1,110 research outputs found
Magnetic correlations in La(2-x)Sr(x)CuO4 from NQR relaxation and specific heat
La-139 and Cu-63 Nuclear Quadrupole Resonance (NQR) relaxation measurements in La(2-x)Sr(x)CuO4 for O = to or less than 0.3 and in the temperature range 1.6 + 450 K are analyzed in terms of Cu(++) magnetic correlations and dynamics. It is described how the magnetic correlations that would result from Cu-Cu exchange are reduced by mobile charge defects related to x-doping. A comprehensive picture is given which explains satisfactorily the x and T dependence of the correlation time, of the correlation length and of the Neel temperature T(sub n)(x) as well as being consistent with known electrical resistivity and magnetic susceptibility measurements. It is discussed how, in the superconducting samples, the mobile defects also cause the decrease, for T yields T(sub c)(+) of the hyperfine Cu electron-nucleus effective interaction, leading to the coexistence of quasi-localized, reduced magnetic moments from 3d Cu electrons and mobile oxygen p-hole carriers. The temperature dependence of the effective hyperfine field around the superconducting transition yields an activation energy which could be related to the pairing energy. New specific heat measurements are also presented and discussed in terms of the above picture
Lattice effects on the spin dynamics in antiferromagnetic molecular rings
We investigate spin dynamics in antiferromagnetic (AF) molecular rings at
finite temperature in the presence of spin-phonon (s-p) interaction. We derive
a general expression for the spin susceptibility in the weak s-p coupling limit
and then we focus on the low-frequency behavior, in order to discuss a possible
microscopic mechanism for nuclear relaxation in this class of magnetic
materials. To lowest order in a perturbative expansion, we find that the
susceptibility takes a Lorentzian profile and all spin operators (, ) contribute to spin dynamics at wave vectors . Spin anisotropies
and local s-p coupling play a key role in the proposed mechanism. Our results
prove that small changes in the spatial symmetry of the ring induce qualitative
changes in the spin dynamics at the nuclear frequency, providing a novel
mechanism for nuclear relaxation. Possible experiments are proposed.Comment: 4 pages, 2 figures. to appear in PR
Tunneling splitting of magnetic levels in Fe8 detected by 1H NMR cross relaxation
Measurements of proton NMR and the spin lattice relaxation rate 1/T1 in the
octanuclear iron (III) cluster [Fe8(N3C6H15)6O2(OH)12][Br8 9H2O], in short Fe8,
have been performed at 1.5 K in a powder sample aligned along the main
anisotropy z axis, as a function of a transverse magnetic field (i.e.,
perpendicular to the main easy axis z). A big enhancement of 1/T1 is observed
over a wide range of fields (2.5-5 T), which can be attributed to the tunneling
dynamics; in fact, when the tunneling splitting of the pairwise degenerate
m=+-10 states of the Fe8 molecule becomes equal to the proton Larmor frequency
a very effective spin lattice relaxation channel for the nuclei is opened. The
experimental results are explained satisfactorily by considering the
distribution of tunneling splitting resulting from the distribution of the
angles in the hard xy plane for the aligned powder, and the results of the
direct diagonalization of the model Hamiltonian.Comment: J. Appl. Phys., in pres
Probing spin dynamics and quantum relaxation in LiY0.998Ho0.002F4 via 19F NMR
We report measurements of 19F nuclear spin-lattice relaxation 1/T1 as a
function of temperature and external magnetic field in LiY0.998Ho0.002F4 single
crystal, a single-ion magnet exhibiting interesting quantum effects. The 19F
1/T1 is found to depend on the coupling with the diluted rare-earth (RE)
moments. Depending on the temperature range, a fast spin diffusion regime or a
diffusion limited regime is encountered. In both cases we find it possible to
use the 19F nucleus as a probe of the rare-earth spin dynamics. The results for
1/T1 show a behavior similar to that observed in molecular nanomagnets, a
result which we attribute to the discreteness of the energy levels in both
cases. At intermediate temperatures the lifetime broadening of the crystal
field split RE magnetic levels follows a T3 power law. At low temperature the
field dependence of 1/T1 shows peaks in correspondence to the critical magnetic
fields for energy level crossings (LC). The results can be explained by
inelastic scattering between the fluorine nuclear spins and the RE magnetic
levels. A key result of this study is that the broadening of the levels at LC
is found to be become extremely small at low temperatures, about 1.7 mT, a
value which is comparable to the weak dipolar fields at the RE lattice
positions. Thus, unlike the molecular magnets, decoherence effects are strongly
suppressed, and it may be possible to measure directly the level repulsions at
avoided level crossings.Comment: 21 pages, 5 figure
Magnetic properties and spin dynamics in single molecule paramagnets Cu6Fe and Cu6Co
The magnetic properties and the spin dynamics of two molecular magnets have
been investigated by magnetization and d.c. susceptibility measurements,
Electron Paramagnetic Resonance (EPR) and proton Nuclear Magnetic Resonance
(NMR) over a wide range of temperature (1.6-300K) at applied magnetic fields,
H=0.5 and 1.5 Tesla. The two molecular magnets consist of
CuII(saldmen)(H2O)}6{FeIII(CN)6}](ClO4)38H2O in short Cu6Fe and the analog
compound with cobalt, Cu6Co. It is found that in Cu6Fe whose magnetic core is
constituted by six Cu2+ ions and one Fe3+ ion all with s=1/2, a weak
ferromagnetic interaction between Cu2+ moments through the central Fe3+ ion
with J = 0.14 K is present, while in Cu6Co the Co3+ ion is diamagnetic and the
weak interaction is antiferromagnetic with J = -1.12 K. The NMR spectra show
the presence of non equivalent groups of protons with a measurable contact
hyperfine interaction consistent with a small admixture of s-wave function with
the d-function of the magnetic ion. The NMR relaxation results are explained in
terms of a single ion (Cu2+, Fe3+, Co3+) uncorrelated spin dynamics with an
almost temperature independent correlation time due to the weak magnetic
exchange interaction. We conclude that the two molecular magnets studied here
behave as single molecule paramagnets with a very weak intramolecular
interaction, almost of the order of the dipolar intermolecular interaction.
Thus they represent a new class of molecular magnets which differ from the
single molecule magnets investigated up to now, where the intramolecular
interaction is much larger than the intermolecular one
Spin dynamics in hole-doped two-dimensional S=1/2 Heisenberg antiferromagnets: ^{63}Cu NQR relaxation in La_{2-x}Sr_xCuO_4 for
The effects on the correlated Cu^{2+} S = 1/2 spin dynamics in the
paramagnetic phase of La_{2-x}Sr_xCuO_4 (for ) due to the
injection of holes are studied by means of ^{63}Cu NQR spin-lattice relaxation
time T_1 measurements. The results are discussed in the framework of the
connection between T_1 and the in-plane magnetic correlation length
. It is found that at high temperatures the system remains in
the renormalized classical regime, with a spin stiffness constant
reduced by small doping to an extent larger than the one due to Zn doping. For
the effect of doping on appears to level off. The
values for derived from T_1 for K are much larger
than the ones estimated from the temperature behavior of sublattice
magnetization in the ordered phase (). It is argued that these
features are consistent with the hypothesis of formation of stripes of
microsegregated holes.Comment: 10 pages, 3 figure
Dynamics of Magnetic Defects in Heavy Fermion LiV2O4 from Stretched Exponential 7Li NMR Relaxation
7Li NMR measurements on LiV2O4 from 0.5 to 4.2 K are reported. A small
concentration of magnetic defects within the structure drastically changes the
7Li nuclear magnetization relaxation versus time from a pure exponential as in
pure LiV2O4 to a stretched exponential, indicating glassy behavior of the
magnetic defects. The stretched exponential function is described as arising
from a distribution of 7Li nuclear spin-lattice relaxation rates and we present
a model for the distribution in terms of the dynamics of the magnetic defects.
Our results explain the origin of recent puzzling 7Li NMR literature data on
LiV2O4 and our model is likely applicable to other glassy systems.Comment: Four typeset pages including four figure
19F nuclear spin relaxation and spin diffusion effects in the single ion magnet LiYF4:Ho3+
Temperature and magnetic field dependences of the 19F nuclear spin-lattice
relaxation in a single crystal of LiYF4 doped with holmium are described by an
approach based on a detailed consideration of the magnetic dipole-dipole
interactions between nuclei and impurity paramagnetic ions and nuclear spin
diffusion processes. The observed non-exponential long time recovery of the
nuclear magnetization after saturation at intermediate temperatures is in
agreement with predictions of the spin-diffusion theory in a case of the
diffusion limited relaxation. At avoided level crossings in the spectrum of
electron-nuclear states of the Ho3+ ion, rates of nuclear spin-lattice
relaxation increase due to quasi-resonant energy exchange between nuclei and
paramagnetic ions, in contrast to the predominant role played by electronic
cross-relaxation processes in the low-frequency ac-susceptibility.Comment: 27 pages total, 5 figures, accepted for publication, Eur. Phys. J.
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