Self-sustainable bio-methanol & bio-char coproduction from 2nd generation biomass gasification

Methanol is an important intermediate in the synthesis of different chemicals. It is mainly produced by reforming of natural gas in centralized facilities with productive capacities on the order of 109 tons per day. Production of methanol from biomass suffers from the cost and logistics of the transportation of biomass and it has not yet maturated into commercial scale. The techno-economic feasibility of the co-production of bio-methanol and bio-char is assessed through detailed computer simulations using process simulator Aspen HYSYS® together with the gasification simulator GASDS. This work further elaborates the previous results on the bio-methanol production process, presenting particularities and updates on previously reported values. The production model is seen to be valid, with payback times that go from 3 to 6 years according to the capacity of the plant (100 to 1000 kt of biomass per year). Self-sustainability is possible but a 50/50 mix of producing and buying electricity yields the most economic choice. © Copyright 2017, AIDIC Servizi S.r.l

Fuzzy adaptive control system of a non-stationary plant with closed-loop passive identifier

Abstract Typically chemical processes have significant nonlinear dynamics, but despite this, industry is conventionally still using PID-based regulatory control systems. Moreover, process units are interconnected, in terms of inlet and outlet material/energy flows, to other neighboring units, thus their dynamic behavior is strongly influenced by these connections and, as a consequence, conventional control systems performance often proves to be poor. This paper proposes a hybrid fuzzy PID control logic, whose tuning parameters are provided in real time. The fuzzy controller tuning is made on the basis of Mamdani controller, also exploiting the results coming from an identification procedure that is carried on when an unmeasured step disturbance of any shape affects the process behavior. In addition, this paper compares a fuzzy logic based PID with PID regulators whose tuning is performed by standard and well-known methods. In some cases the proposed tuning methodology ensures a control performance that is comparable to that guaranteed by simpler and more common tuning methods. However, in case of dynamic changes in the parameters of the controlled system, conventionally tuned PID controllers do not show to be robust enough, thus suggesting that fuzzy logic based PIDs are definitively more reliable and effective

Stopping power of helium gas for ^9Be ions from 2 to 31 MeV

Abstract The stopping power of helium gas for 9Be ions from 2 to 31 MeV is experimentally determined using an indirect method. The residual energy of the 9Be beam as a function of the gas thickness is measured and the stopping power determined by differentiating the thickness–energy curve. The results are compared with predictions of the semi-empirical codes SRIM-2003 and MSTAR. Our data are in better agreement with the MSTAR calculations. The elastic scattering excitation function for the system 9Be + α, extracted using the thick target technique and our stopping power data, is in excellent agreement with the ones measured directly confirming the quality of our data

H2S in geothermal power plants: from waste to additional resource for energy and environment

Geothermal energy is a sustainable and clean energy source. Unfortunately, utilization of high-enthalpy geothermal systems is generally associated with emissions of gases like carbon dioxide (CO2), hydrogen sulfide (H2S), hydrogen (H2), nitrogen (N2), methane (CH4), and argon (Ar). The emission of some of these gases, particularly CO2, H2S and H2, is one of the main environmental concerns associated with the use of geothermal energy. The sequestration of these gases and their geological storage is the most diffuse viable option for reducing emissions. However, there is interesting technology, called AG2STM, that allows to convert H2S and CO2 into syngas. In this work, the match of this technology with geothermal power plant is analyzed as a new potential industrial route. The study is based on two different geothermal power plants located in Hellisheiði and Nesjavellirn (Iceland) that globally emit 61,800 t of CO2 and 28,200 t/y of H2S. The simulations provide some interesting results: (I) the total conversion of H2S that avoids its underground re-injection with the related environmental problem, (II) the reduction of CO2 emissions (about 8 %) and (III) the increasing of the global thermal energy produced with the same amount initial geothermal energy. The latter is due to the possibility to burn extra hydrogen coming from the AG2STM process. Finally, other advantages of this match are the production of an extra medium pressure steam and the possible reuse of the amount of H2 related to the geothermal plants emissions. Copyright © 2018, AIDIC Servizi S.r.l

Magnetic phases and reorientation transitions in antiferromagnetically coupled multilayers

In antiferromagnetically coupled superlattices grown on (001) faces of cubic substrates, e.g. based on materials combinations as Co/Cu, Fe/Si, Co/Cr, or Fe/Cr, the magnetic states evolve under competing influence of bilinear and biquadratic exchange interactions, surface-enhanced four-fold in-plane anisotropy, and specific finite-size effects. Using phenomenological (micromagnetic) theory, a comprehensive survey of the magnetic states and reorientation transitions has been carried out for multilayer systems with even number of ferromagnetic sub-layers and magnetizations in the plane. In two-layer systems (N=2) the phase diagrams in dependence on components of the applied field in the plane include ``swallow-tail'' type regions of (metastable) multistate co-existence and a number of continuous and discontinuous reorientation transitions induced by radial and transversal components of the applied field. In multilayers (N \ge 4) noncollinear states are spatially inhomogeneous with magnetization varying across the multilayer stack. For weak four-fold anisotropy the magnetic states under influence of an applied field evolve by a complex continuous reorientation into the saturated state. At higher anisotropy they transform into various inhomogeneous and asymmetric structures. The discontinuous transitions between the magnetic states in these two-layers and multilayers are characterized by broad ranges of multi-phase coexistence of the (metastable) states and give rise to specific transitional domain structures.Comment: Manuscript 34 pages, 14 figures; submitted for publicatio

The Neuronal EGF-Related Gene Nell2 Interacts with Macf1 and Supports Survival of Retinal Ganglion Cells after Optic Nerve Injury

Nell2 is a neuron-specific protein containing six epidermal growth factor-like domains. We have identified Nell2 as a retinal ganglion cell (RGC)-expressed gene by comparing mRNA profiles of control and RGC-deficient rat retinas. The aim of this study was to analyze Nell2 expression in wild-type and optic nerve axotomized retinas and evaluate its potential role in RGCs. Nell2-positive in situ and immunohistochemical signals were localized to irregularly shaped cells in the ganglion cell layer (GCL) and colocalized with retrogradely-labeled RGCs. No Nell2-positive cells were detected in 2 weeks optic nerve transected (ONT) retinas characterized with approximately 90% RGC loss. RT-PCR analysis showed a dramatic decrease in the Nell2 mRNA level after ONT compared to the controls. Immunoblot analysis of the Nell2 expression in the retina revealed the presence of two proteins with approximate MW of 140 and 90 kDa representing glycosylated and non-glycosylated Nell2, respectively. Both products were almost undetectable in retinal protein extracts two weeks after ONT. Proteome analysis of Nell2-interacting proteins carried out with MALDI-TOF MS (MS) identified microtubule-actin crosslinking factor 1 (Macf1), known to be critical in CNS development. Strong Macf1 expression was observed in the inner plexiform layer and GCL where it was colocalizied with Thy-1 staining. Since Nell2 has been reported to increase neuronal survival of the hippocampus and cerebral cortex, we evaluated the effect of Nell2 overexpression on RGC survival. RGCs in the nasal retina were consistently more efficiently transfected than in other areas (49% vs. 13%; n = 5, p<0.05). In non-transfected or pEGFP-transfected ONT retinas, the loss of RGCs was approximately 90% compared to the untreated control. In the nasal region, Nell2 transfection led to the preservation of approximately 58% more cells damaged by axotomy compared to non-transfected (n = 5, p<0.01) or pEGFP-transfected controls (n = 5, p<0.01)