Inert gas accumulation in sonoluminescing bubbles

In this paper we elaborate on the idea [Lohse et al., Phys. Rev. Lett. 78, 1359-1362 (1997)] that (single) sonoluminescing air bubbles rectify argon. The reason for the rectification is that nitrogen and oxygen dissociate and their reaction products dissolve in water. We give further experimental and theoretical evidence and extend the theory to other gas mixtures. We show that in the absence of chemical reactions (e.g., for inert gas mixtures) gas accumulation in strongly acoustically driven bubbles can also occur.Comment: J. Chem. Phys., in press (to appear in November 1997), 30 pages, 15 eps-figure

Semiconducting-to-metallic photoconductivity crossover and temperature-dependent Drude weight in graphene

We investigated the transient photoconductivity of graphene at various gate-tuned carrier densities by optical-pump terahertz-probe spectroscopy. We demonstrated that graphene exhibits semiconducting positive photoconductivity near zero carrier density, which crosses over to metallic negative photoconductivity at high carrier density. Our observations are accounted for by considering the interplay between photo-induced changes of both the Drude weight and the carrier scattering rate. Notably, we observed multiple sign changes in the temporal photoconductivity dynamics at low carrier density. This behavior reflects the non-monotonic temperature dependence of the Drude weight, a unique property of massless Dirac fermions

Optical characterization of Bi2_2Se3_3 in a magnetic field: infrared evidence for magnetoelectric coupling in a topological insulator material

We present an infrared magneto-optical study of the highly thermoelectric narrow-gap semiconductor Bi$_2$Se$_3$. Far-infrared and mid-infrared (IR) reflectance and transmission measurements have been performed in magnetic fields oriented both parallel and perpendicular to the trigonal $c$ axis of this layered material, and supplemented with UV-visible ellipsometry to obtain the optical conductivity $\sigma_1(\omega)$. With lowering of temperature we observe narrowing of the Drude conductivity due to reduced quasiparticle scattering, as well as the increase in the absorption edge due to direct electronic transitions. Magnetic fields $H \parallel c$ dramatically renormalize and asymmetrically broaden the strongest far-IR optical phonon, indicating interaction of the phonon with the continuum free-carrier spectrum and significant magnetoelectric coupling. For the perpendicular field orientation, electronic absorption is enhanced, and the plasma edge is slightly shifted to higher energies. In both cases the direct transition energy is softened in magnetic field.Comment: Final versio

Nonmarine Ostracoda as proxies in (geo-)archaeology: a review

Abstract Ostracods as bioindicators are extremely useful for reconstructing palaeoenvironment and palaeoclimate and can also indicate the provenance of sediments and materials, for example, in studies on ancient commercial networks. Ostracods are small crustaceans that live in almost all aquatic habitats, both natural and man-made. Due to their calcitic carapace, they have high fossilization potential, and their use in geoarchaeology has been steadily increasing during the last decades. Their small size needs mean that only small volumes of sediment samples are needed, and species-specific ecological tolerances and preferences allow detailed palaeoenvironmental reconstructions. Typical methods of their application are palaeoecological analyses of associations based on ecological information and taphonomy, morphometric variability and stable isotope and chemistry analyses of their shells. The present paper aims to present an overview of applications of non-marine ostracods in (geo-)archaeological research, recommending sampling and analytical techniques for addressing archaeological research questions on palaeoclimate, habitat and landscape changes, water availability and quality, land use and other anthropogenic impacts, the provenance of materials and commercial networks to promote the application of Ostracoda in geoarchaeology/environmental archaeology.1 Introduction 2 Applications 2.1 short history of ostracod‐based palaeoenvironmental reconstructions 2.2 Palaeoclimate and palaeoenvironmental studies on continental archaeological sites 2.2.1 General palaeoenvironment/landscape reconstructions 2.2.2 Salinity 2.2.3 Temperature 2.2.4 Radiocarbon dating 2.3 Landscape changes by human activity 2.4 Water use and water works 2.5 Provenance studies 3 Methods for sampling and lab analyses 4 Conclusion

The rise of (Chiral) 3D mechanical metamaterials

On the occasion of this special issue, we start by briefly outlining some of the history and future perspectives of the field of 3D metamaterials in general and 3D mechanical metamaterials in particular. Next, in the spirit of a specific example, we present our original numerical as well as experimental results on the phenomenon of acoustical activity, the mechanical counterpart of optical activity. We consider a three-dimensional chiral cubic mechanical metamaterial architecture that is different from the one that we have investigated in recent early experiments. We find even larger linear-polarization rotation angles per metamaterial crystal lattice constant than previously and a slower decrease of the effects towards the bulk lim

Two-component radiation model of the sonoluminescing bubble

Based on the experimental data from Weninger, Putterman & Barber, Phys. Rev. (E), 54, R2205 (1996), we offer an alternative interpretation of their experimetal results. A model of sonoluminescing bubble which proposes that the electromagnetic radiation originates from two sources: the isotropic black body or bramsstrahlung emitting core and dipole radiation-emitting shell of accelerated electrons driven by the liquid-bubble interface is outlined.Comment: 5 pages Revtex, submitted to Phys. Rev.

Detection and Identification of Molecular Water Pollutants by Laser Raman Spectroscopy

Laser Raman spectroscopy is evolving into a primary tool for the Identification of molecular water pollutants. This study pushes the limits of detectivity of carbon disulfide and benzene to ~ 20 ppm in water solutions using a high-resolution Raman spectrometer, cooled detectors, and photon counting techniques. The primary limiting factors were found to be the low throughput and the scattered light performance of the monochromator as well as insufficient laser energy. An optomized design for a pollution-measuring instrument is suggested, and a prototype has been built which is useful with any value of excitation energy short of sample degrading. The present instrument scans spectrum windows with fixed preselecting filters followed by a small single monochromator with high throughput. No detector cooling or refinements in signal processing were attempted. The resulting detectivity with 20 mw of laser power was only 1000 ppm. However, the scattered light background or optical noise is unmeasurable except at the laser frequency, where it was a maximum of six percent of full scale measured against the 992 cm-1 Raman band of benzene. Equipped with an ion laser a practical field instrument capable of detectivity of 1 ppm will cost about $20,000. The instrument described herein can be built for$4,000, less laser