The Strongest 100 Point Radio Sources in the LMC at 1.4 GHz

We present the 100 strongest 1.4 GHz point sources from a new mosaic image in the direction of the Large Magellanic Cloud (LMC). The observations making up the mosaic were made over a ten year period and were combined with Parkes single dish data at 1.4 GHz to complete the image for short spacing. An initial list of co-identifications within 10" at 0.843, 4.8 and 8.6 GHz consisted of 2682 sources. Elimination of extended objects and artifact noise allowed the creation of a refined list containing 1988 point sources. Most of these are presumed to be background objects seen through the LMC; a small portion may represent compact H II regions, young SNRs and radio planetary nebulae. For the 1988 point sources we find a preliminary average spectral index of -0.53 and present a 1.4 GHz image showing source location in the direction of the LMC.Comment: 8 pages, 2 figure

Multifrequency radio observations of SNR J0536-6735 (N 59B) with associated pulsar

We present a study of new Australian Telescope Compact Array (ATCA) observations of supernova remnant, SNR J0536-6735. This remnant appears to follow a shell morphology with a diameter of D=36x29 pc (with 1 pc uncertainty in each direction). There is an embedded Hii region on the northern limb of the remnant which made various analysis and measurements (such as flux density, spectral index and polarisation) difficult. The radio-continuum emission followed the same structure as the optical emission, allowing for extent and flux density estimates at 20 cm. We estimate a surface brightness for the SNR at 1 GHz of 2.55x10^-21 W m^-2 Hz^-1 sr^-1. Also, we detect a distinctive radio-continuum point source which confirms the previous suggestion of this remnant being associated with a pulsar wind nebulae (PWN). The tail of this remnant isn't seen in the radio-continuum images and is only seen in the optical and X-ray images.Comment: 10 pages 4 figures, accepted for publication in SA

Multi-frequency study of Local Group Supernova Remnants The curious case of the Large Magellanic Cloud SNR J0528-6714

Aims. Recent ATCA, XMM-Newton and MCELS observations of the Magellanic Clouds (MCs) cover a number of new and known SNRs which are poorly studied, such as SNR J0528-6714 . This particular SNR exhibits luminous radio-continuum emission, but is one of the unusual and rare cases without detectable optical and very faint X-ray emission (initially detected by ROSAT and listed as object [HP99] 498). We used new multi-frequency radio-continuum surveys and new optical observations at H{\alpha}, [S ii] and [O iii] wavelengths, in combination with XMM-Newton X-ray data, to investigate the SNR properties and to search for a physical explanation for the unusual appearance of this SNR. Methods. We analysed the X-ray and Radio-Continuum spectra and present multi-wavelength morphological studies of this SNR. Results. We present the results of new moderate resolution ATCA observations of SNR J0528-6714. We found that this object is a typical older SNR with a radio spectral index of {\alpha}=-0.36 \pm 0.09 and a diameter of D=52.4 \pm 1.0 pc. Regions of moderate and somewhat irregular polarisation were detected which are also indicative of an older SNR. Using a non-equilibrium ionisation collisional plasma model to describe the X-ray spectrum, we find temperatures kT of 0.26 keV for the remnant. The low temperature, low surface brightness, and large extent of the remnant all indicate a relatively advanced age. The near circular morphology indicates a Type Ia event. Conclusions. Our study revealed one of the most unusual cases of SNRs in the Local Group of galaxies - a luminous radio SNR without optical counterpart and, at the same time, very faint X-ray emission. While it is not unusual to not detect an SNR in the optical, the combination of faint X-ray and no optical detection makes this SNR very unique.Comment: 6 pages, 5 figures, Accepted for publication in A&

20 cm VLA Radio-Continuum Study of M31 - Images and Point Source Catalogues

We present a series of new high-sensitivity and high-resolution radio-continuum images of M31 at \lambda=20 cm (\nu=1.4 GHz). These new images were produced by merging archived 20 cm radio-continuum observations from the Very Large Array (VLA) telescope. Images presented here are sensitive to rms=60 \mu Jy and feature high angular resolution (<10"). A complete sample of discrete radio sources have been catalogued and analysed across 17 individual VLA projects. We identified a total of 864 unique discrete radio sources across the field of M31. One of the most prominent regions in M31 is the ring feature for which we estimated total integrated flux of 706 mJy at \lambda=20 cm. We compare here, detected sources to those listed in Gelfand et al. (2004) at \lambda=92 cm and find 118 sources in common to both surveys. The majority (61%) of these sources exhibit a spectral index of \alpha <-0.6 indicating that their emission is predominantly non-thermal in nature. That is more typical for background objects.Comment: 28 pages, 25 figures, accepted for publication in the Serbian Astronomical Journa

Multifrequency Radio Observations of a SNR in the LMC. The Case of SNR J0527-6549 (DEM l204)

We present a detailed study and results of new Australia Telescope Compact Array (ATCA) observations of supernova remnant, SNR J0527-6549. This Large Magellanic Cloud (LMC) ob ject follows a typical supernova remnant (SNR) horseshoe morphology with a diameter of D=(66x58)+-1 pc which is among the largest SNRs in the LMC. Its relatively large size indicates older age while a steeper than expected radio spectral index of aplha=-0.92+-0.11 is more typical for younger and energetic SNRs. Also, we report detections of regions with a high order of polarization at a peak value of ~54+-17% at 6 cm.Comment: 9 Pages, 6 figures, accepted for publication in SA

On the ordeal of quinolone preparation via cyclisation of aryl-enamines; synthesis and structure of ethyl 6-methyl-7-iodo-4-(3-iodo-4-methylphenoxy)-quinoline-3-carboxylate

Recent studies directed to the design of compounds targeting the bc(1) protein complex of Plasmodium falciparum, the parasite responsible for most lethal cases of malaria, identified quinolones (4-oxo-quinolines) with low nanomolar inhibitory activity against both the enzyme and infected erythrocytes. The 4-oxo-quinoline 3-ester chemotype emerged as a possible source of potent bc(1) inhibitors, prompting us to expand the library of available analogs for SAR studies and subsequent lead optimization. We now report the synthesis and structural characterization of unexpected ethyl 6-methyl-7-iodo-4-(3-iodo-4-methylphenoxy)quinoline-3-carboxylate, a 4-aryloxy-quinoline 3-ester formed during attempted preparation of 6-methyl-7-iodo-4-oxo-quinoline-3-carboxylate (4-oxo-quinoline 3-ester). We propose that the 4-aryloxy-quinoline 3-ester derives from 6-methyl-7-iodo-4-hydroxy-quinoline-3-carboxylate (4-hydroxy-quinoline 3-ester), the enol form of 6-methyl-7-iodo-4-oxo-quinoline-3-carboxylate. Formation of the 4-aryloxy-quinoline 3-ester confirms the impact of quinolone/hydroxyquinoline tautomerism, both on the efficiency of synthetic routes to quinolones and on pharmacologic profiles. Tautomers exhibit different cLogP values and interact differently with the enzyme active site. A structural investigation of 6-methyl-7-iodo-4-oxo-quinoline-3-carboxylate and 6-methyl-7-iodo-4-hydroxy-quinoline-3-carboxylate, using matrix isolation coupled to FTIR spectroscopy and theoretical calculations, revealed that the lowest energy conformers of 6-methyl-7-iodo-4-hydroxy-quinoline-3-carboxylate, lower in energy than their most stable 4-oxo-quinoline tautomer by about 27 kJ mol(-1), are solely present in the matrix, while the most stable 4-oxo-quinoline tautomer is solely present in the crystalline phase.Fundacao para a Ciencia e Tecnologia (FCT - Portugal) [UID/Multi/04326/2013]; QREN-COMPETE-UE; CCMAR; FCT [SFRH/BD/81821/2011, RECI/BBB-BQB/0230/2012, UI0313/QUI/2013, UID/FIS/04564/2016]; FEDER/COMPETE-UE; [PTDC/QEQ-QFI/3284/2014 - POCI-01-0145-FEDER-016617]info:eu-repo/semantics/publishedVersio

Bankruptcy prediction in Brazil: a two-stage model employing accounting data

Para tentar medir e prever a “saúde financeira” de empresas, pode-se usar os chamados modelos de previsão de insolvência, construídos com apoio em técnicas estatísticas e aplicados para analisar índices econômico-financeiros selecionados, obtidos a partir dos demonstrativos contábeis. A partir da metade dos anos 90, questões tais como o aparecimento de novas técnicas de modelagem, a crescente importância da gerência do risco de crédito e as condições econômicas vigentes trouxeram de volta o interesse pela análise e previsão da insolvência de empresas. O objetivo deste artigo é descrever um método para elaboração de modelos de previsão de insolvência, fundamentado em técnicas estatísticas, e ilustrá-lo através de uma aplicação empírica a uma amostra de empresas comerciais e industriais brasileiras, empregando dados para o período de 1996 a 2000.It may happen that firms collapse irrespective of their financial statements being published in a regular basis and being prepared according to professional accounting standards and statutory requirements. The relationship between accounting data and business failure therefore deserves ongoing and expert attention. Bankruptcy prediction refers to the search for applicable models or procedures allowing to anticipate convincing signals of future problems.This paper proposes an empirical model for bankruptcy prediction that proceeds in two-stages: the first seeks to select appropriate predictors; the second employs discriminant analysis to classify successful and bankrupt firms. Empirical information has been collected from accounting data published by the Brazilian equivalent of SEC and refers to the period 1996 / 2000. Considering comparable figures reported in the literature, retained models obtain quite good hit ratios. For the selected time period, accounting data may be considered a convenient empirical support to predict bankruptcy in the Brazilian context