Nitrogen dioxide vapor penetration of chlorobutyl rubber SCAPE under operational conditions

Operational self contained atmospheric protective ensembles (SCAPE suits) and fabric from the suits were subjected to a series of tests designed to determine the amount of exposure a wearer of the suit would receive if a spill of the hypergolic oxidizer nitrogen tetroxide (N2O4) should occur nearby. The results of these tests show that a wearer of a "stock" SCAPE suit equipped with a standard liquid air pack, if exposed to a spill resulting in a 26 percent increase of oxidizer in the surrounding atmosphere, will experiment no detectable concentration of nitrogen dioxide (NO2) inside the suit for 15 minutes. Thereafter, the NO2 concentration within the suit will increase for 35 minutes at a rate of 0.07 ppm per minute and then at a gradually decreasing rate until an equilibrium concentration of 3.4 ppm is attained after 100 minutes. Momentary increases of as much as 1.6 ppm can be expected if the wearer were to rise quickly from a squatting position, but the additional NO2 would be dissipated within three minutes. The effect of liquid and vapor N2O4 and of liquid monomethylhydrazine on permeation rates and tensile strength of the SCAPE suit fabric was also investigated

“The Street Was One Place We Could Not Go”: The American Army and Urban Combat in World War II Europe

Much has been written about the nature of the United States Army in World War II and the topic of military effectiveness. This dissertation examines how the United States responded to a combat environment, specifically, fighting in built-up areas, that it had not planned to fight within before World War II. By following three infantry divisions, the 1st, 3rd, and 5th Infantry Divisions through their combat in World War II, this dissertation investigates how the Army of the United States fought within the urban setting to see whether the American Army improved and became more effective as the war continued. It argues that the 1st, 3rd, and 5th Infantry Divisions learned and became more proficient at urban combat over time. This dissertation asserts that as these divisions embraced combined-arms operations in general, that is, mastered the coordination of infantry weapons, armor, and artillery into battle, so they applied those lessons to the urban environment. Whereas the American military had neither doctrine nor tradition of urban combat before World War II, combat units learned to develop methods of fighting within towns and cities. Further, the United States Army processed and incorporated these battlefield lessons into military doctrine at a slower rate. The infantry divisions’ combat experience had a greater impact on army doctrine than the doctrine had on the divisions’ warfighting practices

Is complex fault zone behaviour a reflection of rheological heterogeneity?

Fault slip speeds range from steady plate boundary creep through to earthquake slip. Geological descriptions of faults range from localized displacement on one or more discrete planes, through to distributed shearing flow in tabular zones of finite thickness, indicating a large range of possible strain rates in natural faults. We review geological observations and analyse numerical models of two-phase shear zones to discuss the degree and distribution of fault zone heterogeneity and effects on active fault slip style. There must be certain conditions that produce earthquakes, creep and slip at intermediate velocities. Because intermediate slip styles occur over large ranges in temperature, the controlling conditions must be effects of fault properties and/or other dynamic variables. We suggest that the ratio of bulk driving stress to frictional yield strength, and viscosity contrasts within the fault zone, are critical factors. While earthquake nucleation requires the frictional yield to be reached, steady viscous flow requires conditions far from the frictional yield. Intermediate slip speeds may arise when driving stress is sufficient to nucleate local frictional failure by stress amplification, or local frictional yield is lowered by fluid pressure, but such failure is spatially limited by surrounding shear zone stress heterogeneity

Neutrinos from Early-Phase, Pulsar-Driven Supernovae

Neutron stars, just after their formation, are surrounded by expanding, dense, and very hot envelopes which radiate thermal photons. Iron nuclei can be accelerated in the wind zones of such energetic pulsars to very high energies. These nuclei photo-disintegrate and their products lose energy efficiently in collisions with thermal photons and with the matter of the envelope, mainly via pion production. When the temperature of the radiation inside the envelope of the supernova drops below $\sim 3\times 10^6$ K, these pions decay before losing energy and produce high energy neutrinos. We estimate the flux of muon neutrinos emitted during such an early phase of the pulsar - supernova envelope interaction. We find that a 1 km$^2$ neutrino detector should be able to detect neutrinos above 1 TeV within about one year after the explosion from a supernova in our Galaxy. This result holds if these pulsars are able to efficiently accelerate nuclei to energies $\sim 10^{20}$ eV, as postulated recently by some authors for models of Galactic acceleration of the extremely high energy cosmic rays (EHE CRs).Comment: 16 pages, 3 figures, revised version submitted to Ap

Constraint on the mass scale of a left-right-symmetric electroweak theory from the KL-KS mass difference

The KL-KS mass difference provides a stringent constraint on the mass (MR) of the charged right-handed gauge field occurring in a "manifest" left-right-symmetric electroweak theory, yielding MR1.6 TeV. Taken in the context of a grand-unifying gauge theory, e.g., O(10), such a large bound on MR, along with the measured value of sin2θW, implies that MR109 GeV. © 1982 The American Physical Society

Polymerization of Methyl Methacrylate by Heat-Catalyst and Gamma-Irradiation Methods

Methyl methacrylate (MMA) was bulk-polymerized with 0 to 4% crosslinker (ethylene glycol dimethacrylate, EGDM, and trimethylol propane trimethacrylate, TMPTM), initiated with 0.05 to 5% catalyst (Vazo) at 65-75 C or 0.1 to 1 Mrad/hr gamma radiation at 20 C. Heat-catalyzed MMA conversion to polymer vs. time was obtained directly from polymer mass, which indicated that about 90% conversion had occurred at the exothermic peak temperature. The time to the exothermic peak temperature was used to determine sample polymerization time. The over-all polymerization rate varied with the half-power of initiator concentration. An Arrhenius plot of the initiator-time data gave an activation energy of 18 kcal/mole. A log-log relationship was found between crosslinker concentration and polymerization time over the 65-75 C temperature and 0.1-0.4% initiator range. The crosslinkers were found equally efficient in reducing polymerization time. Peak exothermie temperature varied directly with time, irrespective of the initiator and crosslinker concentrations or bath temperature except as they affected time. In the irradiation tests, the crosslinkers exhibited different data fits: log-log with EGDM and semilog for TMPTM. The time-dose rate equation for uncrosslinked MMA was analogous to that for heat-catalyzed polymerization. Molecular weight of uncrosslinked PMMA was determined as a function of temperature and catalyst concentration, and dose rate. Similar molecular weights were obtained for heat-catalyzed polymerization at 65 C and gamma irradiation at 20 C for numerically the same initiator concentration (%) and does rate (Mrad/hr)

Big Green And Careful: How major California Newspapers Covered Two Ballot Initiatives in the 1990 General Election

Big Green And Careful: How major California Newspapers Covered Two Ballot Initiatives in the 1990 General Electio