Pd-Fe3O4/RGO: a Highly Active and Magnetically Recyclable Catalyst for Suzuki Cross Coupling Reaction using a Microfluidic Flow Reactor

There are several crucial issues that need to be addressed in the field of applied catalysis. These issues are not only related to harmful environmental impact but also include process safety concerns, mass and heat transfer limitations, selectivity, high pressure, optimizing reaction conditions, scale-up issues, reproducibility, process reliability, and catalyst deactivation and recovery. Many of these issues could be solved by adopting the concept of micro-reaction technology and flow chemistry in the applied catalysis field. A microwave assisted reduction technique has been used to prepare well dispersed, highly active Pd/Fe3O4 nanoparticles supported on reduced graphene oxide nanosheets (Pd-Fe3O4/RGO), which act as a unique catalyst for Suzuki cross coupling reactions due to the uniform dispersion of palladium nanoparticles throughout the surface of the magnetite - RGO support. The Pd-Fe3O4/RGO nanoparticles have been shown to exhibit extremely high catalytic activity for Suzuki cross coupling reactions under both batch and continuous reaction conditions. This paper reported a reliable method for Suzuki cross-coupling reaction of 4-bromobenzaldehyde using magnetically recyclable Pd/Fe3O4 nanoparticles supported on RGO nanosheets in a microfluidic-based high throughput flow reactor. Organic synthesis can be performed under high pressure and temperature by using a stainless steel micro tubular flow reactor under continuous flow reaction conditions. Optimizing the reaction conditions was performed via changing several parameters including temperature, pressure, and flow rate. Generally, a scalable flow technique by optimizing the reaction parameters under high-temperature and continuous reaction conditions could be successfully developed

The Effect Of Graphene On Catalytic Performance Of Palladium Nanoparticles Decorated With Fe3O4, Co3O4, And Ni (OH)2: Potential Efficient Catalysts Used For Suzuki Cross—Coupling

Abstract: In this research, we report a scientific investigation of an efficient method used for the synthesis of highly active Palladium Nanoparticles decorated with Fe3O4, Co3O4, and Ni (OH)2 Supported on Graphene as Potential Efficient Catalysts for Suzuki Cross—Coupling. Pd/Fe3O4 nanoparticles supported on graphene nanosheets (Pd/Fe3O4/G) showed an excellent catalytic activity for Suzuki coupling reactions and recycled for up to four times without loss of catalytic activity. An efficient magnetic catalyst has been successfully synthesized using a simple, reproducible fast and reliable method using microwave irradiation conditions. The prepared catalysts are magnetic as in case of iron and cobalt oxides which is an advantage in the separation process of catalyst from the reaction medium via applying a strong external magnetic field. The synthesis approach is based on the Microwave (MW)-assisted simultaneous reduction of palladium and ferric nitrates in the presence of graphene oxide (GO) nanosheets using hydrazine hydrate as the reducing agent. The results provide a fundamental understanding of the system variables by comparing the catalytic activity and recyclability of different catalysts with different properties. The most active and recyclable catalyst was Pd–Fe3O4—supported on graphene which offers several added advantages including recyclability of up to seven times, mild reaction conditions, and short reaction times in an environmentally benign solvent system. Furthermore, the magnetic properties imparted by the Fe3O4 component of the catalyst enables the catalyst to be easily isolated and recycled, thus greatly simplifying the ability to purify the reaction products and increasing the economic value of the catalyst. The utility of these magnetic catalysts towards Suzuki cross coupling reaction was also demonstrated. The high activity and recyclability of these catalysts are attributed to a strong catalyst-support interaction where the defect sites in the reduced GO nanosheets act as nucleation centers for anchoring the Pd and Fe3O4 nanoparticles thus minimizing the potential of their agglomeration and the subsequent decrease in the catalytic activity. Graphical Abstract: [Figure not available: see fulltext.]

Numerical analysis of energy transmission through discontinuities and fillings in Kangir Dam

Abstract A considerable amount of energy is released in the form of shock wave from explosive charge detonation. Shock wave energy is responsible for the creation of crushing and fracture zone around the blast hole. The rest of the shock wave energy is transferred to rock mass as ground vibration. Ground vibration is conveyed to the adjacent structures by body and surface waves. Geological structures like faults, fractures, and fillings play important roles in the wave attenuation. Studying the mechanism of ground wave propagation from blasts gives a better understanding about the stress wave transmission and its effect on the near structures. In this research work, the stress wave transmissions from discontinuities and fillings were evaluated using a field measurement and a Universal Distinct Element Code (UDEC). A single-hole blast was conducted in the Kangir dam, and the resulting vibrations were measured in many points before and after the faults. Numerical simulation shows the effects of geo-mechanical properties of fillings on the reflection and refraction rate of the stress wave. There are more energy reflections in the rock boundaries and soil fillings, and more energy is absorbed by soil fillings compared with rock fillings. Furthermore, there is a close correlation between the ground vibration records for the Kangir dam and the numerical results. The maximum relative error between the actual records and the simulated ones was found to be 18.5%, which shows the UDEC ability for the prediction of blast vibrations

Design, Build, and Evaluation of an AC Loss Measurement Rig for High-Speed Superconducting Bearings

Friction and heat generated in conventional bearings impose a limit on maximum design speed in electrical machines. Superconducting bearings offer the potential for low loss, simplified, and passively stable bearings that can overcome the speed limit and operate at high loads. Although such bearings are contactless and seem to be loss free, AC loss mainly caused by magnetic field inhomogeneity gradually slows down the rotating body. This loss, whose mechanism has not been fully explored, is measured through spin-down tests where the rotational speed of the spinning rotor is measured as a function of time. However, there are some challenges in performing a reliable spin-down test. In this paper, we discuss these challenges as well as the engineering of an experimental test rig that enables us to spin-up, release, and recapture the levitated permanent magnet. We also discuss the specifications of the driving mechanism including the self-aligning coupling, which accommodates permanent magnets of different sizes. Initial test results at 6600 rpm are discussed and further technical improvements to the test rig suggested. This rig will be used as a key tool to explore the AC loss mechanism and inform the design of bearings for high-speed superconducting machines

Design, Build, and Evaluation of an AC Loss Measurement Rig for High-Speed Superconducting Bearings

Friction and heat generated in conventional bearings impose a limit on maximum design speed in electrical machines. Superconducting bearings offer the potential for low loss, simplified, and passively stable bearings that can overcome the speed limit and operate at high loads. Although such bearings are contactless and seem to be loss free, AC loss mainly caused by magnetic field inhomogeneity gradually slows down the rotating body. This loss, whose mechanism has not been fully explored, is measured through spin-down tests where the rotational speed of the spinning rotor is measured as a function of time. However, there are some challenges in performing a reliable spin-down test. In this paper, we discuss these challenges as well as the engineering of an experimental test rig that enables us to spin-up, release, and recapture the levitated permanent magnet. We also discuss the specifications of the driving mechanism including the self-aligning coupling, which accommodates permanent magnets of different sizes. Initial test results at 6600 rpm are discussed and further technical improvements to the test rig suggested. This rig will be used as a key tool to explore the AC loss mechanism and inform the design of bearings for high-speed superconducting machines

Highly Efficient And Magnetically Recyclable Graphene-supported Pd/Fe3O4 Nanoparticle Catalysts For Suzuki And Heck Cross-coupling Reactions

Herein, we report a facile and efficient one-step method for the synthesis of highly active, Pd/Fe3O4 nanoparticles supported on graphene nanosheets (Pd/Fe3O4/G) that exhibit excellent catalytic activity for Suzuki and Heck coupling reactions and that can be magnetically separated from the reaction mixture and recycled multiple times without loss of catalytic activity. The synthesis approach is based on the Microwave (MW)-assisted reduction of palladium and ferric nitrates in the presence of graphene oxide (GO) nanosheets using hydrazine hydrate as the reducing agent. The results provide a fundamental understanding of the system variables by comparing the catalytic activity and recyclability of four different catalysts with different properties. The most active and recyclable catalyst contains 7.6 wt% Pd nanoparticles with 4-6nm diameters in Pd(0) oxidation state well-dispersed with 30wt% Fe3O4 nanoparticles with 12-16 nm diameters on highly reduced GO containing a C/O ratio of 8.1. These combined properties produce remarkable catalytic activity for Suzuki cross coupling reactions under MW reaction conditions with an extremely high turnover number (TON) of 9250 and turn over frequency (TOF) of 111,000 h-1 at 80 °C. The magnetic properties imparted by the Fe3O4 component of the catalyst enables the catalyst to be easily isolated and recycled, thus greatly simplifying the ability to purify the reaction products and increasing the economic value of the catalyst. The utility of these magnetic catalysts towards Suzuki and Heck cross coupling reactions with a variety of functionalized substrates was also demonstrated