminosity satellites have higher [Fe/H]. This intuition can be applied to reconstruct much about the merger histories of nearby galaxies from current and future data sets.Comment: 21 pages, 20 figures. To appear in the Astrophysical Journa

The X-Ray Concentration-Virial Mass Relation

We present the concentration (c)-virial mass (M) relation of 39 galaxy systems ranging in mass from individual early-type galaxies up to the most massive galaxy clusters, (0.06-20) x 10^{14} M_sun. We selected for analysis the most relaxed systems possessing the highest quality data currently available in the Chandra and XMM public data archives. A power-law model fitted to the X-ray c-M relation requires at high significance (6.6 sigma) that c decreases with increasing M, which is a general feature of CDM models. The median and scatter of the c-M relation produced by the flat, concordance LCDM model (Omega_m=0.3, sigma_8=0.9) agrees with the X-ray data provided the sample is comprised of the most relaxed, early forming systems, which is consistent with our selection criteria. Holding the rest of the cosmological parameters fixed to those in the concordance model the c-M relation requires 0.76< sigma_8 <1.07 (99% conf.), assuming a 10% upward bias in the concentrations for early forming systems. The tilted, low-sigma_8 model suggested by a new WMAP analysis is rejected at 99.99% confidence, but a model with the same tilt and normalization can be reconciled with the X-ray data by increasing the dark energy equation of state parameter to w ~ -0.8. When imposing the additional constraint of the tight relation between sigma_8 and Omega_m from studies of cluster abundances, the X-ray c-M relation excludes (>99% conf.) both open CDM models and flat CDM models with Omega_m ~1. This result provides novel evidence for a flat, low-Omega_m universe with dark energy using observations only in the local (z << 1) universe. Possible systematic errors in the X-ray mass measurements of a magnitude ~10% suggested by CDM simulations do not change our conclusions.Comment: Accepted for Publication in ApJ; 13 pages, 4 figures; minor clarifications and updates; correlation coefficients corrected in Table 1 (correct values were used in the analysis in previous versions); conclusions unchange

The Absence of Adiabatic Contraction of the Radial Dark Matter Profile in the Galaxy Cluster A2589

We present an X-ray analysis of the radial mass profile of the radio-quiet galaxy cluster A2589 between 0.015-0.25 r_vir using an XMM-Newton observation. Except for a ~16 kpc shift of the X-ray center of the R=45-60 kpc annulus, A2589 possesses a remarkably symmetrical X-ray image and is therefore an exceptional candidate for precision studies of its mass profile by applying hydrostatic equilibrium. The total gravitating matter profile is well described by the NFW model (fractional residuals <~10%) with c_vir=6.1 +/- 0.3 and M_vir = 3.3 +/- 0.3 x 10^{14} M_sun (r_vir = 1.74 +/- 0.05 Mpc) in excellent agreement with LCDM. When the mass of the hot ICM is subtracted from the gravitating matter profile, the NFW model fitted to the resulting dark matter (DM) profile produces essentially the same result. However, if a component accounting for the stellar mass (M_*) of the cD galaxy is included, then the NFW fit to the DM profile is substantially degraded in the central r ~50 kpc for reasonable M_*/L_V. Modifying the NFW DM halo by adiabatic contraction arising from the early condensation of stellar baryons in the cD galaxy further degrades the fit. The fit is improved substantially with a Sersic-like model recently suggested by high resolution N-body simulations but with an inverse Sersic index, alpha ~0.5, a factor of ~3 higher than predicted. We argue that neither random turbulent motions nor magnetic fields can provide sufficient non-thermal pressure support to reconcile the XMM mass profile with adiabatic contraction of a CDM halo assuming reasonable M_*/L_V. Our results support the scenario where, at least for galaxy clusters, processes during halo formation counteract adiabatic contraction so that the total gravitating mass in the core approximately follows the NFW profile.Comment: 15 pages, 11 figures, accepted for publication in ApJ. Minor changes to match published versio

Gating Alleys to Reduce Crime: A Meta-Analysis and Realist Synthesis

Alley gates are designed to limit access to alleys and the crime opportunities they afford. Informed by the acronym EMMIE we sought to: (1) systematically review the evidence on whether alley gates are Effective at reducing crime, (2) identify the causal Mechanisms through which alley gates are expected to work and the conditions that Moderate effectiveness, and (3) collate information on the Implementation and Economic costs of alley gating. The results of our meta-analysis suggest that alley gating is associated with modest but significant reductions in burglary, with little evidence of spatial displacement. We also identified six mechanisms through which alley gates might plausibly reduce crime, and the conditions in which such mechanisms are most likely to be activated

Canonical Decompositions of n-qubit Quantum Computations and Concurrence

The two-qubit canonical decomposition SU(4) = [SU(2) \otimes SU(2)] Delta [SU(2) \otimes SU(2)] writes any two-qubit quantum computation as a composition of a local unitary, a relative phasing of Bell states, and a second local unitary. Using Lie theory, we generalize this to an n-qubit decomposition, the concurrence canonical decomposition (C.C.D.) SU(2^n)=KAK. The group K fixes a bilinear form related to the concurrence, and in particular any computation in K preserves the tangle ||^2 for n even. Thus, the C.C.D. shows that any n-qubit quantum computation is a composition of a computation preserving this n-tangle, a computation in A which applies relative phases to a set of GHZ states, and a second computation which preserves it. As an application, we study the extent to which a large, random unitary may change concurrence. The result states that for a randomly chosen a in A within SU(2^{2p}), the probability that a carries a state of tangle 0 to a state of maximum tangle approaches 1 as the even number of qubits approaches infinity. Any v=k_1 a k_2 for such an a \in A has the same property. Finally, although ||^2 vanishes identically when the number of qubits is odd, we show that a more complicated C.C.D. still exists in which K is a symplectic group.Comment: v2 corrects odd qubit CCD misstatements, reference chapter for KAK v3 notation change to coincide with sequel, typos. 20 pages, 0 figure

Aircraft Emissions, Their Plume-Scale Effects, and the Spatio-Temporal Sensitivity of the Atmospheric Response:A Review

Non-CO2 aircraft emissions are responsible for the majority of aviation’s climate impact, however their precise effect is largely dependent on the environmental conditions of the ambient air in which they are released. Investigating the principal causes of this spatio-temporal sensitivity can bolster understanding of aviation-induced climate change, as well as offer potential mitigation solutions that can be implemented in the interim to low carbon flight regimes. This review paper covers the generation of emissions and their characteristic dispersion, air traffic distribution, local and global climate impact, and operational mitigation solutions, all aimed at improving scientific awareness of aviation’s non-CO2 climate impact