Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square‐Planar Copper(I) Complex

6,6′′‐Bis(2,4,6‐trimethylanilido)terpyridine (H2TpyNMes) was prepared as a rigid, tridentate pincer ligand containing pendent anilines as hydrogen bond donor groups in the secondary coordination sphere. The coordination geometry of (H2TpyNMes)copper(I)‐halide (Cl, Br and I) complexes is dictated by the strength of the NH–halide hydrogen bond. The CuICl and CuIICl complexes are nearly isostructural, the former presenting a highly unusual square‐planar geometry about CuI. The geometric constraints provided by secondary interactions are reminiscent of blue copper proteins where a constrained geometry, or entatic state, allows for extremely rapid CuI/CuII electron‐transfer self‐exchange rates. Cu(H2TpyNMes)Cl shows similar fast electron transfer (≈105 m−1 s−1) which is the same order of magnitude as biological systems.Entatic state: Hydrogen bonds constrain the geometry of CuI and CuII complexes. A highly unusual square‐planar geometry about CuI (see structure) is shown to be nearly isostructural to the CuII core. The minimal reorganization energy between redox states allows for extremely rapid CuI/CuII electron‐transfer self‐exchange rates.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/134494/1/anie201511527_am.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/134494/2/anie201511527-sup-0001-misc_information.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/134494/3/anie201511527.pd

Higgs-gauge boson interactions in the economical 3-3-1 model

Interactions among the standard model gauge bosons and scalar fields in the framework of SU(3)_C X SU(3)_L X U(1)_X gauge model with minimal (economical) Higgs content are presented. From these couplings, all scalar fields including the neutral scalar $h$ and the Goldstone bosons can be identified and their couplings with the usual gauge bosons such as the photon, the charged $W^\pm$ and the neutral $Z$, without any additional condition, are recovered. In the effective approximation, full content of scalar sector can be recognized. The CP-odd part of Goldstone associated with the neutral non-Hermitian bilepton gauge boson $G_{X^0}$ is decouple, while its CP-even counterpart has the mixing by the same way in the gauge boson sector. Masses of the new neutral Higgs boson $H^0_1$ and the neutral non-Hermitian bilepton $X^0$ are dependent on a coefficient of Higgs self-coupling ($\lambda_1$). Similarly, masses of the singly-charged Higgs boson $H_2^\pm$ and of the charged bilepton $Y^\pm$ are proportional through a coefficient of Higgs self-interaction ($\lambda_4$). The hadronic cross section for production of this Higgs boson at the LHC in the effective vector boson approximation is calculated. Numerical evaluation shows that the cross section can exceed 260 $fb$.Comment: 22 pages, 1 figure, submitted to Phys. Rev.

Testing Higgs models via the H±W∓ZH^\pm W^\mp Z vertex by a recoil method at the International Linear Collider

In general, charged Higgs bosons $H^\pm$ appear in non-minimal Higgs models. The $H^\pm W^\mp Z$ vertex is known to be related to the violation of the global symmetry (custodial symmetry) in the Higgs sector. Its magnitude strongly depends on the structure of the exotic Higgs models which contain higher isospin $SU(2)_L$ representations such as triplet Higgs bosons. We study the possibility of measuring the $H^\pm W^\mp Z$ vertex via single charged Higgs boson production associated with the $W^\pm$ boson at the International Linear Collider (ILC) by using the recoil method. The feasibility of the signal $e^+e^-\to H^\pm W^\mp \to \ell \nu jj$ is analyzed assuming the polarized electron and positron beams and the expected detector performance for the resolution of the two-jet system at the ILC. The background events can be reduced to a considerable extent by imposing the kinematic cuts even if we take into account the initial state radiation. For a relatively light charged Higgs boson whose mass $m_{H^\pm}$ is in the region of 120-130 GeV $< m_{H^\pm} < m_W+m_Z$, the $H^\pm W^\mp Z$ vertex would be precisely testable especially when the decay of $H^\pm$ is lepton specific. The exoticness of the extended Higgs sector can be explored by using combined information for this vertex and the rho parameter.Comment: 22 pages, 23 figure

Low Bias Negative Differential Resistance in Graphene Nanoribbon Superlattices

We theoretically investigate negative differential resistance (NDR) for ballistic transport in semiconducting armchair graphene nanoribbon (aGNR) superlattices (5 to 20 barriers) at low bias voltages V_SD < 500 mV. We combine the graphene Dirac Hamiltonian with the Landauer-B\"uttiker formalism to calculate the current I_SD through the system. We find three distinct transport regimes in which NDR occurs: (i) a "classical" regime for wide layers, through which the transport across band gaps is strongly suppressed, leading to alternating regions of nearly unity and zero transmission probabilities as a function of V_SD due to crossing of band gaps from different layers; (ii) a quantum regime dominated by superlattice miniband conduction, with current suppression arising from the misalignment of miniband states with increasing V_SD; and (iii) a Wannier-Stark ladder regime with current peaks occurring at the crossings of Wannier-Stark rungs from distinct ladders. We observe NDR at voltage biases as low as 10 mV with a high current density, making the aGNR superlattices attractive for device applications.Comment: 6 pages, 4 figure

Potential for measuring the H^\pm W^\mp Z^0 vertex from WZ fusion at the Large Hadron Collider

We investigate the possibility of measuring the H^\pm W^\mp Z^0 vertex from the single $H^\pm$ production process via WZ fusion at the CERN Large Hadron Collider (LHC). This vertex strongly depends on the structure of the Higgs sector in various new physics scenarios, so that its measurement can be useful to distinguish the models. A signal and background simulation under the expected detector performance at the LHC is done for the processes of pp \to W^\pm Z^0 X \to H^\pm X \to tbX and pp \to W^\pm Z^0 X \to H^\pm X \to W^\pm Z^0 X, and the required magnitudes of the H^\pm W^\mp Z^0 vertex for observation are evaluated. It is found that although the loop induced H^\pm W^\pm Z^0 vertex in multi-Higgs doublet models cannot be measurable, the latter process can be useful to test the model with a real and a complex triplets.Comment: 23 pages, 6 figures, version accepted for publication in Physical Review

CP-odd Higgs boson production in association with Neutral gauge boson in High-Energy e+e−e^+e^- Collisions

We study the associated production of a CP-odd Higgs boson $A^0$ with a neutral gauge boson ($Z$ or photon) in high-energy $e^+ e^-$ collisions at the one-loop level in the framework of Two Higgs Doublet Models (THDM). We find that in the small $\tan\beta$ regime the top quark loop contribution is enhanced leading to significant cross-sections (about a few fb), while in the large $\tan\beta$ regime the cross-section does not attain observable rates.Comment: 16 pages Latex, 4 figures, figures in agreement with erratu

Controlling the Electromagnetic Field Confinement with Metamaterials

The definition of a precise illumination region is essential in many applications where the electromagnetic field should be confined in some specific volume. By using conventional structures, it is difficult to achieve an adequate confinement distance (or volume) with negligible levels of radiation leakage beyond it. Although metamaterial structures and metasurfaces are well-known to provide high controllability of their electromagnetic properties, this feature has not yet been applied to solve this problem. We present a method of electromagnetic field confinement based on the generation of evanescent waves by means of metamaterial structures. With this method, the confinement volume can be controlled, namely, it is possible to define a large area with an intense field without radiation leakage. A prototype working in the microwave region has been implemented, and very good agreement between the measurements and the theoretical prediction of field distribution has been obtained

Vector Boson Pair Production in Hadronic Collisions at Order αs\alpha_s: Lepton Correlations and Anomalous Couplings

We present cross sections for production of electroweak vector boson pairs, $WW$, $WZ$ and $ZZ$, in $p\bar{p}$ and $pp$ collisions, at next-to-leading order in $\alpha_s$. We treat the leptonic decays of the bosons in the narrow-width approximation, but retain all spin information via decay angle correlations. We also include the effects of $WWZ$ and $WW\gamma$ anomalous couplings.Comment: 23 pages, 8 figures, 3 table

Associated H−^{-} W+^{+} Production in High Energy e+e−e^+e^- Collisions

We study the associated production of charged Higgs bosons with $W$ gauge bosons in high energy $e^+ e^-$ collisions at the one loop level. We present the analytical results and give a detailed discussion for the total cross section predicted in the context of a general Two Higgs Doublet Model (THDM).Comment: Latex, 31 pages, 6 figures, cosmetically improved and one reference adde