A Top-Down Design for Easy Gram Scale Synthesis of Melem Nano Rectangular Prisms with Improved Surface Area

An unprecedented top-down design for the preparation of melem by 1 h stirring of melamine-based g-C3N4 in 80 °C concentrated sulfuric acid (95-98%) was discovered. The melem product was formed selectively as a monomer on the gram scale without the need for controlled conditions, inert atmosphere, and a special purification technique. The as-prepared air-stable melem showed a distinctive nano rectangular prism morphology that possesses a larger surface area than the melems achieved by traditional bottom-up designs making it a promising candidate for catalysis and adsorption processes. This journal is © The Royal Society of Chemistry.We appreciate the Research Council of the University of Birjand for support of this work. The equipment of the Ural Center for Shared Use "Modern nanotechnology" Ural Federal University (Reg. NO. 2968) was used with the financial support of the Ministry of Science and Higher Education of the RF (Project NO. 075-15-2021-677)

Quantitative and qualitative study of airborne radioactive particles in the safety chamber of Tehran research reactor

Background and Aims: Many systems and processes can cause the introduction of radioactivity into the environment. Human activities in nuclear industry such as nuclear fuel cycle and reactor operation, lead to a significant production and release of radioactivity to the environment. Understanding the physical and chemical nature, including size, chemical composition and radioactivity of aerosol particles in the safety chamber of Tehran research reactor is indispensable for evaluation of exposure level and methods of prevention. The aim of this study was to measure the size distribution of aerosols and their activities, which was determined using an Anderson cascade Impactor (ACI) ACFM model and liquid scintillation respectively. The measurements were performed in three workstations in the safety chamber of Tehran research reactor. Methods: The identification of existing radio nuclides on suspended particles were carried out in the safety chamber by means of environmental sampler and mass size distribution of particles was measured using an Anderson cascade Impactor (ACI). To determine the type and amount of radio nuclides in the aerosol particles the γ-ray spectrometry with a high-purity germanium (HPGe) detector and ultra-low level liquid scintillation spectrometer were used respectively. Results: The results showed that the activities median aerodynamic diameter (AMAD) value for three selected workstations were 2.4, 3.1 and 3μm with geometric standard deviation of 2.3, 2.12 and 2 respectively. Furthermore, the results of particle activity size distribution showed that the most fraction of activity was related to nucleation and accumulation mode, especially particles with the aerodynamic diameter less than 0.4μm. Conclusion: The most activity was related to the number of particles in the accumulation and nucleation mode (fine particles). The origin of these particles can be the coagulation of particles in the nucleation mode. The accumulation mode also contains droplets formed by the chemical conversion of gases to vapors that condense

Parametric investigation of the mechanical behavior of expanding-folding absorbers and their implementation in sandwich panels core

Thin-walled energy absorbers are one of the common structures that are used in vehicle body for increasing the crashworthiness and consequently decreasing injuries. Investigated new type of thin-walled aluminum matrix and a thin-walled steel punch energy absorber structure has been investigated in this paper. Energy is absorbed as the matrix expansion followed by simultaneous matrix and punch folding. Present study proposes a sandwich panel based on expanding-folding absorber units to evaluate their crush mechanism. Parametric study has been done using finite element code LS-DYNA while experimental tests have been implemented to validate the FE model. The panels have been tested under three axial quasi-static loading conditions including a rigid half-cylinder and a rigid plate. Parametric study considers the punch angle, matrix thickness and punch thickness. The optimum structure based on energy absorption has then been used as a structural member in the sandwich panel until a panel with high specific energy absorption be introduced. Also it have been seen that all the curves for the expansion section can be estimated using polynomial second order functions, with a high accuracy