Study of mechanisms controlling the ultraviolet photochemistry of associated and polymeric systems

Vacuum ultraviolet photoionization and photodissociation of associated and polymeric systems of liquid water and alcohol

Methyl bromide: Ocean sources, ocean sinks, and climate sensitivity

The oceans play an important role in the geochemical cycle of methyl bromide (CH_3Br), the major carrier of O_3-destroying bromine to the stratosphere. The quantity of CH_3Br produced annually in seawater is comparable to the amount entering the atmosphere each year from natural and anthropogenic sources. The production mechanism is unknown but may be biological. Most of this CH_3Br is consumed in situ by hydrolysis or reaction with chloride. The size of the fraction which escapes to the atmosphere is poorly constrained; measurements in seawater and the atmosphere have been used to justify both a large oceanic CH_3Br flux to the atmosphere and a small net ocean sink. Since the consumption reactions are extremely temperature-sensitive, small temperature variations have large effects on the CH_3Br concentration in seawater, and therefore on the exchange between the atmosphere and the ocean. The net CH_3Br flux is also sensitive to variations in the rate of CH_3Br production. We have quantified these effects using a simple steady state mass balance model. When CH_3Br production rates are linearly scaled with seawater chlorophyll content, this model reproduces the latitudinal variations in marine CH_3Br concentrations observed in the east Pacific Ocean by Singh et al. [1983] and by Lobert et al. [1995]. The apparent correlation of CH_3Br production with primary production explains the discrepancies between the two observational studies, strengthening recent suggestions that the open ocean is a small net sink for atmospheric CH_3Br, rather than a large net source. The Southern Ocean is implicated as a possible large net source of CH_3Br to the atmosphere. Since our model indicates that both the direction and magnitude of CH_3Br exchange between the atmosphere and ocean are extremely sensitive to temperature and marine productivity, and since the rate of CH_3Br production in the oceans is comparable to the rate at which this compound is introduced to the atmosphere, even small perturbations to temperature or productivity can modify atmospheric CH_3Br. Therefore atmospheric CH_3Br should be sensitive to climate conditions. Our modeling indicates that climate-induced CH_3Br variations can be larger than those resulting from small (±25%) changes in the anthropogenic source, assuming that this source comprises less than half of all inputs. Future measurements of marine CH_3Br, temperature, and primary production should be combined with such models to determine the relationship between marine biological activity and CH_3Br production. Better understanding of the biological term is especially important to assess the importance of non anthropogenic sources to stratospheric ozone loss and the sensitivity of these sources to global climate change

Self-hypnosis for anxiety associated with severe asthma: a case report

BACKGROUND: Management of asthma can be complicated by both medical and psychiatric conditions, such as gastroesophageal reflux, chronic sinusitis, and anxiety. When symptoms of asthma are interpreted without regard to such conditions treatment may yield a suboptimal outcome. For example, anxiety-associated dyspnea, tachypnea, and chest tightness can be mistakenly interpreted as resulting from an exacerbation of asthma. Medical treatment directed only for asthma may thus lead to overuse of asthma medications and increased hospitalizations. CASE PRESENTATION: The described case illustrates how a systemic steroid-dependent patient with asthma benefited from receiving care from a pediatric pulmonologist who also was well versed in the diagnosis and treatment of anxiety. By using self-hypnosis, the patient was able to reduce her dependence on bronchodilators. Following modification of her medical therapy under supervision of the pulmonologist, and regular use of hypnosis, the patient ultimately was weaned off her systemic steroid therapy. CONCLUSIONS: This report emphasizes that anxiety must be considered as a comorbid condition in the treatment of asthma. Self-hypnosis can be a useful skill in the treatment of a patient with anxiety and asthma

Adsorption of HO_x on Aerosol Surfaces: Implications for the Atmosphere of Mars

The potential impact of heterogeneous chemistry on the abundance and distribution of HO_x in the atmosphere of Mars has been assessed by combining observational data of dust and ice aerosol distributions with an updated photochemical model. Critical parameters include the altitude distributions of aerosols, and the surface loss coefficients (γ) of HO_2 on dust and ice in the lower atmosphere, and H on ice above 40 km. We find that adsorption of HO_2 on dust (γHO_2 ≥ 0.01), or ice near 30 km (γHO_2 ≥ 0.1), can deplete OH abundances in the lower atmosphere by 10% or more. Such depletions approach those obtained by lowering the water vapor abundance by an order of magnitude below the global average observed by Viking (≈ 25%). Since the oxidation of CO is catalyzed by HO_x in the lower atmosphere via the reaction CO + OH → CO_2 + H, loss of OH due to adsorption of HO_2 on dust or ice at low altitudes could have a significant effect on the ratio CO : CO_2. The adsorption of H on ice at 50 km (γ_H ≥ 0.01) can result in even larger OH depletions. However, this effect is localized to altitudes > 40 km, where CO oxidation is relatively unimportant. Laboratory data suggest that γHO_2 ≈ 0.01 is a reasonable estimate for adsorption on dust. Larger values are plausible, but are not strongly supported by experimental evidence. The reactivity of HO_2 on ice is unknown, while γH on ice appears to be < 0.001. There is a need for measurements of HO_x adsorption on surfaces representative of Martian aerosols at temperatures < 220 K

Review of Prevention Schemes for Man-In-The-Middle (MITM) Attack in Vehicular Ad hoc Networks

Vehicular Ad-Hoc Network (VANET) is an indispensable part of the Intelligent Transportation System (ITS) due to its abilities to enhance traffic management and safety. Many researchers have been focused on specific areas involving management and storage data, protocols standardization, network fragmentation, monitoring, and quality of service. &nbsp;The benchmarks of security of VANET are studied and figured out in this paper. VANET provides the driver and passenger with the safety application as well as entertainment service. However, the communication between nodes in VANET is susceptible to security threats in both communication modes, which indicates the main hazard. In this paper, we identified different Man-In-The-Middle (MITM) attacks with various behaviors such as message tampering, message delaying, and message dropping, according to the literature. In this study, the essential background of VANET from architectural point of view and communication types are discussed. Then, the overview of MITM attack in VANET is presented. In addition, this paper thoroughly reviews the existing prevention schemes for MITM attack in VANET. This review paper reveals that there is still a need for a better and more efficient preventive scheme to address the MITM attack in VANET. This review paper could serve as evidence and reference in the development of any new security schemes for VANETs

Review of Prevention Schemes for Modification Attack in Vehicular Ad hoc Networks

Vehicular Ad-hoc Network (VANET) technology is the basis of Intelligent Transportation System (ITS) connectivity that enables the delivery of useful information to and fro between vehicles in vehicle-to-vehicle communication mode; or between vehicle and infrastructure in vehicle-to-infrastructure mode for safety and comfort. However, due to the openness of the wireless medium used by VANET, the technology is vulnerable to security threats in both communication modes. In this study, the essential background of VANET from architectural point of view and communication types are discussed. Then, the overview of modification attack in VANET is presented. In addition, this paper thoroughly reviews the existing prevention schemes for modification attack in VANET. This review paper reveals that there is still a need for a better and more efficient preventive scheme to address the modification attack in VANET

Neutron emissions in brittle rocks during compression tests: Monotonic vs cyclic loading

Neutron emission measurements, by means of 3He devices and neutron bubble detectors, were performed during two different kinds of compression tests on brittle rocks: (i) under displacement control, and (ii) under cyclic loading. The material used for the tests was Green Luserna Granite, with different specimen sizes and shapes, and consequently with different brittleness numbers. Since the analyzed material contains iron, our conjecture is that piezonuclear reactions involving fission of iron into aluminum, or into magnesium and silicon, should have occurred during compression damage and failure. Some studies have been already conducted on the different forms of energy emitted during the failure of brittle materials. They are based on the signals captured by acoustic emission measurement systems, or on the detection of electromagnetic charge. On the other hand, piezonuclear neutron emissions from very brittle rock specimens in compression have been discovered only very recently. In this paper, the authors analyse this phenomenon from an experimental point of vie

Corneal Endothelial Morphology in Children with Type 1 Diabetes

Aim. To investigate corneal endothelial cell morphological in children with type 1 diabetes and to determine the systemic and local factors that contribute to these changes. Methods. One hundred sixty eyes of 80 children with type 1 diabetes and 80 eyes of 40 normal children as a control during the period from July 2015 to February 2016 underwent full clinical and ophthalmologic examination. We measured the central corneal thickness (CCT), endothelial cell density (ECD), ploymegathism, and pleomorphism using a noncontact specular microscope. Results. The mean age of the diabetic children was 8.22 ± 3.11 years. The mean duration of type 1 diabetes was 3.51 ± 2.23 years. The mean CCT was significantly higher: 537 ± 33.41 microns (right eye), in the diabetic group compared to the control group. The mean ECD in patients with type 1 diabetes was 3149.84 ± 343.75 cells/mm 2 (right eye), and it was significantly lower than in the control group. Furthermore, pleomorphism was significantly lower 48.73 ± 5.43% (right eye), in the diabetic group compared to the control group. The mean polymegathism was significantly higher 37.96 ± 5.61% (right eye), in the diabetic group compared to the control group. All of these changes are significantly correlated only with the duration of diabetes. Conclusions. Diabetic children have thicker corneas, lower ECD, an increased polymegathism, and a decreased pleomorphism. The duration of diabetes is the factor that affects all of these changes. To what extent these changes affect visional function on long term needs to be investigated in further studies