How regulating and cultural services of ecosystems have changed over time in Italy

In this experimental study, different components are computed for three different ecosystem services (ES). Specifically, supply, demand and use are estimated for pollination service, flood risk regulation service and nature-based tourism. These are analysed and assessed in 2012 and 2018 for the Italian context, in order to estimate the evolution over this period and to allow a significant comparison of results. The same methodology and models are applied for the selected accounting years and accounting tables and tend to reflect as closely as possible the System of Environmental-Economic Accounting-Ecosystem Accounting (SEEA EA), which is the international standard endorsed by the United Nations to compile Natural Capital Accounting in 2021. Both biophysical and monetary assessments are performed using the ARIES technology, an integrated modelling platform providing automatic and flexible integration of data and models, via its semantic modelling nature. Models have been run adjusting the components of the global modelling approach to the Italian context and, whenever available, prioritising the use of local data to carry out the study. This approach is particularly useful to analyse trends over time, as potentially biased components of models and data are substantially mitigated when the same biases is constant over time. This study finds an increase in benefits over the period analysed for the ES examined. The main contribution of this pioneering work is to support the idea that ES accounting or Natural Capital Accounting can provide a very useful tool to improve economic and environmental information at national and regional level. This can support processes to provide the necessary incentives to steer policy-making towards preventative rather than corrective actions, which are usually much less effective and more costly, both at environmental and economic levels. Nevertheless, particular attention must be paid to the meaning of the estimates and the drivers of these values to derive a direct or indirect relationship between the benefits observable and the actual Italian ecosystems condition. © Capriolo A et al

Anthropogenic-scale CO2 degassing from the Central Atlantic Magmatic Province as a driver of the end-Triassic mass extinction

The climatic and environmental impact of exclusively volcanic CO2 emissions is assessed during the main effusive phase of the Central Atlantic Magmatic Province (CAMP), which is synchronous with the end-Triassic mass extinction. CAMP volcanism occurred in brief and intense eruptive pulses each producing extensive basaltic lava flows. Here, CAMP volcanic CO2 injections into the surface system are modelled using a biogeochemical box model for the carbon cycle. Our modelling shows that, even if positive feedback phenomena may be invoked to explain the carbon isotope excursions preserved in end-Triassic sedimentary records, intense and pulsed volcanic activity alone may have caused repeated temperature increases and pH drops, up to 5 °C and about 0.2 log units respectively. Hence, rapid and massive volcanic CO2 emissions from CAMP, on a similar scale to current anthropogenic emissions, severely impacted on climate and environment at a global scale, leading to catastrophic biotic consequences

Deep CO₂ in the end-Triassic Central Atlantic Magmatic Province

Large Igneous Province eruptions coincide with many major Phanerozoic mass extinctions, suggesting a cause-effect relationship where volcanic degassing triggers global climatic changes. In order to fully understand this relationship, it is necessary to constrain the quantity and type of degassed magmatic volatiles, and to determine the depth of their source and the timing of eruption. Here we present direct evidence of abundant CO2 in basaltic rocks from the end-Triassic Central Atlantic Magmatic Province (CAMP), through investigation of gas exsolution bubbles preserved by melt inclusions. Our results indicate abundance of CO2 and a mantle and/or lower-middle crustal origin for at least part of the degassed carbon. The presence of deep carbon is a key control on the emplacement mode of CAMP magmas, favouring rapid eruption pulses (a few centuries each). Our estimates suggest that the amount of CO2 that each CAMP magmatic pulse injected into the end-Triassic atmosphere is comparable to the amount of anthropogenic emissions projected for the 21st century. Such large volumes of volcanic CO2 likely contributed to end-Triassic global warming and ocean acidification

Massive methane fluxing from magma–sediment interaction in the end-Triassic Central Atlantic Magmatic Province

Exceptional magmatic events coincided with the largest mass extinctions throughout Earth’s history. Extensive degassing from organic-rich sediments intruded by magmas is a possible driver of the catastrophic environmental changes, which triggered the biotic crises. One of Earth’s largest magmatic events is represented by the Central Atlantic Magmatic Province, which was synchronous with the end-Triassic mass extinction. Here, we show direct evidence for the presence in basaltic magmas of methane, generated or remobilized from the host sedimentary sequence during the emplacement of this Large Igneous Province. Abundant methane-rich fluid inclusions were entrapped within quartz at the end of magmatic crystallization in voluminous (about 1.0 × 106 km3) intrusions in Brazilian Amazonia, indicating a massive (about 7.2 × 103 Gt) fluxing of methane. These micrometre-sized imperfections in quartz crystals attest an extensive release of methane from magma–sediment interaction, which likely contributed to the global climate changes responsible for the end-Triassic mass extinction

Combustion of propanol isomers : Experimental and kinetic modeling study

In this work an experimental and kinetic modeling study on n-propanol and i-propanol combustion has been performed. New burning velocity measurements were carried out using the heat flux method at 1 atm over the temperature range of 323–393 K. Analysis of the temperature dependence was conducted with to verify the data consistency of the new and available data from the literature. Important inconsistencies were identified with the literature experiments performed using the spherical flame method and the nature of such inconsistencies was discussed. Moreover, a new kinetic mechanism, based on the most recent Konnov model and extended to include C3 alcohol isomers chemistry subset, was validated against new and all available literature data obtained at different combustion regimes. Rate constant parameters were carefully selected by evaluating all experimental and theoretical sources. Moreover, Sarathy et al. (2014) detailed kinetic mechanism was also tested. Overall, both kinetic models reproduce experimental data with good fidelity, but the presented model was found superior in representing ignition delay times data performed at high-pressure conditions

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