7,768 research outputs found
Creating pseudo Kondo-resonances by field-induced diffusion of atomic hydrogen
In low temperature scanning tunneling microscopy (STM) experiments a cerium
adatom on Ag(100) possesses two discrete states with significantly different
apparent heights. These atomic switches also exhibit a Kondo-like feature in
spectroscopy experiments. By extensive theoretical simulations we find that
this behavior is due to diffusion of hydrogen from the surface onto the Ce
adatom in the presence of the STM tip field. The cerium adatom possesses
vibrational modes of very low energy (3-4meV) and very high efficiency (> 20%),
which are due to the large changes of Ce-states in the presence of hydrogen.
The atomic vibrations lead to a Kondo-like feature at very low bias voltages.
We predict that the same low-frequency/high-efficiency modes can also be
observed at lanthanum adatoms.Comment: five pages and four figure
Generalizing Boolean Satisfiability III: Implementation
This is the third of three papers describing ZAP, a satisfiability engine
that substantially generalizes existing tools while retaining the performance
characteristics of modern high-performance solvers. The fundamental idea
underlying ZAP is that many problems passed to such engines contain rich
internal structure that is obscured by the Boolean representation used; our
goal has been to define a representation in which this structure is apparent
and can be exploited to improve computational performance. The first paper
surveyed existing work that (knowingly or not) exploited problem structure to
improve the performance of satisfiability engines, and the second paper showed
that this structure could be understood in terms of groups of permutations
acting on individual clauses in any particular Boolean theory. We conclude the
series by discussing the techniques needed to implement our ideas, and by
reporting on their performance on a variety of problem instances
Algebraic Torsion in Contact Manifolds
We extract a nonnegative integer-valued invariant, which we call the "order
of algebraic torsion", from the Symplectic Field Theory of a closed contact
manifold, and show that its finiteness gives obstructions to the existence of
symplectic fillings and exact symplectic cobordisms. A contact manifold has
algebraic torsion of order zero if and only if it is algebraically overtwisted
(i.e. has trivial contact homology), and any contact 3-manifold with positive
Giroux torsion has algebraic torsion of order one (though the converse is not
true). We also construct examples for each nonnegative k of contact 3-manifolds
that have algebraic torsion of order k but not k - 1, and derive consequences
for contact surgeries on such manifolds. The appendix by Michael Hutchings
gives an alternative proof of our cobordism obstructions in dimension three
using a refinement of the contact invariant in Embedded Contact Homology.Comment: 53 pages, 4 figures, with an appendix by Michael Hutchings; v.3 is a
final update to agree with the published paper, and also corrects a minor
error that appeared in the published version of the appendi
A calorimetric study of egg white proteins
Egg white is of great interest for many culinary and industrial applications. Egg white is used for coating, gluing, thickening and so on in pasta, desserts, etc. There is thus a great interest from the industrial point of view to better know this raw material, used in very large amounts in the dessert production for example, and to obtain egg white fractions with different functional properties.
Various egg white fractions prepared by selected procedures were analyzed by differential scanning calorimetry (DSC). The products resulting from a given fractionation procedure can thus be described by the thermal denaturation parameters (temperatures and enthalpies) of the egg white proteins.
This work demonstrates the interest of the DSC technique and proves that the fractionation procedures selected here give the expected protein fractions
A room temperature 19-channel magnetic field mapping device for cardiac signals
We present a multichannel cardiac magnetic field imaging system built in
Fribourg from optical double-resonance Cs vapor magnetometers. It consists of
25 individual sensors designed to record magnetic field maps of the beating
human heart by simultaneous measurements on a grid of 19 points over the chest.
The system is operated as an array of second order gradiometers using
sophisticated digitally controlled feedback loops.Comment: 3 pages, 3 figures, submitted to Applied Physics Letter
Chemical ordering and composition fluctuations at the (001) surface of the Fe-Ni Invar alloy
We report on a study of (001) oriented fcc Fe-Ni alloy surfaces which
combines first-principles calculations and low-temperature STM experiments.
Density functional theory calculations show that Fe-Ni alloy surfaces are
buckled with the Fe atoms slightly shifted outwards and the Ni atoms inwards.
This is consistent with the observation that the atoms in the surface layer can
be chemically distinguished in the STM image: brighter spots (corrugation
maxima with increased apparent height) indicate iron atoms, darker ones nickel
atoms. This chemical contrast reveals a c2x2 chemical order (50% Fe) with
frequent Fe-rich defects on Invar alloy surface. The calculations also indicate
that subsurface composition fluctuations may additionally modulate the apparent
height of the surface atoms. The STM images show that this effect is pronounced
compared to the surfaces of other disordered alloys, which suggests that some
chemical order and corresponding concentration fluctuations exist also in the
subsurface layers of Invar alloy. In addition, detailed electronic structure
calculations allow us to identify the nature of a distinct peak below the Fermi
level observed in the tunneling spectra. This peak corresponds to a surface
resonance band which is particularly pronounced in iron-rich surface regions
and provides a second type of chemical contrast with less spatial resolution
but one that is essentially independent of the subsurface composition.Comment: 7 pages, 5 figure
Causation, Measurement Relevance and No-conspiracy in EPR
In this paper I assess the adequacy of no-conspiracy conditions employed in
the usual derivations of the Bell inequality in the context of EPR
correlations. First, I look at the EPR correlations from a purely
phenomenological point of view and claim that common cause explanations of
these cannot be ruled out. I argue that an appropriate common cause explanation
requires that no-conspiracy conditions are re-interpreted as mere common
cause-measurement independence conditions. In the right circumstances then,
violations of measurement independence need not entail any kind of conspiracy
(nor backwards in time causation). To the contrary, if measurement operations
in the EPR context are taken to be causally relevant in a specific way to the
experiment outcomes, their explicit causal role provides the grounds for a
common cause explanation of the corresponding correlations.Comment: 20 pages, 1 figur
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