Interplay between Swelling Kinetics and Nanostructure in Perfluorosulfonic Acid Thin-Films: Role of Hygrothermal Aging

Impacts of processing, storage, and operation on thin-film perfluorosulfonic acid (PFSA) ionomer coatings used in electrodes of electrochemical devices remains unestablished. In this work, alteration of structure-function relationship in ionomers is achieved via exposure to elevated temperature and humidity (hygrothermal aging). Findings reflect a strong inverse correlation between aging-induced ionomer thin-film domain orientation and water-transport kinetics evaluated from swelling. Impact of aging is shown to be more pronounced on platinum due to interactions with PFSA, as evidenced by greater increase in nanodomain orientation parallel to substrate accompanied by reduced water transport, in contrast to silicon support

Performance trials on different rates and ratios of N and P fertilisation in Ethiopia to inform field-specific Maize-Nutrient-Management advisory

This report of the Scaling Readiness of Nutrient Management decision Support Tools project focuses on agronomic trials that serve to inform the development of scalable, field-specific advisory for maize farmers in Ethiopia. These trials were conducted to generate additional information required to make a mobile phone-based nutrient decision support tool – Maize-Nutrient-Manager – more scalable in the context of institutional limitations in fertilizer availability and distribution in Ethiopia. The focus of the trials is on establishing proper N:P ratio’s for different fertilization rates with the fertilizers available to farmers in West-Shewa and Jimma (two major maize belts in Ethiopia). The trials were conducted with additional funding from the TAMASA project and in collaboration with EIAR. As the latter institute is involved in conducting fertilizer trials and the development of recommendations, this collaboration also aimed at forming an appropriate entry point for institutionalization of the decision support tool that is being developed

Analysis of Seed Potato Systems in Ethiopia

This study aimed to analyze the seed potato systems in Ethiopia, identify constraints and prioritize improvement options, combining desk research, rapid appraisal and formal surveys, expert elicitation, field observations and local knowledge. In Ethiopia, informal, alternative and formal seed systems co-exist. The informal system, with low quality seed, is dominant. The formal system is too small to contribute significantly to improve that situation. The informal seed system should prioritize improving seed quality by increasing awareness and skills of farmers, improving seed tuber quality of early generations and market access. The alternative and formal seed systems should prioritize improving the production capacity of quality seed by availing new varieties, designing quality control methods and improving farmer’s awareness. To improve overall seed potato supply in Ethiopia, experts postulated co-existence and linkage of the three seed systems and development of self-regulation and selfcertification in the informal, alternative and formal cooperative seed potato systems. Resumen Este estudio tuvo el propósito de analizar los sistemas de producción de papa en Etiopia, identificar limitantes, y priorizar opciones de mejorar, mediante la combinación de investigación de escritorio, apreciaciones rápidas y estudios formales, encuestas a expertos, observaciones de campo y conocimiento local. En Etiopia co-existen sistemas de semilla informal, alternativo y formal. Domina el sistema informal, con baja calidad de semilla. El sistema formal es muy pequeño como para contribuir significativamente al mejoramiento de esa situación. El sistema informal de semilla debería tener como prioridad el mejoramiento en la calidad de la semilla mediante el aumento en la atención y habilidades de los productores, mejorando la calidad de la semilla-tubérculo de las generaciones tempranas y el acceso al mercado. Los sistemas alternativo y formal de semilla deberían priorizar el mejoramiento en la capacidad de producción de semilla de calidad, mediante la validación de nuevas variedades, el diseño de métodos de control de calidad, y mejorando la atención del productor. Para mejorar el suministro general de semilla de papa en Etiopia, los expertos postularon la co-existencia y asociación de los tres sistemas de semillas y el desarrollo de autorregulación y autocertificación en los sistemas cooperativos de semilla de papa informal, alternativo y formal. Keywords Potato . Seed quality . Seed tuber . Seed system . Quality improvement . Expert elicitation . Solanum tuberosum Introductio

Maize-Nutrient-Manager: A mobile phone application for field-specific, balanced nutrient management advisory

To increase productivity and profitability, while limiting nutrient losses and related GHG-emissions, African smallholders need more tailored fertilizer advice. Yet, such advice critically hinges upon – largely lacking – field-level management data, as management is key to efficient fertilizer use. The Maize- Nutrient-Manager (MNM) mobile phone application enables collection of such data at scale, and directly converts this data into actionable advice for the farmer. Focusing on field-level management data, MNM can identify those management practices that are currently imperative for enhancing smallholder farmers’ efficient use of fertilizers in their locality, thereby increasing productivity while reducing greenhouse gas (GHG) emissions. This document describes the background, design principles and development process of then MNM mobile phone application, as well as its pilot use in advisory practice in the Mbozi and Momba districts of Songwe region, Tanzania

Permeation of CO₂ and N₂ through glassy poly(dimethyl phenylene) oxide under steady- and presteady-state conditions

Glassy polymers are often used for gas separations because of their high selectivity. Although the dual‐mode permeation model correctly fits their sorption and permeation isotherms, its physical interpretation is disputed, and it does not describe permeation far from steady state, a condition expected when separations involve intermittent renewable energy sources. To develop a more comprehensive permeation model, we combine experiment, molecular dynamics, and multiscale reaction–diffusion modeling to characterize the time‐dependent permeation of N₂ and CO₂ through a glassy poly(dimethyl phenylene oxide) membrane, a model system. Simulations of experimental time‐dependent permeation data for both gases in the presteady‐state and steady‐state regimes show that both single‐ and dual‐mode reaction–diffusion models reproduce the experimental observations, and that sorbed gas concentrations lag the external pressure rise. The results point to environment‐sensitive diffusion coefficients as a vital characteristic of transport in glassy polymers

Exploiting indigenous knowledge of subsistence farmers’ for the management and conservation of Enset (Ensete ventricosum (Welw.) Cheesman) (musaceae family) diversity on-farm

Enset (Ensete ventricosum (Welw.) Cheesman) belongs to the order sctaminae, the family musaceae. The Musaceae family is subdivided into the genera Musa and Ensete. Enset is an important staple crop for about 20 million people in the country. Recent publications on enset ethnobotany are insignificant when compared to the diverse ethnolingustic communities in the country. Hence, this paper try to identify and document wealth of indigenous knowledge associated with the distribution, diversity, and management of enset in the country. Methods: The study was conducted in eight ethnic groups in the Southern Nations, Nationalities and Peoples’ Regional State. In order to identify and document wealth of indigenous knowledge, the data was collected mainly through individual interviews and direct on-farm participatory monitoring and observation with 320 farm households, key informant interviews. Relevant secondary data, literature and inter-personal data were collected from unpublished progress report from National Enset Research Project, elderly people and senior experts. Results: Enset-based farming system is one of a major agricultural system in Ethiopia that serves as a backbone for at least ¼ of country’s population. Farmers used three morphological characters, two growth attributes, disease resistance and five use values traits in folk classification and characterization of enset. A total of 312 folk landraces have been identified. The number of landraces cultivated on individual farms ranged from one to twenty eight (mean of 8.08 ± 0.93). All ethnic groups in the study area use five use categories in order of importance: kocho yield and quality, bulla quality, amicho use, fiber quality and medicinal/ritual value. Of the 312 landraces 245 landraces having more than two use types. Management and maintenance of on-farm enset diversity is influenced by systematic propagation of the landraces, exchange of planting material and selective pressure. Conclusion: It can be concluded that the existing farmers’ knowledge on naming, classification and diversity should be complemented with maintenance of the creative dynamics of traditional knowledge and transmission of the knowledge are crucial for constructing sustainable management

Community Water Improvement, Household Water Insecurity, and Women’s Psychological Distress: An Intervention and Control Study in Ethiopia

BACKGROUND: Over 650 million people worldwide lack access to safe water supplies, and even among those who have gained access to 'improved' sources, water may be seasonally unreliable, far from homes, expensive, and provide insufficient quantity. Measurement of water access at the level of communities and households remains crude, and better measures of household water insecurity are urgently needed to inform needs assessments and monitoring and evaluation. We set out to assess the validity of a quantitative scale of household water insecurity, and to investigate (1) whether improvements to community water supply reduce water insecurity, (2) whether water interventions affect women's psychological distress, and (3) the impacts of water insecurity on psychological distress, independent of socio-economic status, food security, and harvest quality. METHODS AND FINDINGS: Measures were taken before and one to six months after a community water supply improvement in three villages in rural northern Ethiopia. Villages similar in size and access to water sources and other amenities did not receive interventions, and served as controls. Household water insecurity was assessed using a 21-item scale based on prior qualitative work in Ethiopia. Women's psychological distress was assessed using the WHO Self-Reporting Questionnaire (SRQ-20). Respondents were either female heads of household or wives of the heads of household (n = 247 at baseline, n = 223 at endline); 123 households provided data at both rounds. The intervention was associated with a decline of approximately 2 points on the water insecurity scale between baseline and endline compared to the control (beta -1.99; 95% CI's -3.15, -0.84). We did not find evidence of impact of the intervention on women's psychological distress. Water insecurity was, however, predictive of psychological distress (p <0.01), independent of household food security and the quality of the previous year's harvest. CONCLUSION: These results contribute to the construct validity of our water insecurity scale, and establish our approach to measuring water insecurity as a plausible means of evaluating water interventions. Improvements to community water supplies were effective in reducing household water insecurity, but not psychological distress, in this population. Water insecurity was an important predictor of psychological distress. This study contributes to an emerging literature on quantitative assessment of household water insecurity, and draws attention to the potential impact of improved access to water on women's mental well-being