3,965 research outputs found

    Extreme mechanical resilience of self-assembled nanolabyrinthine materials

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    Low-density materials with tailorable properties have attracted attention for decades, yet stiff materials that can resiliently tolerate extreme forces and deformation while being manufactured at large scales have remained a rare find. Designs inspired by nature, such as hierarchical composites and atomic lattice-mimicking architectures, have achieved optimal combinations of mechanical properties but suffer from limited mechanical tunability, limited long-term stability, and low-throughput volumes that stem from limitations in additive manufacturing techniques. Based on natural self-assembly of polymeric emulsions via spinodal decomposition, here we demonstrate a concept for the scalable fabrication of nonperiodic, shell-based ceramic materials with ultralow densities, possessing features on the order of tens of nanometers and sample volumes on the order of cubic centimeters. Guided by simulations of separation processes, we numerically show that the curvature of self-assembled shells can produce close to optimal stiffness scaling with density, and we experimentally demonstrate that a carefully chosen combination of topology, geometry, and base material results in superior mechanical resilience in the architected product. Our approach provides a pathway to harnessing self-assembly methods in the design and scalable fabrication of beyond-periodic and nonbeam-based nano-architected materials with simultaneous directional tunability, high stiffness, and unsurpassed recoverability with marginal deterioration

    Exercise bouts at three different intensities fail to potentiate concentric power

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    Postactivation potentiation (PAP) has been hypothesized previously to occur during voluntary, concentric actions. We tested the hypothesis that one of at least three different intensities of conditioning exercises would evoke potentiation of power during the concentric, bench press throw (BPT). Twelve men (age = 22.9 &#; 2.7 years, bench press 1 repetition maximum (1RM) = 1.20 ± 0.12 kg•kg-1 body weight) completed five isotonic conditioning presses at ~55, 70, and 86% 1RM, in counterbalanced order, and on separate days. Average and peak power of the BPT using a load of 55% 1RM along with surface electromyography (EMG) of the triceps brachii were collected prior to and 4-minutes following each conditioning bout. Both average and peak power and EMG values (mean ± SD), respectively, were evaluated using two-way analyses of variance with repeated measures. Significant main effect decreases (p \u3c 0.05) in average (-18.6 ± 4.9 W) and peak power (-37.4 ± 9.9 W) occurred across the three different intensities evaluated. No main effects or interactions were observed with the EMG data. Contrary to the previously reported hypothesis, we were unable to demonstrate that conditioning exercise, with three different intensities, can evoke potentiation of power using a load equating to that which is optimum for power production

    Policy instruments in the Common Agricultural Policy

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    Policy changes in the Common Agricultural Policy (CAP) can be explained in terms of the exhaustion and long-term contradictions of policy instruments. Changes in policy instruments have reoriented the policy without any change in formal Treaty goals. The social and economic efficacy of instruments in terms of evidence-based policy analysis was a key factor in whether they were delegitimized. The original policy instruments were generally dysfunctional, but reframing the policy in terms of a multifunctionality paradigm permitted the development of more efficacious instruments. A dynamic interaction takes place between the instruments and policy informed by the predominant discourses

    Computation and interpretation of insolation tables

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    IBM 7074 computer program for computation of insolation tables for surface of Mar

    Higher compressive strengths and the Bauschinger effect in conformally passivated copper nanopillars

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    Our current understanding of size-dependent strength in nano- and microscale crystals is centered around the idea that the overall strength is determined by the stress required to propagate dislocation sources. The nature and type of these dislocation sources is the subject of extensive debate, however, one commonality amongst these theories is that the ability of the free surface to absorb dislocations is a necessary condition for transition to a source controlled regime. In this work we demonstrate that atomic layer deposition (ALD) of conformal 5–25 nm thick TiO_2/Al_(2)O_3 coatings onto electroplated single crystalline copper pillars with diameters ranging from 75 nm to 1 μm generally inhibits the ability of a dislocation to vanish at the free surface. Uniaxial compression tests reveal increased strength and hardening relative to uncoated pillars at equivalent diameters, as well as a notable recovery of plastic strain during unloading, i.e. the Bauschinger effect. Unlike previous reports, these coated pillars retained the stochastic signature in their stress–strain curves. We explain these observations within the framework of a size-dependent strength theory based on a single arm source model, dislocation theory, and microstructural analysis by transmission electron microscopy

    Mounting Materials for Automated Image Analysis of Coals Using Backscattered Electron Imaging

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    In order to apply SEM-based automated image analysis (AIA) to the characterization of not only minerals in coal but to the coal itself, sample preparation methods need to be developed beyond common practice. A significant consideration is the degree of contrast achievable between the mount media chosen and the coal. Four low-atomic number materials (epoxy, polyethylene, polystyrene and carnauba wax) were compared for their potential as suitable mounting media for coal samples. Epoxy is satisfactory only for characterization of mineral particles since the contrast between epoxy and coal particles is negligible. Polyethylene or polystyrene have marginal application for use as mounting material for coal characterization due to limited contrast and sample preparation artifacts. Carnauba wax appears satisfactory as a mounting material since it provides good contrast with coal particles with minimal artifacts

    Gaussians versus back-to-back exponentials: a numerical study

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    The underlying magnetic field distribution in many samples studied by the mu R technique is asymmetric. Despite this, quite often fit functions assuming symmetric (Gaussian) distributions are used. Here, a back-to-back exponential function, which can be made asymmetric with fit parameters, is studied numerically alongside a Gaussian function to see how well each fits symmetric and asymmetric simulated data. Both fit symmetric data well, but the back-to-back exponential is found to be superior for fitting asymmetric data

    The Ultrasensitivity of Living Polymers

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    Synthetic and biological living polymers are self-assembling chains whose chain length distributions (CLDs) are dynamic. We show these dynamics are ultrasensitive: even a small perturbation (e.g. temperature jump) non-linearly distorts the CLD, eliminating or massively augmenting short chains. The origin is fast relaxation of mass variables (mean chain length, monomer concentration) which perturbs CLD shape variables before these can relax via slow chain growth rate fluctuations. Viscosity relaxation predictions agree with experiments on the best-studied synthetic system, alpha-methylstyrene.Comment: 4 pages, submitted to Phys. Rev. Let

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